52
Overall, it is obvious that research on ZIB technology, aided by good engineering, can demonstrate better performance, economic and environmental advantages
than the present-day Pb-acid and Ni-Cd batteries. The ZIBs clearly hold the benefit
to serve the demands for green and sustainable energy storage in modern society.
Acknowledgements This work was supported by the National Research Foundation of Korea
(NRF) grant funded by the Korea government (MIST) No.2020R1A2C3012415 and 2018R1A5A
1025224.
References
1. Etacheri V, Marom R, Elazari R et al (2011) Challenges in the development of advanced
Li-ion batteries: a review. Energy Environ Sci 4:3243–3262
2. Fergus JW (2010) Developments in cathode materials for lithium ion batteries. J Power
Sources 195:939–954
3. Dunn B, Kamath H, Tarascon JM (2011) Electrical energy storage for the grid: a battery of
choices. Science 334:928–935
4. Wang Q, Ping P, Zhao X et al (2012) Thermal runaway caused fire and explosion of lithium
ion battery. J Power Sources 208:210–224
5. Wen J, Yu Y, Chen C (2012) A review on lithium-ion batteries safety issues: existing problems
and possible solutions. Mater Express 2:197–212
6. Wang RY, Wessells CD, Huggins RA et al (2013) Highly reversible open framework
nanoscale electrodes for divalent ion batteries. Nano Lett 13:5748–5752
7. Liu S, Pan GL, Li GR et al (2015) Copper hexacyanoferrate nanoparticles as cathode material
for aqueous Al-ion batteries. J Mater Chem A 3:959–962
8. Xu C, Li B, Du H et al (2012) Energetic zinc ion chemistry: the rechargeable zinc ion battery.
Angew Chem Int Ed 51:933–935
9. Shen Y, Kordesch K (2000) The mechanism of capacity fade of rechargeable alkaline manganese dioxide zinc cells. J Power Sources 87:162–166
10. Ghaemi M, Amrollahi R, Ataherian F et al (2003) New advances on bipolar rechargeable
alkaline manganese dioxide−zinc batteries. J Power Sources 117:233–241
11. Kordesch K, Marsal PA, Urry LF (1957) Dry cell. US Patent 2960558A
12. Vosburgh WC (1959) The manganese dioxide electrode. J Electrochem Soc 106:839–845
13. Kozawa A, Yeager JF (1965) The cathodic reduction mechanism of electrolytic manganese
dioxide in alkaline electrolyte. J Electrochem Soc 112:959–963
14. Vetter KJ (1963) A general thermodynamic theory of the potential of passive electrodes and
its influence on passive corrosion. J Electrochem Soc 110:597–605
15. Gautam GY, Joshua WG, Damon ET et al (2017) Regenerable cu-intercalated MnO 2 layered
cathode for highly cyclable energy dense batteries. Nat Commun 8:14424
16. Gautam GY, Xia W, Jinchao H et al (2017) A conversion-based highly energy dense Cu
2+
intercalated bi-birnessite/Zn alkaline battery. J Mater Chem A 5:15845–15854
17. Shoji T, Yamamoto T (1993) Charging and discharging behavior of zinc—manganese dioxide
galvanic cells using zinc sulfate as electrolyte. J Electroanal Chem 362:153–157
18. Kim SH, Oh SM (1998) Degradation mechanism of layered MnO 2 cathodes in Zn/ZnSO 4 /
MnO 2 rechargeable cells. J Power Sources 72:150–158
19. Mainar AR, Iruin E, Colmenares LC et al (2018) An overview of progress in electrolytes
for secondary zinc-air batteries and other storage systems based on zinc. J Energy Storage
15:304–328
J. Kim et al.
Overall, it is obvious that research on ZIB technology, aided by good engineering, can demonstrate better performance, economic and environmental advantages
than the present-day Pb-acid and Ni-Cd batteries. The ZIBs clearly hold the benefit
to serve the demands for green and sustainable energy storage in modern society.
Acknowledgements This work was supported by the National Research Foundation of Korea
(NRF) grant funded by the Korea government (MIST) No.2020R1A2C3012415 and 2018R1A5A
1025224.
References
1. Etacheri V, Marom R, Elazari R et al (2011) Challenges in the development of advanced
Li-ion batteries: a review. Energy Environ Sci 4:3243–3262
2. Fergus JW (2010) Developments in cathode materials for lithium ion batteries. J Power
Sources 195:939–954
3. Dunn B, Kamath H, Tarascon JM (2011) Electrical energy storage for the grid: a battery of
choices. Science 334:928–935
4. Wang Q, Ping P, Zhao X et al (2012) Thermal runaway caused fire and explosion of lithium
ion battery. J Power Sources 208:210–224
5. Wen J, Yu Y, Chen C (2012) A review on lithium-ion batteries safety issues: existing problems
and possible solutions. Mater Express 2:197–212
6. Wang RY, Wessells CD, Huggins RA et al (2013) Highly reversible open framework
nanoscale electrodes for divalent ion batteries. Nano Lett 13:5748–5752
7. Liu S, Pan GL, Li GR et al (2015) Copper hexacyanoferrate nanoparticles as cathode material
for aqueous Al-ion batteries. J Mater Chem A 3:959–962
8. Xu C, Li B, Du H et al (2012) Energetic zinc ion chemistry: the rechargeable zinc ion battery.
Angew Chem Int Ed 51:933–935
9. Shen Y, Kordesch K (2000) The mechanism of capacity fade of rechargeable alkaline manganese dioxide zinc cells. J Power Sources 87:162–166
10. Ghaemi M, Amrollahi R, Ataherian F et al (2003) New advances on bipolar rechargeable
alkaline manganese dioxide−zinc batteries. J Power Sources 117:233–241
11. Kordesch K, Marsal PA, Urry LF (1957) Dry cell. US Patent 2960558A
12. Vosburgh WC (1959) The manganese dioxide electrode. J Electrochem Soc 106:839–845
13. Kozawa A, Yeager JF (1965) The cathodic reduction mechanism of electrolytic manganese
dioxide in alkaline electrolyte. J Electrochem Soc 112:959–963
14. Vetter KJ (1963) A general thermodynamic theory of the potential of passive electrodes and
its influence on passive corrosion. J Electrochem Soc 110:597–605
15. Gautam GY, Joshua WG, Damon ET et al (2017) Regenerable cu-intercalated MnO 2 layered
cathode for highly cyclable energy dense batteries. Nat Commun 8:14424
16. Gautam GY, Xia W, Jinchao H et al (2017) A conversion-based highly energy dense Cu
2+
intercalated bi-birnessite/Zn alkaline battery. J Mater Chem A 5:15845–15854
17. Shoji T, Yamamoto T (1993) Charging and discharging behavior of zinc—manganese dioxide
galvanic cells using zinc sulfate as electrolyte. J Electroanal Chem 362:153–157
18. Kim SH, Oh SM (1998) Degradation mechanism of layered MnO 2 cathodes in Zn/ZnSO 4 /
MnO 2 rechargeable cells. J Power Sources 72:150–158
19. Mainar AR, Iruin E, Colmenares LC et al (2018) An overview of progress in electrolytes
for secondary zinc-air batteries and other storage systems based on zinc. J Energy Storage
15:304–328
J. Kim et al.