101
Zn
1,3,5-benzenetriPA
inh.
3.5 × 10
−5
, 0.17 eV, 298 K 98%
RH,
Interlayer lined with water
[71]
Zn
3,3′,4,4′-biphenyltetracarboxylate
Guest
8.4 × 10
−3
, 0.25 eV, 300 K, 98%
RH
[(CH
3 )
2 NH
2 ]
+
guests
[72]
Zn
Triazole
inh.
4.6 × 10
−3
, 0.53 eV, 423 K, anh.
Nonporous, encapsulate H
+
carriers in defect sites
[73]
Zn
Benzimidazole, and orthophosphate
inh.
1.3 × 10
−3
, 0.40 eV, 393 K, anh.
Templated
[5]
Zn
Oxalate
inh.
1 × 10
−4
, 0.130 eV, anh.
4.2 × 10
−2
98% RH, 423 K
Works in hydrous and anhydrous
conditions
[74]
Zn
1H-1,2,3-triazole, BDC
Guest
2.65 × 10
−4
, 0.18 eV, up to 393 K,
anh.
SCSC, large temp. range
[10]
Zr
NH
4
+
, phosphate
inh.
1.45 × 10
−3
, 0.26 eV, 453 K, anh.
Anionic framework
[75]
Zr
NH
4
+
, phosphate
inh.
1.45 × 10
−2
, 0.19 eV, 363 K, 95%
RH, 1.1 × 10
−5
503 K, anh.
High temp range
[76]
Zr/Li
(CH
3 )
2 NH
2, oxalate
inh.
3.9 × 10
−5
, 0.64 eV, 67% RH,
290 K
Insulator-conductor transition,
dense
[77]
Zr
1H-pyrazole, 1H-1,2,4-triazole
PSM
>10
−1
, 0.10–0.28 eV, 358 K, 90%
RH
Superprotonic
[78]
Hydroxide conduction
Cr
BTC (MIL-100)
PSM
6.0 × 10
−5
, 0.38 eV, R.T. 99.9%
RH,
Anionic stripping
[79]
Fe
1-amino-BDC
PSM
0.145, 353 K, 100% RH
Anionic stripping
[80]
Ni
1,4-bis(pyrazol-4-yl)benzene-4-X with
X = H, OH, NH
2
PSM
1.16 × 10
−2
, 0.20 eV, 313 K, 100%
RH
PSM with KOH
[81]
Ni
2-pyrimidinecarboxylate
inh.
8 × 10
−5
, 0.19 eV, 300 K, 99%RH
In situ incorporated OH
−
anions
[82]
Zn
2-meim(ZIF-8)
Guest
2.3 × 10
−8
, 0.70 eV, 298 K, 98%
RH
Salt inclusion, first MOF for
OH
−
cond.
[83]
Zn
2-meim(ZIF-8)
Guest
N/A
Used for OH
−
exchange
[84]
Zn
2-meim(ZIF-8)
Guest
9.8 × 10
−4
, 333 K, 33%RH
Ionic liquid, low RH
[85]
Type of conductivity: Guest (extrinsic), PSM (extrinsic), inh.
= native framework via included functionalities (inherent or intrinsic)
RH
= relative humidity, anh.
= anhydrous, bipy
= bipyridyl, terephthalic acid = BDC
= 1,4-benzene dicarboxylic acid, meim
= methylimidazole, BTC
= 1,3,5
benzenetricarboxylic acid, PA
= phosphonic acid, adp
= adipamide, SCSC
= single-crystal-to-single-crystal transition
Polymer Nanocomposites for Ion Transport
Zn
1,3,5-benzenetriPA
inh.
3.5 × 10
−5
, 0.17 eV, 298 K 98%
RH,
Interlayer lined with water
[71]
Zn
3,3′,4,4′-biphenyltetracarboxylate
Guest
8.4 × 10
−3
, 0.25 eV, 300 K, 98%
RH
[(CH
3 )
2 NH
2 ]
+
guests
[72]
Zn
Triazole
inh.
4.6 × 10
−3
, 0.53 eV, 423 K, anh.
Nonporous, encapsulate H
+
carriers in defect sites
[73]
Zn
Benzimidazole, and orthophosphate
inh.
1.3 × 10
−3
, 0.40 eV, 393 K, anh.
Templated
[5]
Zn
Oxalate
inh.
1 × 10
−4
, 0.130 eV, anh.
4.2 × 10
−2
98% RH, 423 K
Works in hydrous and anhydrous
conditions
[74]
Zn
1H-1,2,3-triazole, BDC
Guest
2.65 × 10
−4
, 0.18 eV, up to 393 K,
anh.
SCSC, large temp. range
[10]
Zr
NH
4
+
, phosphate
inh.
1.45 × 10
−3
, 0.26 eV, 453 K, anh.
Anionic framework
[75]
Zr
NH
4
+
, phosphate
inh.
1.45 × 10
−2
, 0.19 eV, 363 K, 95%
RH, 1.1 × 10
−5
503 K, anh.
High temp range
[76]
Zr/Li
(CH
3 )
2 NH
2, oxalate
inh.
3.9 × 10
−5
, 0.64 eV, 67% RH,
290 K
Insulator-conductor transition,
dense
[77]
Zr
1H-pyrazole, 1H-1,2,4-triazole
PSM
>10
−1
, 0.10–0.28 eV, 358 K, 90%
RH
Superprotonic
[78]
Hydroxide conduction
Cr
BTC (MIL-100)
PSM
6.0 × 10
−5
, 0.38 eV, R.T. 99.9%
RH,
Anionic stripping
[79]
Fe
1-amino-BDC
PSM
0.145, 353 K, 100% RH
Anionic stripping
[80]
Ni
1,4-bis(pyrazol-4-yl)benzene-4-X with
X = H, OH, NH
2
PSM
1.16 × 10
−2
, 0.20 eV, 313 K, 100%
RH
PSM with KOH
[81]
Ni
2-pyrimidinecarboxylate
inh.
8 × 10
−5
, 0.19 eV, 300 K, 99%RH
In situ incorporated OH
−
anions
[82]
Zn
2-meim(ZIF-8)
Guest
2.3 × 10
−8
, 0.70 eV, 298 K, 98%
RH
Salt inclusion, first MOF for
OH
−
cond.
[83]
Zn
2-meim(ZIF-8)
Guest
N/A
Used for OH
−
exchange
[84]
Zn
2-meim(ZIF-8)
Guest
9.8 × 10
−4
, 333 K, 33%RH
Ionic liquid, low RH
[85]
Type of conductivity: Guest (extrinsic), PSM (extrinsic), inh.
= native framework via included functionalities (inherent or intrinsic)
RH
= relative humidity, anh.
= anhydrous, bipy
= bipyridyl, terephthalic acid = BDC
= 1,4-benzene dicarboxylic acid, meim
= methylimidazole, BTC
= 1,3,5
benzenetricarboxylic acid, PA
= phosphonic acid, adp
= adipamide, SCSC
= single-crystal-to-single-crystal transition
Polymer Nanocomposites for Ion Transport