594
60. Gao HW, Yan TX, Zhang CB, He HJ (2008) “Theoretical and experimental analysis on vibrational spectra of formate species adsorbed on Cu–Al 2 O 3 catalyst” J Mol Struct THEOCHEM
857(1–3):38–43
61. Campbell CT, Daube KA (1987) “A surface science investigation of the water-gas shift reaction on Cu (111)” J Catal 104(1):109–119
62. Zhao Y, Yang Y, Mims C, Peden CHF, Li J, Mei D (2011) “Insight into methanol synthesis
from CO 2 hydrogenation on Cu (1 1 1): complex reaction network and the effects of H 2 O” J
Catal 281:199–211
63. Van Herwijnen T, Guczalski RT, Jong WAD (1980) “Kinetics and mechanism of the CO shift
on Cu/ZnO II. kinetics of the decomposition of formic Acid” J Catal 63(1):94–101
64. Van Herwijnen T, Jong WAD (1980) “Kinetics and mechanism of the CO shift on Cu/ZnO
I. kinetics of the forward and reverse CO shift reactions” J Catal 63:83–93
65. Grabow LC, Gokhale AA, Evans ST, Dumesic JA, Mavrikakis M (2008) “Mechanism of the
water gas shift reaction on Pt: first principles, experiments, and microkinetic modeling” J
Phys Chem C 112(12):4608–4617
66. Gokhale AA, Dumesic JA, Mavrikakis M (2008) “On the mechanism of low-temperature
water gas shift reaction on copper” J Am Chem Soc 130(4):1402–1414
67. MartI L, Siemer N, Frenzel J, Marx D (2015) “Reaction network of methanol synthesis over
Cu/ZnO nanocatalysts” ACS Catal 5(7):4201–4218
68. Suh YW, Moon SH, Rhee HK (2000) “Active sites in Cu/ZnO/ZrO 2 catalysts for methanol
synthesis from CO/H 2 ” Catal Today 63(2–4):447–452
69. Fujitani T, Nakamura J (2000) “The chemical modification seen in the Cu/ZnO methanol
synthesis catalysts” Appl Catal A Gen 191(1–2):111–129
70. Szanyi J, Goodman DW (1991) “Methanol synthesis on a Cu (100) catalyst” Catal Lett
10:383–390
71. Chinchen GC, Waugh KC, Whan DA (1986) “The activity and state of the copper surface in
methanol synthesis catalysts” Appl Catal 25:101–107
72. Rasmussen PB, Kazuta M, Chorkendorff I (1994) “Synthesis of methanol from a mixture of
H 2 and CO 2 on Cu (100)” Surf Sci 318(3):267–280
73. Rasmussen PB, Holmblad PM, Askgaard T, Ovesen CV, Stoltze P, Nørskov JK, Chorkendorff
I (1994) “Methanol synthesis on Cu (100) from a binary gas mixture of CO 2 and H 2 ” Catal
Lett 26:373–381
74. Yoshihara J, Campbell CT (1996) “Methanol synthesis and reverse water–gas shift kinetics
over Cu (110) model catalysts: structural sensitivity” J Catal 161(2):776–782
75. Yoshihara J, Parker SC, Schafer A, Campbell CT (1995) “Methanol synthesis and reverse
water-gas shift kinetics over clean polycrystalline copper” Catal Lett 31:313–324
76. Chen HY, Lau SP, Chen L, Lin J, Huan CHA, Tan KL, Pan JS (1999) “Synergism between Cu
and Zn sites in Cu/Zn catalysts for methanol synthesis” Appl Surf Sci 152(3–4):193–199
77. Hansen PL, Wagner JB, Helveg S, Rostrup-Nielsen JR, Clausen BS, Topsøe H (2002) “Atomresolved imaging of dynamic shape changes in supported copper nanocrystals” Science
295(5562):2053–2055
78. Ovesen CV, Clausen BS, Schiotz J, Stoltze P, Topsøe H, Nørskov JK (1997) “Kinetic implications of dynamical changes in catalyst morphology during methanol synthesis over Cu/ZnO
catalysts” J Catal 168(2):133–142
79. Liu X, Lu GQ, Yan Z, Beltramini J (2003) “Recent advances in catalysts for methanol synthesis via hydrogenation of CO and CO 2 ” Ind Eng Chem Res 42(25):6518–6530
80. Twigg MV, Spencer MS (2001) “Deactivation of supported copper metal catalysts for hydrogenation reactions” Appl Catal A Gen 212(1–2):161–174
81. Jadhav SG, Vaidya PD, Bhanage BM, Joshi JB (2014) “Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies” Chem Eng Res Des 92(11):2557–2567
82. Álvarez A, Bansode A, Urakawa A, Bavykina AV, Wezendonk TA, Makkee M, Gascon J,
Kapteijn F (2017) “Challenges in the greener production of formates/formic acid, methaK. Tripathi et al.
