24
62. Zhang Z, Yang Z, Huang J et al (2015) Enhancement of electrochemical performance with
Zn-Al-Bi layered hydrotalcites as anode material for Zn/Ni secondary battery. Electrochim
Acta. https://doi.org/10.1016/j.electacta.2014.12.145
63. Parker JF, Chervin CN, Nelson ES (2014) Wiring zinc in three dimensions re-writes battery performance—dendrite-free cycling. Energy Environ Sci. https://doi.org/10.1039/
c3ee43754j
64. Eisenberg M Alkaline galvanic cells, US Patent 5215836A
65. Phillips J, Mohanta S (2010) Electrolyte composition for nickel-zinc batteries, US Patent
7,550,230 16 April 2010
66. Wang YM, Wainwright G (1986) Formation and decomposition kinetic-studies of calcium
zincate in 20 w/o KOH. J Electrochem Soc 133:1869–1872. https://doi.org/10.1149/1.2109037
67. Ein-Eli Y, Auinat M, Starosvetsky D (2003) Electrochemical and surface studies of zinc in
alkaline solutions containing organic corrosion inhibitors. J Power Sources 114:330–337.
https://doi.org/10.1016/S0378-7753(02)00598-0
68. Frackowiak E, Kiciak M (1984) The influence of polyethylene glycol on some properties of
zinc electrodes. Electrochim Acta 29:1359–1363
69. Narty VK, Binder L, Kordesch K (1994) Identification of organic corrosion-inhibitors suitable for use in rechargeable alkaline zinc batteries. J Power Sources 52:217–222
70. Parker JF, Chervin CN, Pala IR, Machler M (2017) Rechargeable nickel–3D zinc batteries:
an energy-dense, safer alternative to lithium-ion. Science 356:415–418
71. Wang Z, Wu Z, Bramnik N, Mitra S (2013) Fabrication of high-performance flexible alkaline batteries by implementing multiwalled carbon nanotubes and copolymer separator. Adv
Mater 26:970–976. https://doi.org/10.1002/adma.201304020
72. Higashi S, Lee SW, Lee JS et al (2016) Avoiding short circuits from zinc metal dendrites
in anode by backside-plating configuration. Nat Commun 7:1–6. https://doi.org/10.1038/
ncomms11801
73. Einerhand R, Visscher W et al (1991) Zinc electrode shape change II. Process and mechanism. J Electrochem Soc 138:7
74. McBreen J (1972) Zinc electrode shape change in secondary cells. J Electrochem Soc. https://
doi.org/10.1149/1.2404060
75. Desai D, Turney DE, Anantharaman B et al (2014) Morphological evolution of nanocluster
aggregates and single crystals in alkaline zinc electrodeposition. J Phys Chem C 118:8656–
8666. https://doi.org/10.1021/jp411104a
76. Gong M, Li Y, Zhang H et al (2014) Ultrafast high-capacity NiZn battery with NiAlColayered double hydroxide. Energy Environ Sci 7:2025. https://doi.org/10.1039/c4ee00317a
77. Liu L, Yang Z (2018) The composite of ZnSn(OH)6 and Zn–Al layered double hydroxides
used as negative material for zinc–nickel alkaline batteries. Ionics 24:1–11. https://doi.
org/10.1007/s11581-018-2446-1
78. Long J, Yang Z, Zeng X, Huang J (2016) A new class of nanocomposites of Zn–Al–Bi layered double oxides: large reversible capacity and better cycle performance for alkaline secondary batteries. RSC Adv 6:92896–92904. https://doi.org/10.1039/C6RA18164C
79. Yang H, Yang Z, Wen X, Liu L (2017) The in-situ growth of zinc-aluminum layered double
hydroxides on graphene and its application as anode active materials for Zn-Ni secondary
battery. Electrochim Acta 252:507–515. https://doi.org/10.1016/j.electacta.2017.09.014
80. Wei X, Desai D, Yadav GG et al (2016) Impact of anode substrates on electrodeposited zinc
over cycling in zinc-anode rechargeable alkaline batteries. Electrochim Acta 212:603–613.
https://doi.org/10.1016/j.electacta.2016.07.041
81. Gregory DP, Jones PC, Redfearn DP (1972) The corrosion of zinc anodes in aqueous alkaline
electrolytes. J Electrochem Soc 119(10):1288–1293
82. Shivkumar R, Kalaignan GP, Vasudevan T (1998) Studies with porous zinc electrodes
with additives for secondary alkaline batteries. J Power Sources 75:90–100. https://doi.
