639
119. Li Y-N, Ma R, He L-N, Diao Z-F (2014) Homogeneous hydrogenation of carbon dioxide to
methanol. Catal Sci Technol 4:1498–1512
120. Tominaga KI, Sasaki Y, Kawai M, Watanabe T, Saito M (1993) Ruthenium complex catalysed
hydrogenation of carbon dioxide to carbon monoxide, methanol and methane. J Chem Soc
Chem Commun:629–631
121. Tominaga K, Sasaki Y, Watanabe T, Saito M (1995) Homogeneous hydrogenation of carbon
dioxide to methanol catalyzed by ruthenium cluster anions in the presence of halide anions.
Bull Chem Soc Jpn 68:2837–2842
122. Huff CA, Sanford MS (2011) Cascade catalysis for the homogeneous hydrogenation of CO 2
to methanol. J Am Chem Soc 133:18122–18125
123. Wesselbaum S, Moha V, Meuresch M, Brosinski S, Thenert KM, Kothe J, vom Stein T,
Englert U, Hölscher M, Klankermayer J, Leitner W (2015) Hydrogenation of carbon dioxide
to methanol using a homogeneous ruthenium–triphos catalyst: from mechanistic investigations to multiphase catalysis. Chem Sci 6:693–704
124. Kothandaraman J, Goeppert A, Czaun M, Olah GA, Prakash GKS (2016) Conversion of
CO 2 from air into methanol using a polyamine and a homogeneous ruthenium catalyst. J Am
Chem Soc 138:778–781
125. Kar S, Goeppert A, Kothandaraman J, Prakash GKS (2017) Manganese catalyzed sequential
hydrogenation of CO 2 to methanol via formamide. ACS Catal 7:6347–6351
126. Schneidewind J, Adam R, Baumann W, Jackstell R, Beller M (2017) Low-temperature hydrogenation of carbon dioxide to methanol with a homogeneous cobalt catalyst. Angew Chem
Int Ed 56:1890–1893
127. Ribeiro APC, Martins LMDRS, Pombeiro AJL (2017) Carbon dioxide-to-methanol singlepot conversion using a cscorpionate iron(II) catalyst. Green Chem 19:4811–4815
128. Tsurusaki A, Murata K, Onishi N, Sordakis K, Laurenczy G, Himeda Y (2017) Investigation
of hydrogenation of formic acid to methanol using H 2 or formic acid as a hydrogen source.
ACS Catal 7:1123–1131
129. Eisenschmid TG, Eisenberg R (1989) The iridium complex catalyzed reduction of carbon
dioxide to methoxide by alkylsilanes. Organometallics 8:1822–1824
130. Huang F, Zhang CG, Jiang JL, Wang ZX, Guan HR (2011) How does the nickel pincer complex catalyze the conversion of CO 2 to a methanol derivative? A computational mechanistic
study. Inorg Chem 50:3816–3825
131. Chakraborty S, Zhang J, Krause JA, Guan H (2010) An efficient nickel catalyst for the reduction of carbon dioxide with a borane. J Am Chem Soc 132:8872–8873
132. Scheuermann ML, Semproni SP, Pappas I, Chirik PJ (2014) Carbon dioxide hydrosilylation
promoted by cobalt pincer complexes. Inorg Chem 53:9463–9465
133. Metsanen TT, Oestreich M (2015) Temperature-dependent chemoselective hydrosilylation of carbon dioxide to formaldehyde or methanol oxidation state. Organometallics
2015(34):543–546
134. Mazzotta MG, Xiong M, Abu-Omar MM (2017) Carbon dioxide reduction to silyl-protected
methanol catalyzed by an oxorhenium pincer PNN complex. Organometallics 36:1688–1691
135. Morris DS, Weetman C, Wennmacher JTC, Cokoja M, Drees M, Kühn FE, Love JB (2017)
Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion. Catal Sci Technol 7:2838–2845
136. Bertini F, Glatz M, Stöger B, Peruzzini M, Veiros LF, Kirchner K, Gonsalvi L (2019) Carbon
dioxide reduction to methanol catalyzed by Mn(I) PNP pincer complexes under mild reaction
conditions. ACS Catal 9:632–639
137. Enthaler S, von Langermann J, Schmidt T (2010) Carbon dioxide and formic acid-the couple
for environmental-friendly hydrogen storage? Energy Environ Sci 3:1207–1217
138. Joo F (2008) Breakthroughs in hydrogen storage-formic acid as a sustainable storage material
for hydrogen. ChemSusChem 1:805–808
139. Grasemann M, Laurenczy G (2012) Formic acid as a hydrogen source recent developments
and future trends. Energy Environ Sci 5:8171–8181
Efficient Homogeneous Catalysts for Conversion of CO 2 to Fine Chemicals
119. Li Y-N, Ma R, He L-N, Diao Z-F (2014) Homogeneous hydrogenation of carbon dioxide to
methanol. Catal Sci Technol 4:1498–1512
120. Tominaga KI, Sasaki Y, Kawai M, Watanabe T, Saito M (1993) Ruthenium complex catalysed
hydrogenation of carbon dioxide to carbon monoxide, methanol and methane. J Chem Soc
Chem Commun:629–631
121. Tominaga K, Sasaki Y, Watanabe T, Saito M (1995) Homogeneous hydrogenation of carbon
dioxide to methanol catalyzed by ruthenium cluster anions in the presence of halide anions.