60. Gao HW, Yan TX, Zhang CB, He HJ (2008) “Theoretical and experimental analysis on vibrational spectra of formate species adsorbed on Cu–Al 2 O 3 catalyst” J Mol Struct THEOCHEM
857(1–3):38–43
61. Campbell CT, Daube KA (1987) “A surface science investigation of the water-gas shift reaction on Cu (111)” J Catal 104(1):109–119
62. Zhao Y, Yang Y, Mims C, Peden CHF, Li J, Mei D (2011) “Insight into methanol synthesis
from CO 2 hydrogenation on Cu (1 1 1): complex reaction network and the effects of H 2 O” J
Catal 281:199–211
63. Van Herwijnen T, Guczalski RT, Jong WAD (1980) “Kinetics and mechanism of the CO shift
on Cu/ZnO II. kinetics of the decomposition of formic Acid” J Catal 63(1):94–101
64. Van Herwijnen T, Jong WAD (1980) “Kinetics and mechanism of the CO shift on Cu/ZnO
I. kinetics of the forward and reverse CO shift reactions” J Catal 63:83–93
65. Grabow LC, Gokhale AA, Evans ST, Dumesic JA, Mavrikakis M (2008) “Mechanism of the
water gas shift reaction on Pt: first principles, experiments, and microkinetic modeling” J
Phys Chem C 112(12):4608–4617
66. Gokhale AA, Dumesic JA, Mavrikakis M (2008) “On the mechanism of low-temperature
water gas shift reaction on copper” J Am Chem Soc 130(4):1402–1414
67. MartI L, Siemer N, Frenzel J, Marx D (2015) “Reaction network of methanol synthesis over
Cu/ZnO nanocatalysts” ACS Catal 5(7):4201–4218
68. Suh YW, Moon SH, Rhee HK (2000) “Active sites in Cu/ZnO/ZrO 2 catalysts for methanol
synthesis from CO/H 2 ” Catal Today 63(2–4):447–452
69. Fujitani T, Nakamura J (2000) “The chemical modification seen in the Cu/ZnO methanol
synthesis catalysts” Appl Catal A Gen 191(1–2):111–129
70. Szanyi J, Goodman DW (1991) “Methanol synthesis on a Cu (100) catalyst” Catal Lett
10:383–390
71. Chinchen GC, Waugh KC, Whan DA (1986) “The activity and state of the copper surface in
methanol synthesis catalysts” Appl Catal 25:101–107
72. Rasmussen PB, Kazuta M, Chorkendorff I (1994) “Synthesis of methanol from a mixture of
H 2 and CO 2 on Cu (100)” Surf Sci 318(3):267–280
73. Rasmussen PB, Holmblad PM, Askgaard T, Ovesen CV, Stoltze P, Nørskov JK, Chorkendorff
I (1994) “Methanol synthesis on Cu (100) from a binary gas mixture of CO 2 and H 2 ” Catal
Lett 26:373–381
74. Yoshihara J, Campbell CT (1996) “Methanol synthesis and reverse water–gas shift kinetics
over Cu (110) model catalysts: structural sensitivity” J Catal 161(2):776–782
75. Yoshihara J, Parker SC, Schafer A, Campbell CT (1995) “Methanol synthesis and reverse
water-gas shift kinetics over clean polycrystalline copper” Catal Lett 31:313–324
76. Chen HY, Lau SP, Chen L, Lin J, Huan CHA, Tan KL, Pan JS (1999) “Synergism between Cu
and Zn sites in Cu/Zn catalysts for methanol synthesis” Appl Surf Sci 152(3–4):193–199
77. Hansen PL, Wagner JB, Helveg S, Rostrup-Nielsen JR, Clausen BS, Topsøe H (2002) “Atomresolved imaging of dynamic shape changes in supported copper nanocrystals” Science
295(5562):2053–2055
78. Ovesen CV, Clausen BS, Schiotz J, Stoltze P, Topsøe H, Nørskov JK (1997) “Kinetic implications of dynamical changes in catalyst morphology during methanol synthesis over Cu/ZnO
catalysts” J Catal 168(2):133–142
79. Liu X, Lu GQ, Yan Z, Beltramini J (2003) “Recent advances in catalysts for methanol synthesis via hydrogenation of CO and CO 2 ” Ind Eng Chem Res 42(25):6518–6530
80. Twigg MV, Spencer MS (2001) “Deactivation of supported copper metal catalysts for hydrogenation reactions” Appl Catal A Gen 212(1–2):161–174
81. Jadhav SG, Vaidya PD, Bhanage BM, Joshi JB (2014) “Catalytic carbon dioxide hydrogenation to methanol: A review of recent studies” Chem Eng Res Des 92(11):2557–2567
82. Álvarez A, Bansode A, Urakawa A, Bavykina AV, Wezendonk TA, Makkee M, Gascon J,
Kapteijn F (2017) “Challenges in the greener production of formates/formic acid, methaK. Tripathi et al.