6.5 Copper
113
(a)
(b)
Fig. 6.9 PES profiles of size-resolved a valance DOS polarization and b 2p DOS entrapment of
Cu clusters. Reprinted with permission from [63, 64]. Copyright 1990 American Physical Society.
Copyright 2006 Elsevier
6.5.3 BOLS-TB Formulation and Derivatives
The BOLS-TB formulation extracts bonding and electronic information from these
nice sets of data. The linearization of the size dependent APECS peaks of Cu/HOPG
gives the slope B ν and the interception that corresponds to the E 2p (∞) = 932.7 eV
[69]. The slope corresponds to m = 1 for the Cu spherical dot (τ = 3). Fitting to the
E L (K), the α
(K), the E M (K), and the E K (K) curves, one can obtain the responsive
E ν (0) and E ν (∞) values for the Cu/HOPG clusters. Figure 6.11 presents the fitting
to the size dependent APECS lines.
Table 6.3 presents information derived from the formulation of observations. The
atomic 2p level energy E 2p (0) = 931.0 eV and its bulk shift 2p (∞) = 1.70 eV.
113
(a)
(b)
Fig. 6.9 PES profiles of size-resolved a valance DOS polarization and b 2p DOS entrapment of
Cu clusters. Reprinted with permission from [63, 64]. Copyright 1990 American Physical Society.
Copyright 2006 Elsevier
6.5.3 BOLS-TB Formulation and Derivatives
The BOLS-TB formulation extracts bonding and electronic information from these
nice sets of data. The linearization of the size dependent APECS peaks of Cu/HOPG
gives the slope B ν and the interception that corresponds to the E 2p (∞) = 932.7 eV
[69]. The slope corresponds to m = 1 for the Cu spherical dot (τ = 3). Fitting to the
E L (K), the α
(K), the E M (K), and the E K (K) curves, one can obtain the responsive
E ν (0) and E ν (∞) values for the Cu/HOPG clusters. Figure 6.11 presents the fitting
to the size dependent APECS lines.
Table 6.3 presents information derived from the formulation of observations. The
atomic 2p level energy E 2p (0) = 931.0 eV and its bulk shift 2p (∞) = 1.70 eV.