592
15. Alwin M, Mathias P, Karl W (1925) “Production of oxygenated organic compounds”,
US1558559
16. Goeppert A, Czaun M, Jones JP, Surya Prakash GK, Olah GA (2014) “Recycling of carbon
dioxide to methanol and derived products – closing the loop” Chem Soc Rev 43:7995–8048
17. Natta G (1953) P.H. Emmet (Ed.) Catalysis,Vol. III . Reinhold Publishing, New York
18. Basile A, Dalena F (2017) “Methanol production and applications: An overview” Methanol:
science and engineering. Elsevier, Amsterdam
19. Olah GA (2013) “Towards oil independence through renewable methanol chemistry” Angew
Chem Int Ed 52:104–107
20. Asthana S, Samanta C, Bhaumik A, Banerjee B, Voolapalli RK, Saha B (2016) “Direct synthesis of dimethyl ether from syngas over Cu-based catalysts: Enhanced selectivity in the
presence of MgO”J Catal 334:89–101
21. Zhen X, Wang Y (2015) “An overview of methanol as an internal combustion engine fuel”
Renew Sustain Energy Rev 52:477–493
22. Li K, Chen JG (2019) “CO 2 hydrogenation to methanol over ZrO 2 -containing catalysts:
Insights into ZrO 2 induced synergy” ACS Catal 9(9):7840–7861
23. Lee S (1989) “Methanol synthesis technology” CRC press, Boca Raton
24. Graaf GH, Sijtsema PJJM, Stamhuis EJ, Joosten GEH (1986) “Chemical equilibria in methanol synthesis” Chem Eng Sci 41:2883–2890
25. Skrzypek J, Lachowska M, Serafin D (1990) “Methanol synthesis from CO 2 and H 2 : dependence of equilibrium conversions and exit equilibrium concentrations of components on the
main process variables” Chem Eng Sci 45:89–96
26. Chang T, Rousseau RW, Kilpatrick PK (1986) “Methanol synthesis reactions: calculations of equilibrium conversions using equations of state” Ind Eng Chem Process Des Dev
25:477–481
27. Van Bennekom JG, Winkelman JGM, Venderbosch RH, Nieland SDGB, Heeres HJ (2012)
“Modeling and experimental studies on phase and chemical equilibria in high-pressure methanol synthesis” Ind Eng Chem Res 51:12233–12243
28. Van Bennekom JG, Venderbosch RH, Winkelman JGM, Wilbers E, Assink D, Lemmens
KPJ, Heeres HJ (2013) “Methanol synthesis beyond chemical equilibrium” Chem Eng Sci
87:204–208
29. Shen JW, Jun WK, Choi SH, Lee WK (2000) “Thermodynamic investigation of methanol and
dimethyl ether synthesis from CO 2 hydrogenation” Korean J Chem Eng 17:210–216
30. Aguayo TA (2007) “Kinetic modeling of dimethyl ether synthesis in a single step on a CuO−
ZnO−Al 2 O 3 /γ-Al 2 O 3 catalyst” Ind Eng Chem Res 46:5522–5530
31. Qin Z, Su T, Ji H, Chen J (2015) “Experimental and theoretical study of the intrinsic kinetics
for dimethyl ether synthesis from CO 2 over Cu–Fe–Zr/HZSM‐5” AICHE J 61:857–866
32. Bowker M (2019) “Methanol Synthesis from CO 2 hydrogenation” ChemCatChem
11:4238–4246
33. Palma V, Meloni E, Ruocco C, Martino M, Ricca A (2017) “ Chapter 2 “ State of the art of
conventional reactors for methanol production” Methanol: science and engineering. Elsevier,
Amsterdam
34. Spath PL, Dayton DC (2003) “Preliminary screening – technical and economic assessment
of synthesis gas to fuels and chemicals with emphasis on the potential for biomass-derived
syngas” NREL is a US department of energy laboratory
35. Grabow LC, Mavrikakis M (2011) “Mechanism of methanol synthesis on Cu through
CO 2 and CO hydrogenation” ACS Catal 1:365–384
36. Liu G, Willcox D, Garland M, Kung HH (1985) “The role of CO 2 in methanol synthesis on
CuZn oxide: An isotope labeling study” J Catal 96:251–260
37. Yang Y, Mims CA, Mei DH, Peden CHF, Campbell CT (2013) “Mechanistic studies of methanol synthesis over Cu from CO/CO 2 /H 2 /H 2 O mixtures: The source of C in methanol and the
