3 Continuous Catalytic Processes with Supported Ionic Liquid …
67
29. Hintermair U, Franciò G, Leitner W (2013) A fully integrated continuous-flow system for asymmetric catalysis: enantioselective hydrogenation with supported ionic liquid phase catalysts
using supercritical CO 2 as the mobile phase. Chem Eur J 19:4538
30. Amara Z, Poliakoff M, Duque R, Geier D, Franciò G, Gordon CM, Meadows RE, Woodward
R, Leitner W (2016) Enabling the scale-up of a key asymmetric hydrogenation step in the
synthesis of an API using continuous flow solid-supported catalysis. Org Process Res Dev
20:1321
31. (a) Werner S, Szesni N, Fischer RW, Haumann M, Wasserscheid P (2009) Homogeneous
ruthenium-based water–gas shift catalysts via supported ionic liquid phase (SILP) technology
at low temperature and ambient pressure. Phys Chem Chem Phys 11:10817; (b) Szesni N, Kaiser
M, Fischer RW, Haumann M, Werner S, Wasserscheid P (2011) Katalysatorzusammensetzung
für die Umsetzung von Kohlenmonoxid in Gasströmen. WO 2011023368 A1
32. Werner S, Szesni N, Bittermann A, Schneider MJ, Härter P, Haumann M, Wasserscheid P
(2010) Screening of Supported Ionic Liquid Phase (SILP) catalysts for the very low temperature
water–gas-shift reaction. Appl Cat A Gen 377:70
33. Bauer T, Stepic R, Wolf P, Kollhoff F, Karawacka W, Wick CR, Haumann M, Wasserscheid
P, Smith DM, Smith A-S, Libuda J (2018) Dynamic equilibria in supported ionic liquid phase
(SILP) catalysis: in situ IR spectroscopy identifies [Ru(CO) x Cl y ] n species in water gas shift
catalysis. Cat Sci Technol 8:344
34. Werner S, Szesni N, Kaiser M, Fischer RW, Haumann M, Wasserscheid P (2010) Ultra-lowtemperature water–gas shift catalysis using supported ionic liquid phase (SILP) materials.
ChemCatChem 2:1399
35. Stepi´ c R, Wick CR, Strobel V, Berger D, Vuˇ cemilovi´ c-Alagi´ c N, Haumann M, Wasserscheid
P, Smith A-S, Smith DM (2019) Mechanism of the water–gas shift reaction catalyzed by
efficient ruthenium-based catalysts: a computational and experimental study. Angew Chem Int
Ed 58:741
36. Werner S, Szesni N, Kaiser M, Haumann M, Wasserscheid P (2012) A scalable preparation
method for SILP and SCILL ionic liquid thin-film materials. Chem Eng Technol 35:1962
37. Werner S, Haumann M (2014) Ultralow temperature water–gas shift reaction enabled by supported ionic liquid phase catalysts. In: Riisager A, Fehrmann R, Haumann M (eds) Supported
ionic liquids—fundamentals and applications, chap 16. Wiley-VCH, Weinheim
38. Szesni N Clariant Produkte Germany, private communication
39. Yoneda N, Kusano S, Yasui M, Pujado P, Wilcher S (2001) Recent advances in processes and
catalysts for the production of acetic acid. Appl Catal A 221:253
40. (a) Riisager A, Jørgensen B, Wasserscheid P, Fehrmann R (2006) First application of supported
ionic liquid phase (SILP) catalysis for continuous methanol carbonylation. Chem Commun 994;
(b) Riisager A, Fehrmann R (2006) A process for continuous carbonylation by supported ionic
liquid-phase catalysis. WO2006122563 A1
41. (a) Khokarale SG, García-Suárez EJ, Fehrmann R, Riisager A (2017) Highly selective continuous gas-phase methoxycarbonylation of ethylene with supported ionic liquid phase (SILP)
catalysts. ChemCatChem 9:1824; (b) Riisager A, Fehrmann R, Garcia Suarez E, Xiong J
(2017) Palladium catalyst system comprising zwitterion and/or acid-functionalyzed ionic
liquid. US2017341067 A1
42. Zhao J, Yu Y, Xu X, Di S, Wang B, Xu H, Ni J, Guo LL, Pan Z, Li X (2017) Stabilizing Au(III)
in supported-ionic-liquid-phase (SILP) catalyst using CuCl 2 via a redox mechanism. Appl Cat
