593
38. Studt F, Behrens M, Kunkes EL, Thomas N, Zander S, Tarasov A, Schumann J, Frei E, Varley
JB, Abild-Pedersen F, Nørskov JK, Schlögl R (2015) “The Mechanism of CO and CO 2 hydrogenation to methanol over Cu-based catalysts” ChemCatChem 7(7):1105–1111
39. Kandemir T, Friedrich M, Parker SF, Studt F, Lennon D, Schlogl R, Behrens M (2016)
“Different routes to methanol: inelastic neutron scattering spectroscopy of adsorbates on supported copper catalysts” Phys Chem Chem Phys 18:17253–17258
40. Waugh KC (1992) “Methanol synthesis” Catal Today 15(1):51–75
41. Frenzel J, Marx D (2014) “Methanol synthesis on ZnO(000ī). IV. reaction mechanisms and
electronic structure” J Chem Phys 141:124710
42. Behrens M, Studt F, Kasatkin I, Kühl S, Hävecker M, Abild-pedersen F, Zander S, Girgsdies
F, Kurr P, Kniep B, Tovar M, Fischer RW, Nørskov JK, Schlögl R (2012) “The active site of
methanol synthesis over Cu/ZnO/Al 2 O 3 industrial catalysts” Science 759:893–897
43. Klier K (1982) “Methanol synthesis” Adv Catal 31:243–313
44. Chinchen GC, Denny PJ, Parker DG, Spencer MS, Whan DA (1987) “Mechanism of methanol synthesis from CO 2 /CO/H 2 mixtures over copper/zinc oxide/alumina catalysts: Use of
14
C-labelled reactants” Appl Catal 30(2):333–338
45. Liu YM, Liu JT, Liu SZ, Li J, Gao ZH, Zuo ZJ, Huang W (2017) “Reaction mechanisms of
methanol synthesis from CO/CO 2 hydrogenation on Cu 2 O (111): Comparison with Cu (111)”
J CO 2 Util 20:59–65
46. Kunkes EL, Studt F, Abild-pedersen F, Schlögl R, Behrens M (2015) “Hydrogenation of
CO 2 to methanol and CO on Cu/ZnO/Al 2 O 3 : Is there a common intermediate or not?” J Catal
328:43–48
47. Taylor PA, Rasmussen PB, Chorkendorff IJ (1995) “Is the observed hydrogenation of formate
the rate-limiting step in methanol synthesis?” J Chem Soc Faraday Trans 91:1267–1269
48. Yatsu T, Nishimura H, Fujitani T, Nakamura J (2000) “Synthesis and decomposition of formate on a Cu/SiO 2 catalyst: Comparison to Cu (111)” J Catal 191(2):423–429
49. Kattel S, Chen JG, Liu P (2017) “Active sites for CO 2 hydrogenation to methanol on Cu/ZnO
catalysts” Science 355:1296–1299
50. Edwards JF (1984) “In situ characterization of adsorbed species on methanol synthesis catalysts by FT-IR spectroscopy” Ph.D. thesis, Iowa State University, Ames
51. Fujitani T, Choi Y, Sano M, Kushida Y, Nakamura J (2000) “Scanning tunneling microscopy
study of formate species synthesized from CO 2 hydrogenation and prepared by adsorption of
formic acid over Cu (111)” J Phys Chem B 104(6):1235–1240
52. Fujitani T, Nakamura I, Ueno S, Uchijima T, Nakamura J (1997) “Methanol synthesis by
hydrogenation of CO 2 over a Zn-deposited Cu (111): formate intermediate” Appl Surf Sci
121-122:583–586
53. Millar GJ, Rochester CH, Howe C, Waugh KC (1992) “Vapour liquid equilibria of the
lennard- jones fluid from the NpT plus test particle method” Mol Phys 76(4):833–849
54. Nakano H, Nakamura I, Fujitani T, Nakamura J (2001) “Structure-dependent kinetics for
synthesis and decomposition of formate species over Cu (111) and Cu (110) model catalysts”
J Phys Chem B 105(7):1355–1365
55. Nishimura H, Yatsu T, Fujitani T, Uchijima T, Nakamura JJ (2000) “Synthesis and decomposition of formate on a Cu (111) surface- kinetic analysis” J Mol Catal A Chem 155(1–2):3–11
56. Taylor PA, Rasmussen PB, Ovesen CV, Stoltze P, Chorkendorff I (1992) “Formate synthesis
on Cu (100)” Surf Sci 261(1–3):191–206
57. Youngs TGA, Haq S, Bowker M (2008) “Formic acid adsorption and oxidation on Cu (110)”
Surf Sci 602(10):1775–1782
58. Sotiropoulos A, Milligan PK, Cowie BCC, Kadodwala M (2000) “A structural study of formate on Cu (111)” Surf Sci 444:52–60
59. Ying DHS, Madix RJ (1980) “Thermal desorption study of formic acid decomposition on a
clean Cu (110) Surface” J Catal 61(1):48–56
Perspectives in Carbon Oxides Conversion to Methanol/Dimethyl Ether: Distinctive…
