23
40. Arora P, Zhang ZJ (2004) Battery separators. Chem Rev 104:4419–4462. https://doi.
org/10.1021/cr020738u
41. Yadav GG, Wei X, Huang J et al (2018) Accessing the second electron capacity of MnO2 by
exploring complexation and intercalation reactions in energy dense alkaline batteries. Int J
Hydrogen Energ 43:8480–8487. https://doi.org/10.1016/j.ijhydene.2018.03.061
42. Yao YF, Gupta N, Wroblowa HS (1987) Rechargeable manganese oxide electrodes: Part I
Chemically modified materials. J Electroanal Chem Interfac Electrochem 223:107–117
43. Dzieciuch MA, Gupta N, Wroblowa HS (1988) Rechargeable cells with modified MnO2
cathodes. J Electrochem Soc 135:2415–2418. https://doi.org/10.1149/1.2095349
44. Yadav GG, Turney D, Huang J, Wei X, Banerjee S (2019) Breaking the 2 V barrier in aqueous zinc chemistry: creating 2.45 and 2.8 V MnO 2–Zn aqueous batteries. ACS Energy Lett
4:2144–2146
45. Yadav GG, Cho J, Turney D et al (2019) Going beyond intercalation capacity of aqueous batteries by exploiting conversion reactions of Mn and Zn electrodes for energy-dense applications. Adv Energy Mater 9:1902270. https://doi.org/10.1021/acsenergylett.9b01643
46. Biegler C, Deutscher RL, Fletcher S, Hua S (1983) Accelerated testing of additives in zinc
plates of nickel zinc cells.
47. Sato Y, Kanda M, Niki H et al (1983) Long life sealed nickel zinc cell using a new separator.
J Power Sources 9:147–159. https://doi.org/10.1016/0378-7753(83)80029-9
48. Nichols JT, McLarnon FR, Cairns EJ (1985) Zinc electrode cycle-life performance in alkaline electrolytes having reduced zinc species solubility. Chem Eng Commun 37:355–379.
https://doi.org/10.1080/00986448508911290
49. Gagnon EG (1986) Effects of KOH concentration on the shape change and cycle life of Zn/
NIOOH cells. J Electrochem Soc 133:1989–1995. https://doi.org/10.1149/1.2108327
50. Jones RA (1982) Nickel-Zinc Cell, US Patent 4,358,517, US Patent and Trade Office
51. Gagnon EG, Wang YM (1987) Pasted-rolled zinc electrodes containing calcium
hydroxide for use in Zn/NIOOH cells. J Electrochem Soc 134:2091–2096. https://doi.
org/10.1149/1.2100830
52. Charkey A (1995) Sealed zinc secondary battery and zinc electrode therefor. US Patent
5,460,899, 24 Oct 1995
53. Müller S, Holzer F, Haas O (1998) Optimized zinc electrode for the rechargeable zinc–air
battery.
54. Adler TC, McLarnon FR, Cairns EJ (1998) Investigations of a new family of alkaline-fluoride-carbonate electrolytes for zinc/nickel oxide cells. Ind Eng Chem Res {37}:{3237–
3241}. doi: {https://doi.org/10.1021/ie9800694}
55. Charkey A (1999) Calcium zincate electrode for alkaline batteries and method of making
same, US Patent 5863676, US Patent Office.
56. Zhang C, Wang JM, Zhang L, Zhang JQ (2001) Study of the performance of secondary alkaline pasted zinc electrodes. J Appl Electrochem 31:1049–1054
57. Wang R, Yang Z, Yang B et al (2014) Superior cycle stability and high rate capability of
Zn–Al–in-hydrotalcite as negative electrode materials for Ni–Zn secondary batteries. J Power
Sources. https://doi.org/10.1016/j.jpowsour.2013.11.071
58. Ito Y, Nyce M, Plivelich R et al (2011) Zinc morphology in zinc-nickel flow assisted batteries
and impact on performance. J Power Sources 196:2340–2345
59. Gan W, Zhou D, Zhao J, Zhou L (2015) Stable zinc anodes by in situ polymerization of conducting polymer to conformally coat zinc oxide particles. J Appl Electrochem 45:913–919.
https://doi.org/10.1007/s10800-015-0833-0
60. Chamoun M, Hertzberg BJ, Gupta T et al (2015) Hyper-dendritic nanoporous zinc foam
anodes. NPG Asia Materials 7:e178–e178. https://doi.org/10.1038/am.2015.32
61. Davies G, Hsieh AG, Hultmark M et al (2016) Utilization of hyper-dendritic zinc during high
rate discharge in alkaline electrolytes. J Electrochem Soc 163:A1340–A1347. https://doi.
