53
20. Whittingham MS, Siu C, Ding J (2018) Can multielectron intercalation reactions be the basis
of next generation batteries? Acc Chem Res 51:258–264
21. Tang B, Shan L, Liang S et al (2019) Issues and opportunities facing aqueous zinc-ion batteries. Energy Environ Sci 12:3288–3304
22. Huang S, Zhu J, Tian J et al (2019) Recent progress in the electrolytes of aqueous zinc-ion
batteries. Chem Eur J 25:14480–14494
23. Manalastas W, Kumar S, Verma V et al (2019) Water in rechargeable multivalent-ion batteries: An electrochemical pandora’s box. ChemSusChem 12:379–396
24. Xu J, Du H, Li B et al (2009) Reversible insertion properties of zinc ion into manganese
dioxide and its application for energy storage. Electrochem Solid-State Lett 12:A61–A65
25. Kasiri G, Trócoli R, Hashemi AM et al (2016) An electrochemical investigation of the aging
of copper hexacyanoferrate during the operation in zinc-ion batteries. Electrochim Acta
222:74–83
26. Senguttuvan P, Han S, Kim S et al (2016) A high power rechargeable nonaqueous multivalent
Zn/V2O 5 battery. Adv Energ Mater 6:1600826
27. Xu W, Wang Y (2019) Recent progress on zinc-ion rechargeable batteries. Nano-Micro Lett
11:90
28. Deravaj S, Munichandraiah N (2008) Effect of crystallographic structure of MnO 2 on its
electrochemical capacitance properties. J Phys Chem C 112:4406–4417
29. Cheng FY, Chen J, Gou XL et al (2005) High-power alkaline Zn–MnO 2 batteries using
γ-MnO 2 nanowires/nanotubes and electrolytic zinc powder. Adv Mater 17:2753–2756
30. Alfaruqi MH, Gim J, Kim S et al (2015) Enhanced reversible divalent zinc storage in a structurally stable α-MnO 2 nanorod electrode. J Power Sources 288:320–327
31. Xu C, Chen Y, Shi S et al (2015) Secondary batteries with multivalent ions for energy storage.
Sci Rep 5:14120–14128
32. Lee B, Lee HR, Kim H et al (2015) Elucidating the intercalation mechanism of zinc ions into
α-MnO 2 for rechargeable zinc batteries. Chem Commun 51:9265–9268
33. Lee B, Yoon CS, Lee HR et al (2014) Electrochemically-induced reversible transition from
the tunneled to layered polymorphs of manganese dioxide. Sci Rep 4:6066
34. Lee B, Seo HR, Lee HR et al (2016) Critical role of pH evolution of electrolyte in the reaction
mechanism for rechargeable zinc batteries. ChemSusChem 9:1–10
35. Pan H, Shao Y, Yan P et al (2016) Reversible aqueous zinc/manganese oxide energy storage
from conversion reactions. Nat Energy 1:16039
36. Alfaruqi MH, Mathew V, Gim J et al (2015) Electrochemically induced structural transformation in a γ-MnO 2 cathode of a high capacity zinc-ion battery system. Chem Mater
27:3609–3620
37. Alfaruqi MH, Gim J, Kim S et al (2015) A layered δ-MnO 2 nanoflake cathode with high zincstorage capacities for eco-friendly battery applications. Electrochem Commun 60:121–125
38. Zhang N, Cheng F, Liu J et al (2017) Rechargeable aqueous zinc-manganese dioxide batteries
with high energy and power densities. Nat Commun 8:405
39. Islam S, Alfaruqi MH, Song J et al (2017) Carbon-coated manganese dioxide nanoparticles
and their enhanced electrochemical properties for zinc-ion battery applications. J Energy
Chem 26:815–819
40. Yuan C, Zhang Y, Pan Y et al (2014) Investigation of the intercalation of polyvalent cations
(Mg
2+
, Zn
2+
) into λ-MnO 2 for rechargeable aqueous battery. Electrochim Acta 116:404–412
41. Zhang N, Cheng F, Liu Y et al (2016) Cation-deficient spinel ZnMn 2 O 4 cathode in Zn(CF 3 SO 3 ) 2
electrolyte for rechargeable aqueous Zn-ion battery. J Am Chem Soc 138:12894–12901
42. Sun W, Wang F, Hou S et al (2017) Zn/MnO 2 battery chemistry with H
+ and Zn
2+ coinsertion.