38. Studt F, Behrens M, Kunkes EL, Thomas N, Zander S, Tarasov A, Schumann J, Frei E, Varley
JB, Abild-Pedersen F, Nørskov JK, Schlögl R (2015) “The Mechanism of CO and CO 2 hydrogenation to methanol over Cu-based catalysts” ChemCatChem 7(7):1105–1111
39. Kandemir T, Friedrich M, Parker SF, Studt F, Lennon D, Schlogl R, Behrens M (2016)
“Different routes to methanol: inelastic neutron scattering spectroscopy of adsorbates on supported copper catalysts” Phys Chem Chem Phys 18:17253–17258
40. Waugh KC (1992) “Methanol synthesis” Catal Today 15(1):51–75
41. Frenzel J, Marx D (2014) “Methanol synthesis on ZnO(000ī). IV. reaction mechanisms and
electronic structure” J Chem Phys 141:124710
42. Behrens M, Studt F, Kasatkin I, Kühl S, Hävecker M, Abild-pedersen F, Zander S, Girgsdies
F, Kurr P, Kniep B, Tovar M, Fischer RW, Nørskov JK, Schlögl R (2012) “The active site of
methanol synthesis over Cu/ZnO/Al 2 O 3 industrial catalysts” Science 759:893–897
43. Klier K (1982) “Methanol synthesis” Adv Catal 31:243–313
44. Chinchen GC, Denny PJ, Parker DG, Spencer MS, Whan DA (1987) “Mechanism of methanol synthesis from CO 2 /CO/H 2 mixtures over copper/zinc oxide/alumina catalysts: Use of
14
C-labelled reactants” Appl Catal 30(2):333–338
45. Liu YM, Liu JT, Liu SZ, Li J, Gao ZH, Zuo ZJ, Huang W (2017) “Reaction mechanisms of
methanol synthesis from CO/CO 2 hydrogenation on Cu 2 O (111): Comparison with Cu (111)”
J CO 2 Util 20:59–65
46. Kunkes EL, Studt F, Abild-pedersen F, Schlögl R, Behrens M (2015) “Hydrogenation of
CO 2 to methanol and CO on Cu/ZnO/Al 2 O 3 : Is there a common intermediate or not?” J Catal
328:43–48
47. Taylor PA, Rasmussen PB, Chorkendorff IJ (1995) “Is the observed hydrogenation of formate
the rate-limiting step in methanol synthesis?” J Chem Soc Faraday Trans 91:1267–1269
48. Yatsu T, Nishimura H, Fujitani T, Nakamura J (2000) “Synthesis and decomposition of formate on a Cu/SiO 2 catalyst: Comparison to Cu (111)” J Catal 191(2):423–429
49. Kattel S, Chen JG, Liu P (2017) “Active sites for CO 2 hydrogenation to methanol on Cu/ZnO
catalysts” Science 355:1296–1299
50. Edwards JF (1984) “In situ characterization of adsorbed species on methanol synthesis catalysts by FT-IR spectroscopy” Ph.D. thesis, Iowa State University, Ames
51. Fujitani T, Choi Y, Sano M, Kushida Y, Nakamura J (2000) “Scanning tunneling microscopy
study of formate species synthesized from CO 2 hydrogenation and prepared by adsorption of
formic acid over Cu (111)” J Phys Chem B 104(6):1235–1240
52. Fujitani T, Nakamura I, Ueno S, Uchijima T, Nakamura J (1997) “Methanol synthesis by
hydrogenation of CO 2 over a Zn-deposited Cu (111): formate intermediate” Appl Surf Sci
121-122:583–586
53. Millar GJ, Rochester CH, Howe C, Waugh KC (1992) “Vapour liquid equilibria of the
lennard- jones fluid from the NpT plus test particle method” Mol Phys 76(4):833–849
54. Nakano H, Nakamura I, Fujitani T, Nakamura J (2001) “Structure-dependent kinetics for
synthesis and decomposition of formate species over Cu (111) and Cu (110) model catalysts”
J Phys Chem B 105(7):1355–1365
55. Nishimura H, Yatsu T, Fujitani T, Uchijima T, Nakamura JJ (2000) “Synthesis and decomposition of formate on a Cu (111) surface- kinetic analysis” J Mol Catal A Chem 155(1–2):3–11
56. Taylor PA, Rasmussen PB, Ovesen CV, Stoltze P, Chorkendorff I (1992) “Formate synthesis
on Cu (100)” Surf Sci 261(1–3):191–206
57. Youngs TGA, Haq S, Bowker M (2008) “Formic acid adsorption and oxidation on Cu (110)”
Surf Sci 602(10):1775–1782
58. Sotiropoulos A, Milligan PK, Cowie BCC, Kadodwala M (2000) “A structural study of formate on Cu (111)” Surf Sci 444:52–60
59. Ying DHS, Madix RJ (1980) “Thermal desorption study of formic acid decomposition on a
clean Cu (110) Surface” J Catal 61(1):48–56
Perspectives in Carbon Oxides Conversion to Methanol/Dimethyl Ether: Distinctive…