org/10.1149/2.0891607jes
Aqueous Mn-Zn and Ni-Zn Batteries for Sustainable Energy Storage
40. Arora P, Zhang ZJ (2004) Battery separators. Chem Rev 104:4419–4462. https://doi.
org/10.1021/cr020738u
41. Yadav GG, Wei X, Huang J et al (2018) Accessing the second electron capacity of MnO2 by
exploring complexation and intercalation reactions in energy dense alkaline batteries. Int J
Hydrogen Energ 43:8480–8487. https://doi.org/10.1016/j.ijhydene.2018.03.061
42. Yao YF, Gupta N, Wroblowa HS (1987) Rechargeable manganese oxide electrodes: Part I
Chemically modified materials. J Electroanal Chem Interfac Electrochem 223:107–117
43. Dzieciuch MA, Gupta N, Wroblowa HS (1988) Rechargeable cells with modified MnO2
cathodes. J Electrochem Soc 135:2415–2418. https://doi.org/10.1149/1.2095349
44. Yadav GG, Turney D, Huang J, Wei X, Banerjee S (2019) Breaking the 2 V barrier in aqueous zinc chemistry: creating 2.45 and 2.8 V MnO 2–Zn aqueous batteries. ACS Energy Lett
4:2144–2146
45. Yadav GG, Cho J, Turney D et al (2019) Going beyond intercalation capacity of aqueous batteries by exploiting conversion reactions of Mn and Zn electrodes for energy-dense applications. Adv Energy Mater 9:1902270. https://doi.org/10.1021/acsenergylett.9b01643
46. Biegler C, Deutscher RL, Fletcher S, Hua S (1983) Accelerated testing of additives in zinc
plates of nickel zinc cells.
47. Sato Y, Kanda M, Niki H et al (1983) Long life sealed nickel zinc cell using a new separator.
J Power Sources 9:147–159. https://doi.org/10.1016/0378-7753(83)80029-9
48. Nichols JT, McLarnon FR, Cairns EJ (1985) Zinc electrode cycle-life performance in alkaline electrolytes having reduced zinc species solubility. Chem Eng Commun 37:355–379.
https://doi.org/10.1080/00986448508911290
49. Gagnon EG (1986) Effects of KOH concentration on the shape change and cycle life of Zn/
NIOOH cells. J Electrochem Soc 133:1989–1995. https://doi.org/10.1149/1.2108327
50. Jones RA (1982) Nickel-Zinc Cell, US Patent 4,358,517, US Patent and Trade Office
51. Gagnon EG, Wang YM (1987) Pasted-rolled zinc electrodes containing calcium
hydroxide for use in Zn/NIOOH cells. J Electrochem Soc 134:2091–2096. https://doi.
org/10.1149/1.2100830
52. Charkey A (1995) Sealed zinc secondary battery and zinc electrode therefor. US Patent
5,460,899, 24 Oct 1995
53. Müller S, Holzer F, Haas O (1998) Optimized zinc electrode for the rechargeable zinc–air
battery.
54. Adler TC, McLarnon FR, Cairns EJ (1998) Investigations of a new family of alkaline-fluoride-carbonate electrolytes for zinc/nickel oxide cells. Ind Eng Chem Res {37}:{3237–
3241}. doi: {https://doi.org/10.1021/ie9800694}
55. Charkey A (1999) Calcium zincate electrode for alkaline batteries and method of making
same, US Patent 5863676, US Patent Office.
56. Zhang C, Wang JM, Zhang L, Zhang JQ (2001) Study of the performance of secondary alkaline pasted zinc electrodes. J Appl Electrochem 31:1049–1054
57. Wang R, Yang Z, Yang B et al (2014) Superior cycle stability and high rate capability of
Zn–Al–in-hydrotalcite as negative electrode materials for Ni–Zn secondary batteries. J Power
Sources. https://doi.org/10.1016/j.jpowsour.2013.11.071
58. Ito Y, Nyce M, Plivelich R et al (2011) Zinc morphology in zinc-nickel flow assisted batteries
and impact on performance. J Power Sources 196:2340–2345
59. Gan W, Zhou D, Zhao J, Zhou L (2015) Stable zinc anodes by in situ polymerization of conducting polymer to conformally coat zinc oxide particles. J Appl Electrochem 45:913–919.
https://doi.org/10.1007/s10800-015-0833-0
60. Chamoun M, Hertzberg BJ, Gupta T et al (2015) Hyper-dendritic nanoporous zinc foam
anodes. NPG Asia Materials 7:e178–e178. https://doi.org/10.1038/am.2015.32
61. Davies G, Hsieh AG, Hultmark M et al (2016) Utilization of hyper-dendritic zinc during high
rate discharge in alkaline electrolytes. J Electrochem Soc 163:A1340–A1347. https://doi.
org/10.1149/2.0891607jes
Aqueous Mn-Zn and Ni-Zn Batteries for Sustainable Energy Storage