54
45. Alfaruqi MH, Islam S, Mathew V et al (2017) Ambient redox synthesis of vanadium-doped
manganese dioxide nanoparticles and their enhanced zinc storage properties. Appl Surf Sci
404:435–442
46. Lee J, Ju JB, Cho W et al (2013) Todorokite-type MnO 2 as a zinc-ion intercalating material.
Electrochim Acta 112:138–143
47. Jiang B, Xu C, Wu C et al (2017) Manganese Sesquioxide as cathode material for multivalent
zinc ion battery with high capacity and long cycle life. Electrochim Acta 229:422–428
48. Hao J, Mou J, Zhang J et al (2018) Electrochemically induced spinel-layered phase transition
of Mn 3 O 4 in high performance neutral aqueous rechargeable zinc battery. Electrochim Acta
259:170–178
49. Xu D, Li B, Wei C et al (2014) Preparation and characterization of MnO2/acid-treated CNT
nanocomposites for energy storage with zinc ions. Electrochim Acta 133:254–261
50. Qiu W, Li Y, You A et al (2017) High-performance flexible quasi-solid-state Zn–MnO2 battery based on MnO2 nanorod arrays coated 3D porous nitrogen-doped carbon cloth. J Mater
Chem A 5:14838–14846
51. Islam S, Alfaruqi MH, Mathew V et al (2017) Facile synthesis and the exploration of the zinc
storage mechanism of β-MnO 2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries. J Mater Chem A 5:23299–23309
52. Huang J, Wang Z, Hou M et al (2018) Polyaniline-intercalated manganese dioxide nanolayers
as a high-performance cathode material for an aqueous zinc-ion battery. Nat Commun 9:2906
53. Chao D, Zhou W, Ye C et al (2019) An electrolytic Zn-MnO 2 battery for high-voltage and
scalable energy storage. Angew Chem Int Ed 58:7823–7828
54. Yun L, Shanyu W, James RS et al (2019) Reaction mechanisms for long-life rechargeable Zn/
MnO 2 batteries. Chem Mater 31:2036–2047
55. Mingqiang L, Zhao Q, Ye C et al (2019) Tuning phase evolution of β-MnO2 during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery. Nano Energy
64:103942
56. Wang C, Yinxiang Z, Xiang X et al (2020) γ-MnO2 nanorods/graphene composite as
efficient cathode for advanced rechargeable aqueous zinc-ion battery. J Energy Chem
43(2020):182–187
57. Chunyan W, Mingqiang W, Zhichao H et al (2020) Rechargeable aqueous zinc–manganese
dioxide/Graphene batteries with high rate capability and large capacity. ACS App Energy
Mater 3(2):1742–1748
58. Guo C, Shuo T, Binglei C et al (2020) Constructing α-MnO 2 @ PPy core-shell nanorods
towards enhancing electrochemical behaviors in aqueous zinc ion battery. Mater Lett
262:127180
59. Soundharrajan V, Sambandam B, Kim S et al (2020) The dominant role of Mn
2+ additive
on the electrochemical reaction in ZnMn 2 O 4 cathode for aqueous zinc-ion batteries. Energy
Storage Mater. https://doi.org/10.1016/j.ensm.2019.12.021
60. Li H, Han C, Huang Y et al (2018) An extremely safe and wearable solid-state zinc ion battery based on a hierarchical structured polymer electrolyte. Energy Environ Sci 11:941–951
61. Zeng Y, Zhang Y, Meng Y et al (2017) Achieving ultrahigh energy density and long durability
in a flexible rechargeable quasi-solid-state Zn–MnO 2 battery. Adv Mater 29:1700274
62. Kundu D, Adams D, Duffort V et al (2016) A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode. Nat Energy 1:16119
63. Alfarugi MH, Mathew V, Song J et al (2017) Electrochemical zinc intercalation in lithium
vanadium oxide: a high-capacity zinc-ion battery cathode. Chem Mater 29:1684–1694
64. Jo JH, Sun YK, Myung ST (2017) Hollandite-type Al-doped VO 1.52 (OH) 0.77 as a zinc ion
insertion host material. J Mater Chem A 5:8367–8375
65. Xia C, Guo J, Lei Y (2018) Rechargeable aqueous zinc-ion battery based on porous framework zinc pyrovanadate intercalation cathode. Adv Mater 30:1705580
