5.4 Summary
95
Table 5.2 The BOLS-NEP-ZPS analysis of the electron BE shift of the even undercoordinated
atoms leads to quantitative information about the energy level of an isolated atom and the associated
entrapment and polarization
Energy levels
Site
z
C z
d z ( ´
Å)
E z /eV
E ν (z)/eV
Rh(100) 3d 3/2 [23]
Atom
0
–
302.16
Bulk
12.0
1.00
2.68
0.48
306.53
(100) S 1
4.0
0.88
2.36
0.54
307.15
Adatom
3.0
0.82
2.20
0.58
307.51
Polaron
306.20
W(110) 4f 7/2 [25]
Atom
0
31.083
Bulk
12
1.00
2.79
1.11
33.256
(110)S 1 (p)
6
0.94
2.61
1.19
33.401
Kink(p)
4
0.88
2.44
1.29
33.565
Polaron
28.910
Pt (111) 4f 7/2 [24]
Atom
0
–
68.10
Bulk
12.00
1.00
2.77
0.4867
70.49
S 1
4.25
0.89
2.47
0.5468
70.91
Adatom
3.15
0.83
2.20
0.5935
71.18
Re (12 ¯
31)
4f 5/2 [27]
Atom
0
40.014
Bulk
12
1.00
2.75
0.67
42.643
S 1
3.6
0.86
2.35
0.78
43.088
Kink
2.8
0.80
2.19
0.84
43.310
Re (12 ¯
31)
4f 7/2 [27]
S 1
3.6
0.86
2.35
0.78
40.30
O-(12 ¯
31) S 1
O sits between the outermost two
atomic layers
40.65
Energy levels
Site
z
C z
d z ( ´
Å)
E z /eV
E ν (z)/eV
Rh(100) 3d 3/2 [23]
Atom
0
–
302.16
Bulk
12.0
1.00
2.68
0.48
306.53
(100) S 1
4.0
0.88
2.36
0.54
307.15
Adatom
3.0
0.82
2.20
0.58
307.51
Polaron
306.20
W(110) 4f 7/2 [25]
Atom
0
31.083
Bulk
12
1.00
2.79
1.11
33.256
(110)S 1 (p)
6
0.94
2.61
1.19
33.401
Kink(p)
4
0.88
2.44
1.29
33.565
Polaron
28.910
Pt (111) 4f 7/2
[24]
Atom
0
–
68.10
Bulk
12.00
1.00
2.77
0.4867
70.49
S 1
4.25
0.89
2.47
0.5468
70.91
(continued)