Table 6
(continued)
Matrix and target
molecules
Weight/
volume of
sample
Extraction solvent
Salts
Buffer
Clean-up
Analytical
method
Reference
Celery and lettuce
–
11 pharmaceutical
compounds
500 mg
dry
weight
7 mL ACN/MeOH/
H
2 O (74.1:0:28.6),
(60.7:10.7:28.6),
(53.6:17.9:28.6),
(35.7:35.7:28.6)
2 g anhydrous
Na
2 SO
4 , 0.5 g
NaCl
150 mg L
À1
Na
2 EDTA
d-SPE (12.5 mg
C18, 12.5 PSA,
225 mg Na
2 SO
4 )
HPLC-MS/
MS
[119]
Lettuce leaves
– carbamazepine,
flumequine, and
thiabendazole
10 g wet
weight
10 mL of ACN
6 g of MgSO
4
1.5 g of NaOAc
d-SPE (125 mg
PSA, 150 mg C18,
750 mg MgSO
4 ),
0.45
μm PTFE
filter
LC-QqLITMS/MS
[122]
Sedative functional foods
(based on Salvia
miltiorrhiza
and
Schisandra chinensis)
–
11 blockers
2 g wet
weight
5 ml of acetic acid/
ACN/MeOH
(0.1:3:7, v/v/v)
15 ml of acetic
acid/ACN/
MeOH (0.1:3:7,
v/v/v) (second
round)
None
d-SPE (50 mg PSA,
500 mg MgSO
4 )
UPLC-MS/
MS
[150]
Baby food (some of vegetal
origin)
– sulfonamides
5 g dry
weight
15 g wet
weight
10 mL ultrapure
water, 15 mL of 1%
acetic acid in ACN
15 mL of 1% acetic
acid in ACN
6 g MgSO
4
1.5 g NaOAc
150 mg PSA,
150 mg C18,
900 mg MgSO
4
UHPLC-HR/
MS
[139]
Buckwheat and related
products
– atropine and
scopolamine
5 g dry
weight
10 mL H
2 O, 10 mL
ACN containing 1%
(v/v) of formic acid
4 g of anhydrous Na
2 SO
4
1 g NH
4 Ac
25 mg of PSA,
25 mg of GBC
UHPLC-MS/
MS
[35]
Lettuce
– 13 wastewaterderived contaminants
0.5 g dry
weight
20 mL
ACN-MeOH (1:1,
v/v), MTBE-MeOH
(1:1, v/v), hexane4 g MgSO
4 , 1 g
NaCl
1 g sodium citrate 0.2
μm PTFE
filters,
liquid-liquid
extracted with hexane (hexane
HPLC-MS
[7]
452
R. Manasfi et al.
(continued)
Matrix and target
molecules
Weight/
volume of
sample
Extraction solvent
Salts
Buffer
Clean-up
Analytical
method
Reference
Celery and lettuce
–
11 pharmaceutical
compounds
500 mg
dry
weight
7 mL ACN/MeOH/
H
2 O (74.1:0:28.6),
(60.7:10.7:28.6),
(53.6:17.9:28.6),
(35.7:35.7:28.6)
2 g anhydrous
Na
2 SO
4 , 0.5 g
NaCl
150 mg L
À1
Na
2 EDTA
d-SPE (12.5 mg
C18, 12.5 PSA,
225 mg Na
2 SO
4 )
HPLC-MS/
MS
[119]
Lettuce leaves
– carbamazepine,
flumequine, and
thiabendazole
10 g wet
weight
10 mL of ACN
6 g of MgSO
4
1.5 g of NaOAc
d-SPE (125 mg
PSA, 150 mg C18,
750 mg MgSO
4 ),
0.45
μm PTFE
filter
LC-QqLITMS/MS
[122]
Sedative functional foods
(based on Salvia
miltiorrhiza
and
Schisandra chinensis)
–
11 blockers
2 g wet
weight
5 ml of acetic acid/
ACN/MeOH
(0.1:3:7, v/v/v)
15 ml of acetic
acid/ACN/
MeOH (0.1:3:7,
v/v/v) (second
round)
None
d-SPE (50 mg PSA,
500 mg MgSO
4 )
UPLC-MS/
MS
[150]
Baby food (some of vegetal
origin)
– sulfonamides
5 g dry
weight
15 g wet
weight
10 mL ultrapure
water, 15 mL of 1%
acetic acid in ACN
15 mL of 1% acetic
acid in ACN
6 g MgSO
4
1.5 g NaOAc
150 mg PSA,
150 mg C18,
900 mg MgSO
4
UHPLC-HR/
MS
[139]
Buckwheat and related
products
– atropine and
scopolamine
5 g dry
weight
10 mL H
2 O, 10 mL
ACN containing 1%
(v/v) of formic acid
4 g of anhydrous Na
2 SO
4
1 g NH
4 Ac
25 mg of PSA,
25 mg of GBC
UHPLC-MS/
MS
[35]
Lettuce
– 13 wastewaterderived contaminants
0.5 g dry
weight
20 mL
ACN-MeOH (1:1,
v/v), MTBE-MeOH
(1:1, v/v), hexane4 g MgSO
4 , 1 g
NaCl
1 g sodium citrate 0.2
μm PTFE
filters,
liquid-liquid
extracted with hexane (hexane
HPLC-MS
[7]
452
R. Manasfi et al.