J Am Chem Soc 139:9775–9778
43. Ha S, Lee KT (2016) Batteries: converting to long stability. Nat Energy 1:16057
44. Wu B, Zhang G, Yan M et al (2018) Graphene scroll-coated α-MnO 2 nanowires as high performance cathode materials for aqueous Zn-ion battery. Small 14:1703850
Recent Developments of Zinc-Ion Batteries
20. Whittingham MS, Siu C, Ding J (2018) Can multielectron intercalation reactions be the basis
of next generation batteries? Acc Chem Res 51:258–264
21. Tang B, Shan L, Liang S et al (2019) Issues and opportunities facing aqueous zinc-ion batteries. Energy Environ Sci 12:3288–3304
22. Huang S, Zhu J, Tian J et al (2019) Recent progress in the electrolytes of aqueous zinc-ion
batteries. Chem Eur J 25:14480–14494
23. Manalastas W, Kumar S, Verma V et al (2019) Water in rechargeable multivalent-ion batteries: An electrochemical pandora’s box. ChemSusChem 12:379–396
24. Xu J, Du H, Li B et al (2009) Reversible insertion properties of zinc ion into manganese
dioxide and its application for energy storage. Electrochem Solid-State Lett 12:A61–A65
25. Kasiri G, Trócoli R, Hashemi AM et al (2016) An electrochemical investigation of the aging
of copper hexacyanoferrate during the operation in zinc-ion batteries. Electrochim Acta
222:74–83
26. Senguttuvan P, Han S, Kim S et al (2016) A high power rechargeable nonaqueous multivalent
Zn/V2O 5 battery. Adv Energ Mater 6:1600826
27. Xu W, Wang Y (2019) Recent progress on zinc-ion rechargeable batteries. Nano-Micro Lett
11:90
28. Deravaj S, Munichandraiah N (2008) Effect of crystallographic structure of MnO 2 on its
electrochemical capacitance properties. J Phys Chem C 112:4406–4417
29. Cheng FY, Chen J, Gou XL et al (2005) High-power alkaline Zn–MnO 2 batteries using
γ-MnO 2 nanowires/nanotubes and electrolytic zinc powder. Adv Mater 17:2753–2756
30. Alfaruqi MH, Gim J, Kim S et al (2015) Enhanced reversible divalent zinc storage in a structurally stable α-MnO 2 nanorod electrode. J Power Sources 288:320–327
31. Xu C, Chen Y, Shi S et al (2015) Secondary batteries with multivalent ions for energy storage.
Sci Rep 5:14120–14128
32. Lee B, Lee HR, Kim H et al (2015) Elucidating the intercalation mechanism of zinc ions into
α-MnO 2 for rechargeable zinc batteries. Chem Commun 51:9265–9268
33. Lee B, Yoon CS, Lee HR et al (2014) Electrochemically-induced reversible transition from
the tunneled to layered polymorphs of manganese dioxide. Sci Rep 4:6066
34. Lee B, Seo HR, Lee HR et al (2016) Critical role of pH evolution of electrolyte in the reaction
mechanism for rechargeable zinc batteries. ChemSusChem 9:1–10
35. Pan H, Shao Y, Yan P et al (2016) Reversible aqueous zinc/manganese oxide energy storage
from conversion reactions. Nat Energy 1:16039
36. Alfaruqi MH, Mathew V, Gim J et al (2015) Electrochemically induced structural transformation in a γ-MnO 2 cathode of a high capacity zinc-ion battery system. Chem Mater
27:3609–3620
37. Alfaruqi MH, Gim J, Kim S et al (2015) A layered δ-MnO 2 nanoflake cathode with high zincstorage capacities for eco-friendly battery applications. Electrochem Commun 60:121–125
38. Zhang N, Cheng F, Liu J et al (2017) Rechargeable aqueous zinc-manganese dioxide batteries
with high energy and power densities. Nat Commun 8:405
39. Islam S, Alfaruqi MH, Song J et al (2017) Carbon-coated manganese dioxide nanoparticles
and their enhanced electrochemical properties for zinc-ion battery applications. J Energy
Chem 26:815–819
40. Yuan C, Zhang Y, Pan Y et al (2014) Investigation of the intercalation of polyvalent cations
(Mg
2+
, Zn
2+
) into λ-MnO 2 for rechargeable aqueous battery. Electrochim Acta 116:404–412
41. Zhang N, Cheng F, Liu Y et al (2016) Cation-deficient spinel ZnMn 2 O 4 cathode in Zn(CF 3 SO 3 ) 2
electrolyte for rechargeable aqueous Zn-ion battery. J Am Chem Soc 138:12894–12901
42. Sun W, Wang F, Hou S et al (2017) Zn/MnO 2 battery chemistry with H
+ and Zn
2+ coinsertion.
J Am Chem Soc 139:9775–9778
43. Ha S, Lee KT (2016) Batteries: converting to long stability. Nat Energy 1:16057
44. Wu B, Zhang G, Yan M et al (2018) Graphene scroll-coated α-MnO 2 nanowires as high performance cathode materials for aqueous Zn-ion battery. Small 14:1703850
Recent Developments of Zinc-Ion Batteries