743
industrial-grade IPA, 189
modern synthetic petrochemical, 189
semi-hollow porous nano-palladium, 194
Isotactic and syndiotactic poly-α-olefins
bridged and unbridged C 2 -symmetric
octahedral catalysts, 686, 687
bridged chemical linkage, 686
C 2 -symmetric metallocene catalyst, 685
definition, 684
mechanism, 684, 686
metallocene-based systems, 686
metallocene catalysts, 687, 688
prochiral monomer, 687
properties
atactic PP, 683, 684
catalyst compositions, 684, 685
metallocene-based catalyst, 686
R 4 M catalysts, 684
stereorigid structures, 684, 685
Isothermal reactors, 576
K
KBR K-SAAT
TM process, 121
Kerr-McGee/AGG Lummus Crest (KMALC)
technology, 605
Ketazines, 273
Kinetics, DRM reaction
mechanism
ER, 339–341
Langmuir Hinshelwood
Kinetics, 341–344
types, 338
rate expression, 338
RWGS, 338
L
Langmuir Hinshelwood Kinetics
Bradford mechanism, 342, 343
Tsipouriari mechanism, 343, 344
Langmuir–Hinshelwood–Hougen–Watson
(LHHW), 475, 484, 491
Lanthanides, 338
La 2 O 2 CO 3 , 343
Layered double hydroxides (LDH), 137
Le Chatelier’s principle, 417
Lewis acids, 123, 128
“Ligand effect”, 217
Light coker gas oil (LCGO), 5
Light cycle oil (LCO), 72, 78
Linear LDPE (LLDPE)
mechanical and thermal properties, 676
polymer chains, 676
Liquefied petroleum gas (LPG), 157, 163, 514
Liquid-fed flame synthesis, 542
Liquid phase reactors, 577, 578
Liquid phase sulfiding, 46
Liquid-to-coal (LTC), 405
Low-density PE (LDPE), 676
mechanical and thermal properties, 676
polymer chains, 676
LSR naphtha, 381
Lubes hydroprocessing, 391, 392
Lubricants, 391
LURGI EUROFUEL
® process, 120
Lurgi’s MTP process, 162
M
Maleic acid, 54
Mars, 548, 549
Mars ascent vehicle (MAV), 548
Martian soil, 549
Matrix, 82, 84
MCM-41-supported catalysts, 450
MEA-based blend, 655
Mechanism of demulsification, 718, 719
Mechanism pathways, 366
Medium-density PE (MDPE)
mechanical and thermal properties, 676
polymer chains, 676
Membrane processes, 549
Membrane reactors, 578–580, 590
Membrane reformers, 417
advantage, 417
process-intensified reactor, 417
Membrane separation, 396, 607
Membranes, 607
Mesoporosity, 364–365
Metal and non-metal doping, 585
Metal catalysts, 257, 258
Metal complexes, 611
Metal deposition, 49
Metal-exchanged zeolites, 116
Metallic catalysts, 134
Metallic impurities, 75
Metal-linker coordination bond, 395
Metal-loaded catalyst, 511
Metal loading methods, 510
Metallocene catalyst
and chelated complex systems, 700
C 2 -symmetric, 684
cyclic olefin monomers polymerizable,
687, 688
palladium α-diimine-based catalyst, 692
polypropylene, 686
pseudotetrahedral, 686
Index
industrial-grade IPA, 189
modern synthetic petrochemical, 189
semi-hollow porous nano-palladium, 194
Isotactic and syndiotactic poly-α-olefins
bridged and unbridged C 2 -symmetric
octahedral catalysts, 686, 687
bridged chemical linkage, 686
C 2 -symmetric metallocene catalyst, 685
definition, 684
mechanism, 684, 686
metallocene-based systems, 686
metallocene catalysts, 687, 688
prochiral monomer, 687
properties
atactic PP, 683, 684
catalyst compositions, 684, 685
metallocene-based catalyst, 686
R 4 M catalysts, 684
stereorigid structures, 684, 685
Isothermal reactors, 576
K
KBR K-SAAT
TM process, 121
Kerr-McGee/AGG Lummus Crest (KMALC)
technology, 605
Ketazines, 273
Kinetics, DRM reaction
mechanism
ER, 339–341
Langmuir Hinshelwood
Kinetics, 341–344
types, 338
rate expression, 338
RWGS, 338
L
Langmuir Hinshelwood Kinetics
Bradford mechanism, 342, 343
Tsipouriari mechanism, 343, 344
Langmuir–Hinshelwood–Hougen–Watson
(LHHW), 475, 484, 491
Lanthanides, 338
La 2 O 2 CO 3 , 343
Layered double hydroxides (LDH), 137
Le Chatelier’s principle, 417
Lewis acids, 123, 128
“Ligand effect”, 217
Light coker gas oil (LCGO), 5
Light cycle oil (LCO), 72, 78
Linear LDPE (LLDPE)
mechanical and thermal properties, 676
polymer chains, 676
Liquefied petroleum gas (LPG), 157, 163, 514
Liquid-fed flame synthesis, 542
Liquid phase reactors, 577, 578
Liquid phase sulfiding, 46
Liquid-to-coal (LTC), 405
Low-density PE (LDPE), 676
mechanical and thermal properties, 676
polymer chains, 676
LSR naphtha, 381
Lubes hydroprocessing, 391, 392
Lubricants, 391
LURGI EUROFUEL
® process, 120
Lurgi’s MTP process, 162
M
Maleic acid, 54
Mars, 548, 549
Mars ascent vehicle (MAV), 548
Martian soil, 549
Matrix, 82, 84
MCM-41-supported catalysts, 450
MEA-based blend, 655
Mechanism of demulsification, 718, 719
Mechanism pathways, 366
Medium-density PE (MDPE)
mechanical and thermal properties, 676
polymer chains, 676
Membrane processes, 549
Membrane reactors, 578–580, 590
Membrane reformers, 417
advantage, 417
process-intensified reactor, 417
Membrane separation, 396, 607
Membranes, 607
Mesoporosity, 364–365
Metal and non-metal doping, 585
Metal catalysts, 257, 258
Metal complexes, 611
Metal deposition, 49
Metal-exchanged zeolites, 116
Metallic catalysts, 134
Metallic impurities, 75
Metal-linker coordination bond, 395
Metal-loaded catalyst, 511
Metal loading methods, 510
Metallocene catalyst
and chelated complex systems, 700
C 2 -symmetric, 684
cyclic olefin monomers polymerizable,
687, 688
palladium α-diimine-based catalyst, 692
polypropylene, 686
pseudotetrahedral, 686
Index