1.6 Amphidynamic Crystal
11
(PMOs) by Sozzani and co-workers (Fig. 1.9a) [16]. Kitagawa S. and co-workers
have investigated the gas adsorption properties of MOFs system with the rotation
properties of the ligands (Fig. 1.9b) [17]. When the rotator possesses high dipolar
moment, the rotation in the amphidynamic crystals can response to external electric field. Garcia-Garibay M.A. and co-workers have revealed that external electric
field which is generated from alternating current can interact with the rotation of
the high dipolar rotator in the crystals (Fig. 1.9c) [18a–b]. Recently, several examples of such dipolar rotors have been reported, based on molecular crystals [18],
Fig. 1.9 Several examples of amphidynamic crystals possessing functional properties. Part a is
adapted with permission [16b]. Copyright 2008, The Royal Society of Chemistry. Part b is reproduced with permission [17d]. Copyright 2006, John Wiley and Sons. Part c is reproduced with
permission [18b]. Copyright 2006, American Physical Society. Part d is reproduced with permission [21]. Copyright 2013, American Chemical Society. Part e is reproduced with permission [22c].
Copyright 2013, American Chemical Society
11
(PMOs) by Sozzani and co-workers (Fig. 1.9a) [16]. Kitagawa S. and co-workers
have investigated the gas adsorption properties of MOFs system with the rotation
properties of the ligands (Fig. 1.9b) [17]. When the rotator possesses high dipolar
moment, the rotation in the amphidynamic crystals can response to external electric field. Garcia-Garibay M.A. and co-workers have revealed that external electric
field which is generated from alternating current can interact with the rotation of
the high dipolar rotator in the crystals (Fig. 1.9c) [18a–b]. Recently, several examples of such dipolar rotors have been reported, based on molecular crystals [18],
Fig. 1.9 Several examples of amphidynamic crystals possessing functional properties. Part a is
adapted with permission [16b]. Copyright 2008, The Royal Society of Chemistry. Part b is reproduced with permission [17d]. Copyright 2006, John Wiley and Sons. Part c is reproduced with
permission [18b]. Copyright 2006, American Physical Society. Part d is reproduced with permission [21]. Copyright 2013, American Chemical Society. Part e is reproduced with permission [22c].
Copyright 2013, American Chemical Society