134
5 Mechanical-Stimulation-Triggered and Solvent-Vapor-Induced …
Fig. 5.4 Crystal structures of 3O scsc . a Dimer of (S)- and (R)-3 with an inversion center, b tetramer,
and c packing structure of 3O scsc
emission lifetime (τ av )
10 of 3G/MeOH were determined to be 0.05 and 384.1 μs,
respectively (Fig. 5.17 and Table 5.3). In contrast, 3O scsc presents a drastically redshifted emission spectrum with CIE coordinates of (0.56, 0.43) and blue-shifted
excitation band, i.e., 3O scsc exhibits a broad emission spectrum with λ em,max =
612 nm (Fig. 5.5, orange solid line), and the excitation spectrum is also broader with
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