role of water” J Catal 298:10–17
K. Tripathi et al.
15. Alwin M, Mathias P, Karl W (1925) “Production of oxygenated organic compounds”,
US1558559
16. Goeppert A, Czaun M, Jones JP, Surya Prakash GK, Olah GA (2014) “Recycling of carbon
dioxide to methanol and derived products – closing the loop” Chem Soc Rev 43:7995–8048
17. Natta G (1953) P.H. Emmet (Ed.) Catalysis,Vol. III . Reinhold Publishing, New York
18. Basile A, Dalena F (2017) “Methanol production and applications: An overview” Methanol:
science and engineering. Elsevier, Amsterdam
19. Olah GA (2013) “Towards oil independence through renewable methanol chemistry” Angew
Chem Int Ed 52:104–107
20. Asthana S, Samanta C, Bhaumik A, Banerjee B, Voolapalli RK, Saha B (2016) “Direct synthesis of dimethyl ether from syngas over Cu-based catalysts: Enhanced selectivity in the
presence of MgO”J Catal 334:89–101
21. Zhen X, Wang Y (2015) “An overview of methanol as an internal combustion engine fuel”
Renew Sustain Energy Rev 52:477–493
22. Li K, Chen JG (2019) “CO 2 hydrogenation to methanol over ZrO 2 -containing catalysts:
Insights into ZrO 2 induced synergy” ACS Catal 9(9):7840–7861
23. Lee S (1989) “Methanol synthesis technology” CRC press, Boca Raton
24. Graaf GH, Sijtsema PJJM, Stamhuis EJ, Joosten GEH (1986) “Chemical equilibria in methanol synthesis” Chem Eng Sci 41:2883–2890
25. Skrzypek J, Lachowska M, Serafin D (1990) “Methanol synthesis from CO 2 and H 2 : dependence of equilibrium conversions and exit equilibrium concentrations of components on the
main process variables” Chem Eng Sci 45:89–96
26. Chang T, Rousseau RW, Kilpatrick PK (1986) “Methanol synthesis reactions: calculations of equilibrium conversions using equations of state” Ind Eng Chem Process Des Dev
25:477–481
27. Van Bennekom JG, Winkelman JGM, Venderbosch RH, Nieland SDGB, Heeres HJ (2012)
“Modeling and experimental studies on phase and chemical equilibria in high-pressure methanol synthesis” Ind Eng Chem Res 51:12233–12243
28. Van Bennekom JG, Venderbosch RH, Winkelman JGM, Wilbers E, Assink D, Lemmens
KPJ, Heeres HJ (2013) “Methanol synthesis beyond chemical equilibrium” Chem Eng Sci
87:204–208
29. Shen JW, Jun WK, Choi SH, Lee WK (2000) “Thermodynamic investigation of methanol and
dimethyl ether synthesis from CO 2 hydrogenation” Korean J Chem Eng 17:210–216
30. Aguayo TA (2007) “Kinetic modeling of dimethyl ether synthesis in a single step on a CuO−
ZnO−Al 2 O 3 /γ-Al 2 O 3 catalyst” Ind Eng Chem Res 46:5522–5530
31. Qin Z, Su T, Ji H, Chen J (2015) “Experimental and theoretical study of the intrinsic kinetics
for dimethyl ether synthesis from CO 2 over Cu–Fe–Zr/HZSM‐5” AICHE J 61:857–866
32. Bowker M (2019) “Methanol Synthesis from CO 2 hydrogenation” ChemCatChem
11:4238–4246
33. Palma V, Meloni E, Ruocco C, Martino M, Ricca A (2017) “ Chapter 2 “ State of the art of
conventional reactors for methanol production” Methanol: science and engineering. Elsevier,
Amsterdam
34. Spath PL, Dayton DC (2003) “Preliminary screening – technical and economic assessment
of synthesis gas to fuels and chemicals with emphasis on the potential for biomass-derived
syngas” NREL is a US department of energy laboratory
35. Grabow LC, Mavrikakis M (2011) “Mechanism of methanol synthesis on Cu through
CO 2 and CO hydrogenation” ACS Catal 1:365–384
36. Liu G, Willcox D, Garland M, Kung HH (1985) “The role of CO 2 in methanol synthesis on
CuZn oxide: An isotope labeling study” J Catal 96:251–260
37. Yang Y, Mims CA, Mei DH, Peden CHF, Campbell CT (2013) “Mechanistic studies of methanol synthesis over Cu from CO/CO 2 /H 2 /H 2 O mixtures: The source of C in methanol and the
role of water” J Catal 298:10–17
K. Tripathi et al.