Bull Chem Soc Jpn 68:2837–2842
122. Huff CA, Sanford MS (2011) Cascade catalysis for the homogeneous hydrogenation of CO 2
to methanol. J Am Chem Soc 133:18122–18125
123. Wesselbaum S, Moha V, Meuresch M, Brosinski S, Thenert KM, Kothe J, vom Stein T,
Englert U, Hölscher M, Klankermayer J, Leitner W (2015) Hydrogenation of carbon dioxide
to methanol using a homogeneous ruthenium–triphos catalyst: from mechanistic investigations to multiphase catalysis. Chem Sci 6:693–704
124. Kothandaraman J, Goeppert A, Czaun M, Olah GA, Prakash GKS (2016) Conversion of
CO 2 from air into methanol using a polyamine and a homogeneous ruthenium catalyst. J Am
Chem Soc 138:778–781
125. Kar S, Goeppert A, Kothandaraman J, Prakash GKS (2017) Manganese catalyzed sequential
hydrogenation of CO 2 to methanol via formamide. ACS Catal 7:6347–6351
126. Schneidewind J, Adam R, Baumann W, Jackstell R, Beller M (2017) Low-temperature hydrogenation of carbon dioxide to methanol with a homogeneous cobalt catalyst. Angew Chem
Int Ed 56:1890–1893
127. Ribeiro APC, Martins LMDRS, Pombeiro AJL (2017) Carbon dioxide-to-methanol singlepot conversion using a cscorpionate iron(II) catalyst. Green Chem 19:4811–4815
128. Tsurusaki A, Murata K, Onishi N, Sordakis K, Laurenczy G, Himeda Y (2017) Investigation
of hydrogenation of formic acid to methanol using H 2 or formic acid as a hydrogen source.
ACS Catal 7:1123–1131
129. Eisenschmid TG, Eisenberg R (1989) The iridium complex catalyzed reduction of carbon
dioxide to methoxide by alkylsilanes. Organometallics 8:1822–1824
130. Huang F, Zhang CG, Jiang JL, Wang ZX, Guan HR (2011) How does the nickel pincer complex catalyze the conversion of CO 2 to a methanol derivative? A computational mechanistic
study. Inorg Chem 50:3816–3825
131. Chakraborty S, Zhang J, Krause JA, Guan H (2010) An efficient nickel catalyst for the reduction of carbon dioxide with a borane. J Am Chem Soc 132:8872–8873
132. Scheuermann ML, Semproni SP, Pappas I, Chirik PJ (2014) Carbon dioxide hydrosilylation
promoted by cobalt pincer complexes. Inorg Chem 53:9463–9465
133. Metsanen TT, Oestreich M (2015) Temperature-dependent chemoselective hydrosilylation of carbon dioxide to formaldehyde or methanol oxidation state. Organometallics
2015(34):543–546
134. Mazzotta MG, Xiong M, Abu-Omar MM (2017) Carbon dioxide reduction to silyl-protected
methanol catalyzed by an oxorhenium pincer PNN complex. Organometallics 36:1688–1691
135. Morris DS, Weetman C, Wennmacher JTC, Cokoja M, Drees M, Kühn FE, Love JB (2017)
Reduction of carbon dioxide and organic carbonyls by hydrosilanes catalysed by the perrhenate anion. Catal Sci Technol 7:2838–2845
136. Bertini F, Glatz M, Stöger B, Peruzzini M, Veiros LF, Kirchner K, Gonsalvi L (2019) Carbon
dioxide reduction to methanol catalyzed by Mn(I) PNP pincer complexes under mild reaction
conditions. ACS Catal 9:632–639
137. Enthaler S, von Langermann J, Schmidt T (2010) Carbon dioxide and formic acid-the couple
for environmental-friendly hydrogen storage? Energy Environ Sci 3:1207–1217
138. Joo F (2008) Breakthroughs in hydrogen storage-formic acid as a sustainable storage material
for hydrogen. ChemSusChem 1:805–808
139. Grasemann M, Laurenczy G (2012) Formic acid as a hydrogen source recent developments
and future trends. Energy Environ Sci 5:8171–8181
Efficient Homogeneous Catalysts for Conversion of CO 2 to Fine Chemicals