66
M. Haumann
by use of rhodium complex catalysts. J Chem Soc A 3133; (c) Evans D, Yagupsky G, Wilkinson GJ (1968) The reaction of hydridocarbonyltris(triphenylphosphine)rhodium with carbon
monoxide, and of the reaction products, hydridodicarbonylbis(triphenylphosphine)rhodium
and dimeric species, with hydrogen. J Chem Soc A 2660
13. Haumann M, Dentler K, Joni J, Riisager A, Wasserscheid P (2007) Continuous gas-phase
hydroformylation of 1-butene using supported ionic liquid phase (SILP) catalysts. Adv Synth
Catal 349:425
14. Hibbel J, Wiebus E, Cornils B (2013) 75 Jahre Hydroformylierung – Oxoreaktoren und
Oxoanlagen der Ruhrchemie AG und der Oxea GmbH von 1938 bis 2013. Chem Ing Tech
85:1853
15. Haumann M, Jakuttis M, Werner S, Wasserscheid P (2009) Supported ionic liquid phase (SILP)
catalyzed hydroformylation of 1-butene in a gradient-free loop reactor. J Catal 263:321
16. van Leeuwen PWNM, Kamer PC, Reek JNH, Dierkes P (2000) Ligand bite angle effects in
metal-catalyzed C−C bond formation. Chem Rev 100:2741
17. Klein H, Jackstell R, Wiese K-D, Borgmann C, Beller M (2001) Hoch selektive Katalysatoren
für die Hydroformylierung interner Olefine zu linearen Aldehyden. Angew Chem 113:3505
18. Behr A, Obst D, Schulte C, Schosser T (2003) Highly selective tandem isomerization–hydroformylation reaction of trans-4-octene to n-nonanal with rhodium-BIPHEPHOS catalysis. J
Mol Catal A 206:179
19. Haumann M, Jakuttis M, Franke R, Schönweiz A, Wasserscheid P (2011) Continuous gasphase hydroformylation of a highly diluted technical C4 feed using supported ionic liquid
phase catalysts. ChemCatChem 3:1822
20. (a) Jakuttis M, Schönweiz A, Werner S, Franke R, Wiese K-D, Haumann M, Wasserscheid P
(2011) Rhodium–phosphite SILP catalysis for the highly selective hydroformylation of mixed
C 4 feedstocks. Angew Chem Int Ed 50:4492; (b) Franke R, Brausch N, Fridag D, Christiansen A, Becker M, Wasserscheid P, Haumann M, Jakuttis M, Werner S, Schönweiz A
(2012) Einsatz von supported ionic liquid phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in
2-Stellung unverzweigten Aldehyden. WO 2012041846 A1
21. Selent D, Franke R, Kubis C, Spannenberg A, Baumann W, Kreidler B, Börner A (2011)
A new diphosphite promoting highly regioselective rhodium-catalyzed hydroformylation.
Organometallics 30:4509
22. (a) Walter S, Haumann M, Wasserscheid P, Hahn H, Franke R (2015) n-butane carbonylation to
n-pentanal using a cascade reaction of dehydrogenation and SILP-catalyzed hydroformylation.
AIChE J 61:893; (b) Hahn H, Dyballa KM, Franke R, Fridag D, Walter S, Haumann M, Wasserscheid P (2016) SILP-Katalysator zur Hydroformylierung von Olefinen mit Synthesegas. DE
102015201560 A1
23. http://www.romeo-h2020.eu/. Accessed 10.01.2019
24. Hintermair U, Zhao G, Santini CC, Muldoon MJ, Cole-Hamilton DJ (2007) Supported ionic
liquid phase catalysis with supercritical flow. Chem Commun 1462
25. (a) Öchsner E, Schneider MJ, Meyer C, Haumann M, Wasserscheid P (2011) Challenging the
scope of continuous, gas-phase reactions with supported ionic liquid phase (SILP) catalysts—
Asymmetric hydrogenation of methyl acetoacetate. Appl Cat A Gen 399:35; (b) Haumann
M, Öchsner E, Wasserscheid P (2010) Hybridmaterialien zur heterogen katalysierten asymmetrischen Hydrierung im Gaskontakt und Verfahren zu ihrer Anwendung. DE 102009011815
A1
26. Abed R, Rinker RG (1973) Diffusion-limited reaction in supported liquid-phase catalysis. J
Catal 31:119
27. Hintermair U, Höfener T, Pullmann T, Franciò G, Leitner W (2010) Continuous enantioselective
hydrogenation with a molecular catalyst in supported ionic liquid phase under supercritical CO 2
flow. ChemCatChem 2:150
28. Hintermair U, Roosen C, Kaever M, Kronenberg H, Thelen R, Aey S, Leitner W, Greiner L
(2011) A versatile lab to pilot scale continuous reaction system for supercritical fluid processing.