B Environ 206:175
67
29. Hintermair U, Franciò G, Leitner W (2013) A fully integrated continuous-flow system for asymmetric catalysis: enantioselective hydrogenation with supported ionic liquid phase catalysts
using supercritical CO 2 as the mobile phase. Chem Eur J 19:4538
30. Amara Z, Poliakoff M, Duque R, Geier D, Franciò G, Gordon CM, Meadows RE, Woodward
R, Leitner W (2016) Enabling the scale-up of a key asymmetric hydrogenation step in the
synthesis of an API using continuous flow solid-supported catalysis. Org Process Res Dev
20:1321
31. (a) Werner S, Szesni N, Fischer RW, Haumann M, Wasserscheid P (2009) Homogeneous
ruthenium-based water–gas shift catalysts via supported ionic liquid phase (SILP) technology
at low temperature and ambient pressure. Phys Chem Chem Phys 11:10817; (b) Szesni N, Kaiser
M, Fischer RW, Haumann M, Werner S, Wasserscheid P (2011) Katalysatorzusammensetzung
für die Umsetzung von Kohlenmonoxid in Gasströmen. WO 2011023368 A1
32. Werner S, Szesni N, Bittermann A, Schneider MJ, Härter P, Haumann M, Wasserscheid P
(2010) Screening of Supported Ionic Liquid Phase (SILP) catalysts for the very low temperature
water–gas-shift reaction. Appl Cat A Gen 377:70
33. Bauer T, Stepic R, Wolf P, Kollhoff F, Karawacka W, Wick CR, Haumann M, Wasserscheid
P, Smith DM, Smith A-S, Libuda J (2018) Dynamic equilibria in supported ionic liquid phase
(SILP) catalysis: in situ IR spectroscopy identifies [Ru(CO) x Cl y ] n species in water gas shift
catalysis. Cat Sci Technol 8:344
34. Werner S, Szesni N, Kaiser M, Fischer RW, Haumann M, Wasserscheid P (2010) Ultra-lowtemperature water–gas shift catalysis using supported ionic liquid phase (SILP) materials.
ChemCatChem 2:1399
35. Stepi´ c R, Wick CR, Strobel V, Berger D, Vuˇ cemilovi´ c-Alagi´ c N, Haumann M, Wasserscheid
P, Smith A-S, Smith DM (2019) Mechanism of the water–gas shift reaction catalyzed by
efficient ruthenium-based catalysts: a computational and experimental study. Angew Chem Int
Ed 58:741
36. Werner S, Szesni N, Kaiser M, Haumann M, Wasserscheid P (2012) A scalable preparation
method for SILP and SCILL ionic liquid thin-film materials. Chem Eng Technol 35:1962
37. Werner S, Haumann M (2014) Ultralow temperature water–gas shift reaction enabled by supported ionic liquid phase catalysts. In: Riisager A, Fehrmann R, Haumann M (eds) Supported
ionic liquids—fundamentals and applications, chap 16. Wiley-VCH, Weinheim
38. Szesni N Clariant Produkte Germany, private communication
39. Yoneda N, Kusano S, Yasui M, Pujado P, Wilcher S (2001) Recent advances in processes and
catalysts for the production of acetic acid. Appl Catal A 221:253
40. (a) Riisager A, Jørgensen B, Wasserscheid P, Fehrmann R (2006) First application of supported
ionic liquid phase (SILP) catalysis for continuous methanol carbonylation. Chem Commun 994;
(b) Riisager A, Fehrmann R (2006) A process for continuous carbonylation by supported ionic
liquid-phase catalysis. WO2006122563 A1
41. (a) Khokarale SG, García-Suárez EJ, Fehrmann R, Riisager A (2017) Highly selective continuous gas-phase methoxycarbonylation of ethylene with supported ionic liquid phase (SILP)
catalysts. ChemCatChem 9:1824; (b) Riisager A, Fehrmann R, Garcia Suarez E, Xiong J
(2017) Palladium catalyst system comprising zwitterion and/or acid-functionalyzed ionic
liquid. US2017341067 A1
42. Zhao J, Yu Y, Xu X, Di S, Wang B, Xu H, Ni J, Guo LL, Pan Z, Li X (2017) Stabilizing Au(III)
in supported-ionic-liquid-phase (SILP) catalyst using CuCl 2 via a redox mechanism. Appl Cat
B Environ 206:175