org/10.1016/S0378-7753(98)00096-2
D. E. Turney et al.
62. Zhang Z, Yang Z, Huang J et al (2015) Enhancement of electrochemical performance with
Zn-Al-Bi layered hydrotalcites as anode material for Zn/Ni secondary battery. Electrochim
Acta. https://doi.org/10.1016/j.electacta.2014.12.145
63. Parker JF, Chervin CN, Nelson ES (2014) Wiring zinc in three dimensions re-writes battery performance—dendrite-free cycling. Energy Environ Sci. https://doi.org/10.1039/
c3ee43754j
64. Eisenberg M Alkaline galvanic cells, US Patent 5215836A
65. Phillips J, Mohanta S (2010) Electrolyte composition for nickel-zinc batteries, US Patent
7,550,230 16 April 2010
66. Wang YM, Wainwright G (1986) Formation and decomposition kinetic-studies of calcium
zincate in 20 w/o KOH. J Electrochem Soc 133:1869–1872. https://doi.org/10.1149/1.2109037
67. Ein-Eli Y, Auinat M, Starosvetsky D (2003) Electrochemical and surface studies of zinc in
alkaline solutions containing organic corrosion inhibitors. J Power Sources 114:330–337.
https://doi.org/10.1016/S0378-7753(02)00598-0
68. Frackowiak E, Kiciak M (1984) The influence of polyethylene glycol on some properties of
zinc electrodes. Electrochim Acta 29:1359–1363
69. Narty VK, Binder L, Kordesch K (1994) Identification of organic corrosion-inhibitors suitable for use in rechargeable alkaline zinc batteries. J Power Sources 52:217–222
70. Parker JF, Chervin CN, Pala IR, Machler M (2017) Rechargeable nickel–3D zinc batteries:
an energy-dense, safer alternative to lithium-ion. Science 356:415–418
71. Wang Z, Wu Z, Bramnik N, Mitra S (2013) Fabrication of high-performance flexible alkaline batteries by implementing multiwalled carbon nanotubes and copolymer separator. Adv
Mater 26:970–976. https://doi.org/10.1002/adma.201304020
72. Higashi S, Lee SW, Lee JS et al (2016) Avoiding short circuits from zinc metal dendrites
in anode by backside-plating configuration. Nat Commun 7:1–6. https://doi.org/10.1038/
ncomms11801
73. Einerhand R, Visscher W et al (1991) Zinc electrode shape change II. Process and mechanism. J Electrochem Soc 138:7
74. McBreen J (1972) Zinc electrode shape change in secondary cells. J Electrochem Soc. https://
doi.org/10.1149/1.2404060
75. Desai D, Turney DE, Anantharaman B et al (2014) Morphological evolution of nanocluster
aggregates and single crystals in alkaline zinc electrodeposition. J Phys Chem C 118:8656–
8666. https://doi.org/10.1021/jp411104a
76. Gong M, Li Y, Zhang H et al (2014) Ultrafast high-capacity NiZn battery with NiAlColayered double hydroxide. Energy Environ Sci 7:2025. https://doi.org/10.1039/c4ee00317a
77. Liu L, Yang Z (2018) The composite of ZnSn(OH)6 and Zn–Al layered double hydroxides
used as negative material for zinc–nickel alkaline batteries. Ionics 24:1–11. https://doi.
org/10.1007/s11581-018-2446-1
78. Long J, Yang Z, Zeng X, Huang J (2016) A new class of nanocomposites of Zn–Al–Bi layered double oxides: large reversible capacity and better cycle performance for alkaline secondary batteries. RSC Adv 6:92896–92904. https://doi.org/10.1039/C6RA18164C
79. Yang H, Yang Z, Wen X, Liu L (2017) The in-situ growth of zinc-aluminum layered double
hydroxides on graphene and its application as anode active materials for Zn-Ni secondary
battery. Electrochim Acta 252:507–515. https://doi.org/10.1016/j.electacta.2017.09.014
80. Wei X, Desai D, Yadav GG et al (2016) Impact of anode substrates on electrodeposited zinc
over cycling in zinc-anode rechargeable alkaline batteries. Electrochim Acta 212:603–613.
https://doi.org/10.1016/j.electacta.2016.07.041
81. Gregory DP, Jones PC, Redfearn DP (1972) The corrosion of zinc anodes in aqueous alkaline
electrolytes. J Electrochem Soc 119(10):1288–1293
82. Shivkumar R, Kalaignan GP, Vasudevan T (1998) Studies with porous zinc electrodes
with additives for secondary alkaline batteries. J Power Sources 75:90–100. https://doi.
org/10.1016/S0378-7753(98)00096-2
D. E. Turney et al.