Org Process Res Dev 15:1275
M. Haumann
by use of rhodium complex catalysts. J Chem Soc A 3133; (c) Evans D, Yagupsky G, Wilkinson GJ (1968) The reaction of hydridocarbonyltris(triphenylphosphine)rhodium with carbon
monoxide, and of the reaction products, hydridodicarbonylbis(triphenylphosphine)rhodium
and dimeric species, with hydrogen. J Chem Soc A 2660
13. Haumann M, Dentler K, Joni J, Riisager A, Wasserscheid P (2007) Continuous gas-phase
hydroformylation of 1-butene using supported ionic liquid phase (SILP) catalysts. Adv Synth
Catal 349:425
14. Hibbel J, Wiebus E, Cornils B (2013) 75 Jahre Hydroformylierung – Oxoreaktoren und
Oxoanlagen der Ruhrchemie AG und der Oxea GmbH von 1938 bis 2013. Chem Ing Tech
85:1853
15. Haumann M, Jakuttis M, Werner S, Wasserscheid P (2009) Supported ionic liquid phase (SILP)
catalyzed hydroformylation of 1-butene in a gradient-free loop reactor. J Catal 263:321
16. van Leeuwen PWNM, Kamer PC, Reek JNH, Dierkes P (2000) Ligand bite angle effects in
metal-catalyzed C−C bond formation. Chem Rev 100:2741
17. Klein H, Jackstell R, Wiese K-D, Borgmann C, Beller M (2001) Hoch selektive Katalysatoren
für die Hydroformylierung interner Olefine zu linearen Aldehyden. Angew Chem 113:3505
18. Behr A, Obst D, Schulte C, Schosser T (2003) Highly selective tandem isomerization–hydroformylation reaction of trans-4-octene to n-nonanal with rhodium-BIPHEPHOS catalysis. J
Mol Catal A 206:179
19. Haumann M, Jakuttis M, Franke R, Schönweiz A, Wasserscheid P (2011) Continuous gasphase hydroformylation of a highly diluted technical C4 feed using supported ionic liquid
phase catalysts. ChemCatChem 3:1822
20. (a) Jakuttis M, Schönweiz A, Werner S, Franke R, Wiese K-D, Haumann M, Wasserscheid P
(2011) Rhodium–phosphite SILP catalysis for the highly selective hydroformylation of mixed
C 4 feedstocks. Angew Chem Int Ed 50:4492; (b) Franke R, Brausch N, Fridag D, Christiansen A, Becker M, Wasserscheid P, Haumann M, Jakuttis M, Werner S, Schönweiz A
(2012) Einsatz von supported ionic liquid phase (SILP) Katalysatorsystemen in der Hydroformylierung von olefinhaltigen Gemischen zu Aldehydgemischen mit hohem Anteil von in
2-Stellung unverzweigten Aldehyden. WO 2012041846 A1
21. Selent D, Franke R, Kubis C, Spannenberg A, Baumann W, Kreidler B, Börner A (2011)
A new diphosphite promoting highly regioselective rhodium-catalyzed hydroformylation.
Organometallics 30:4509
22. (a) Walter S, Haumann M, Wasserscheid P, Hahn H, Franke R (2015) n-butane carbonylation to
n-pentanal using a cascade reaction of dehydrogenation and SILP-catalyzed hydroformylation.
AIChE J 61:893; (b) Hahn H, Dyballa KM, Franke R, Fridag D, Walter S, Haumann M, Wasserscheid P (2016) SILP-Katalysator zur Hydroformylierung von Olefinen mit Synthesegas. DE
102015201560 A1
23. http://www.romeo-h2020.eu/. Accessed 10.01.2019
24. Hintermair U, Zhao G, Santini CC, Muldoon MJ, Cole-Hamilton DJ (2007) Supported ionic
liquid phase catalysis with supercritical flow. Chem Commun 1462
25. (a) Öchsner E, Schneider MJ, Meyer C, Haumann M, Wasserscheid P (2011) Challenging the
scope of continuous, gas-phase reactions with supported ionic liquid phase (SILP) catalysts—
Asymmetric hydrogenation of methyl acetoacetate. Appl Cat A Gen 399:35; (b) Haumann
M, Öchsner E, Wasserscheid P (2010) Hybridmaterialien zur heterogen katalysierten asymmetrischen Hydrierung im Gaskontakt und Verfahren zu ihrer Anwendung. DE 102009011815
A1
26. Abed R, Rinker RG (1973) Diffusion-limited reaction in supported liquid-phase catalysis. J
Catal 31:119
27. Hintermair U, Höfener T, Pullmann T, Franciò G, Leitner W (2010) Continuous enantioselective
hydrogenation with a molecular catalyst in supported ionic liquid phase under supercritical CO 2
flow. ChemCatChem 2:150
28. Hintermair U, Roosen C, Kaever M, Kronenberg H, Thelen R, Aey S, Leitner W, Greiner L
(2011) A versatile lab to pilot scale continuous reaction system for supercritical fluid processing.
Org Process Res Dev 15:1275