J. Kim et al.
45. Alfaruqi MH, Islam S, Mathew V et al (2017) Ambient redox synthesis of vanadium-doped
manganese dioxide nanoparticles and their enhanced zinc storage properties. Appl Surf Sci
404:435–442
46. Lee J, Ju JB, Cho W et al (2013) Todorokite-type MnO 2 as a zinc-ion intercalating material.
Electrochim Acta 112:138–143
47. Jiang B, Xu C, Wu C et al (2017) Manganese Sesquioxide as cathode material for multivalent
zinc ion battery with high capacity and long cycle life. Electrochim Acta 229:422–428
48. Hao J, Mou J, Zhang J et al (2018) Electrochemically induced spinel-layered phase transition
of Mn 3 O 4 in high performance neutral aqueous rechargeable zinc battery. Electrochim Acta
259:170–178
49. Xu D, Li B, Wei C et al (2014) Preparation and characterization of MnO2/acid-treated CNT
nanocomposites for energy storage with zinc ions. Electrochim Acta 133:254–261
50. Qiu W, Li Y, You A et al (2017) High-performance flexible quasi-solid-state Zn–MnO2 battery based on MnO2 nanorod arrays coated 3D porous nitrogen-doped carbon cloth. J Mater
Chem A 5:14838–14846
51. Islam S, Alfaruqi MH, Mathew V et al (2017) Facile synthesis and the exploration of the zinc
storage mechanism of β-MnO 2 nanorods with exposed (101) planes as a novel cathode material for high performance eco-friendly zinc-ion batteries. J Mater Chem A 5:23299–23309
52. Huang J, Wang Z, Hou M et al (2018) Polyaniline-intercalated manganese dioxide nanolayers
as a high-performance cathode material for an aqueous zinc-ion battery. Nat Commun 9:2906
53. Chao D, Zhou W, Ye C et al (2019) An electrolytic Zn-MnO 2 battery for high-voltage and
scalable energy storage. Angew Chem Int Ed 58:7823–7828
54. Yun L, Shanyu W, James RS et al (2019) Reaction mechanisms for long-life rechargeable Zn/
MnO 2 batteries. Chem Mater 31:2036–2047
55. Mingqiang L, Zhao Q, Ye C et al (2019) Tuning phase evolution of β-MnO2 during microwave hydrothermal synthesis for high-performance aqueous Zn ion battery. Nano Energy
64:103942
56. Wang C, Yinxiang Z, Xiang X et al (2020) γ-MnO2 nanorods/graphene composite as
efficient cathode for advanced rechargeable aqueous zinc-ion battery. J Energy Chem
43(2020):182–187
57. Chunyan W, Mingqiang W, Zhichao H et al (2020) Rechargeable aqueous zinc–manganese
dioxide/Graphene batteries with high rate capability and large capacity. ACS App Energy
Mater 3(2):1742–1748
58. Guo C, Shuo T, Binglei C et al (2020) Constructing α-MnO 2 @ PPy core-shell nanorods
towards enhancing electrochemical behaviors in aqueous zinc ion battery. Mater Lett
262:127180
59. Soundharrajan V, Sambandam B, Kim S et al (2020) The dominant role of Mn
2+ additive
on the electrochemical reaction in ZnMn 2 O 4 cathode for aqueous zinc-ion batteries. Energy
Storage Mater. https://doi.org/10.1016/j.ensm.2019.12.021
60. Li H, Han C, Huang Y et al (2018) An extremely safe and wearable solid-state zinc ion battery based on a hierarchical structured polymer electrolyte. Energy Environ Sci 11:941–951
61. Zeng Y, Zhang Y, Meng Y et al (2017) Achieving ultrahigh energy density and long durability
in a flexible rechargeable quasi-solid-state Zn–MnO 2 battery. Adv Mater 29:1700274
62. Kundu D, Adams D, Duffort V et al (2016) A high-capacity and long-life aqueous rechargeable zinc battery using a metal oxide intercalation cathode. Nat Energy 1:16119
63. Alfarugi MH, Mathew V, Song J et al (2017) Electrochemical zinc intercalation in lithium
vanadium oxide: a high-capacity zinc-ion battery cathode. Chem Mater 29:1684–1694
64. Jo JH, Sun YK, Myung ST (2017) Hollandite-type Al-doped VO 1.52 (OH) 0.77 as a zinc ion
insertion host material. J Mater Chem A 5:8367–8375
65. Xia C, Guo J, Lei Y (2018) Rechargeable aqueous zinc-ion battery based on porous framework zinc pyrovanadate intercalation cathode. Adv Mater 30:1705580
J. Kim et al.
