100
Fe
Oxalate
inh.
1.3 × 10
−3
, 0.37 eV, R.T., 98%RH
1-D, no acid groups
[53]
Fe/Cr; Mn/Cr NR
3 CH
2 COOH, R = methyl, ethyl, or
n-butyl; oxalate
inh.
∼10
−4
S cm
−1
, R.T., 65% RH
Low humidity
[54]
Gd, Dy
Mucic acid, oxalic acid
inh.
4.7 × 10
−4
S cm
−1
, 0.70 eV, >348 K,
95% RH
Channel-assisted, magnetic
[55]
In
5-sulfoisophthalate
inh.
>10
−3
, 0.31 eV, 298 K, 40% RH
Anionic, single crystal
[56]
La
[Ru(4,4′-dcbpy)
3 ]
4−
inh.
5.5 × 10
−7
, 313 K, 95% RH
Visualization via luminescence
[57]
La
Benzene-1,2,4,5-tetramethylenePA
inh.
4 × 10
−3
, 0.32 eV, 333 K, 98% RH Utilizes phosphonic acid group,
resists swelling
[58]
La,Ce, Pr, Nd,
Sm, Eu, Gd
1,2,4,5-tetrakis(phosphonomethyl)benzene
inh.
6 × 10
−3
, 0.17 eV, 358 K, 95% RH Particle size dependence:
Bigger = better conductivity
[59]
Mg, Sr
2,2′,6,6′-tetracarboxybiphenyl
inh.
2.7 × 10
−4
, 0.47 eV, 363 K, 98%
RH
Novel water aggregates
[60]
Mn
2,5-dihydroxy-1,4-benzoquinone
inh.
4 × 10
−5
, 0.26 eV, 298 K, 95%RH
Water-induced structure change,
reversible
[61]
Mn/Cr
Oxalate
Guest
1.1 × 10
−3
, 0.23 eV, R.T., 96% RH Ferromagnetic
[62]
Na
Tris(hydrogen phosphonate)
PSM
2.1 × 10
−2
, 0.21 eV, 358 K, 90%
RH
Isomorphous ligand replacement
[63]
Na
2,4,6-trihydroxy-1,3,5-benzenetrisulfonate
Guest
5 × 10
−4
, 0.34 eV, 423 K, Anh.
Triazole guests
[64]
Ni
2,5-dioxido-1,4-BDC
PSM
2.2 × 10
−2
, 0.12–0.20 eV, 353 K,
95%RH
pH dependence, soaked in
sulfuric acid
[65]
Zn
3-methyl-2-(pyridin-4-ylmethylamino)
butanoic acid]
inh.
4.45 × 10
−5
, 0.34 eV, 304 K, 98%
RH
Water chains confined in
hydrophobic pores
[66]
Zn
2,5-dioxidoBDC
PSM
4.3 × 10
−9
, 419 K, anh.
Post-grafted histamine
[67]
Zn
1,2,4-triazole, orthophosphates
inh.
>10
−4
, 0.60 eV, 423 K, anh.
Anisotropic conductivity
[68]
Zn
Bis(4-carboxyphenyl)imidazolium
inh.
2.3 × 10
−3
, 0.22 eV, R.T. 95% RH, Low conductivity until fifth water
introduced
[69]
Zn
adp, oxalate
PSM,
guest
10
−2
, 0.63 eV, R.T., 98%RH
Rational design
[70]
Table 1 (continued)
Metal
Organic linker
Type
Conductivity (S cm
−1
)/E
a /Temp/RH Comment
Reference
C. A. Bauer
Fe
Oxalate
inh.
1.3 × 10
−3
, 0.37 eV, R.T., 98%RH
1-D, no acid groups
[53]
Fe/Cr; Mn/Cr NR
3 CH
2 COOH, R = methyl, ethyl, or
n-butyl; oxalate
inh.
∼10
−4
S cm
−1
, R.T., 65% RH
Low humidity
[54]
Gd, Dy
Mucic acid, oxalic acid
inh.
4.7 × 10
−4
S cm
−1
, 0.70 eV, >348 K,
95% RH
Channel-assisted, magnetic
[55]
In
5-sulfoisophthalate
inh.
>10
−3
, 0.31 eV, 298 K, 40% RH
Anionic, single crystal
[56]
La
[Ru(4,4′-dcbpy)
3 ]
4−
inh.
5.5 × 10
−7
, 313 K, 95% RH
Visualization via luminescence
[57]
La
Benzene-1,2,4,5-tetramethylenePA
inh.
4 × 10
−3
, 0.32 eV, 333 K, 98% RH Utilizes phosphonic acid group,
resists swelling
[58]
La,Ce, Pr, Nd,
Sm, Eu, Gd
1,2,4,5-tetrakis(phosphonomethyl)benzene
inh.
6 × 10
−3
, 0.17 eV, 358 K, 95% RH Particle size dependence:
Bigger = better conductivity
[59]
Mg, Sr
2,2′,6,6′-tetracarboxybiphenyl
inh.
2.7 × 10
−4
, 0.47 eV, 363 K, 98%
RH
Novel water aggregates
[60]
Mn
2,5-dihydroxy-1,4-benzoquinone
inh.
4 × 10
−5
, 0.26 eV, 298 K, 95%RH
Water-induced structure change,
reversible
[61]
Mn/Cr
Oxalate
Guest
1.1 × 10
−3
, 0.23 eV, R.T., 96% RH Ferromagnetic
[62]
Na
Tris(hydrogen phosphonate)
PSM
2.1 × 10
−2
, 0.21 eV, 358 K, 90%
RH
Isomorphous ligand replacement
[63]
Na
2,4,6-trihydroxy-1,3,5-benzenetrisulfonate
Guest
5 × 10
−4
, 0.34 eV, 423 K, Anh.
Triazole guests
[64]
Ni
2,5-dioxido-1,4-BDC
PSM
2.2 × 10
−2
, 0.12–0.20 eV, 353 K,
95%RH
pH dependence, soaked in
sulfuric acid
[65]
Zn
3-methyl-2-(pyridin-4-ylmethylamino)
butanoic acid]
inh.
4.45 × 10
−5
, 0.34 eV, 304 K, 98%
RH
Water chains confined in
hydrophobic pores
[66]
Zn
2,5-dioxidoBDC
PSM
4.3 × 10
−9
, 419 K, anh.
Post-grafted histamine
[67]
Zn
1,2,4-triazole, orthophosphates
inh.
>10
−4
, 0.60 eV, 423 K, anh.
Anisotropic conductivity
[68]
Zn
Bis(4-carboxyphenyl)imidazolium
inh.
2.3 × 10
−3
, 0.22 eV, R.T. 95% RH, Low conductivity until fifth water
introduced
[69]
Zn
adp, oxalate
PSM,
guest
10
−2
, 0.63 eV, R.T., 98%RH
Rational design
[70]
Table 1 (continued)
Metal
Organic linker
Type
Conductivity (S cm
−1
)/E
a /Temp/RH Comment
Reference
C. A. Bauer