595
nol, and DME by heterogeneously catalyzed CO 2 hydrogenation processes” Chem Rev
117(14):9804–9838
83. Li MMJ, Tsang SCE (2018) “Bimetallic catalysts for green methanol production via CO 2 and
renewable hydrogen: a mini-review and prospects” Cat Sci Technol 8:3450–3464
84. Ye J, Liu C, Mei D, Ge Q (2013) “Active oxygen vacancy site for methanol synthesis from
CO 2 hydrogenation on In 2 O 3 (110): A DFT study” ACS Catal 3(6):1296–1306
85. Ye J, Liu C, Ge Q (2012) “DFT study of CO 2 adsorption and hydrogenation on the In 2 O 3
surface” J Phys Chem C 116(14):7817–7825
86. Sun K, Fan Z, Ye J, Yan J, Ge Q, Li Y, He W, Yang W, Liu CJ (2015) “Hydrogenation of CO 2
to methanol over In 2 O 3 catalyst” J CO 2 Util 12:1–6
87. Martin O, Martin AJ, Mondelli C, Mitchell S, Segawa TF, Hauert R, Drouilly C, CurullaFerré D, Pérez-Ramírez J (2016) “Indium oxide as a superior catalyst for methanol synthesis
by CO 2 hydrogenation” Angew Chem Int Ed 55:6261–6265
88. Dou M, Zhang M, Chen Y, Yu Y (2018) “Theoretical study of methanol synthesis from CO 2
and CO hydrogenation on the surface of ZrO 2 supported In 2 O 3 catalyst” Surf Sci 672-673:7–12
89. Akkharaphatthawon N, Chanlek N, Cheng CK, Chareonpanich M, limtrakul J, Witoon T
(2019) “Tuning adsorption properties of Ga x In 2−x O 3 catalysts for enhancement of methanol synthesis activity from CO 2 hydrogenation at high reaction temperature” Appl Surf Sci
489(30):278–286
90. Chou CY, Lobo RF (2019) “Direct conversion of CO 2 into methanol over promoted indium
oxide-based catalysts” Appl Catal A Gen 583:117144
91. Men YL, Liu Y, Wang Q, Luo Z, Shao S, Li Y, Pan Y (2019) “Highly dispersed Pt-based
catalysts for selective CO 2 hydrogenation to methanol at atmospheric pressure” Chem Eng
Sci 200:167–175
92. Ye J, Liu CJ, Mei D, Ge Q (2014) “Methanol synthesis from CO 2 hydrogenation over a Pd 4 /
In 2 O 3 model catalyst: A combined DFT and kinetic study” J Catal 317:44–53
93. Ye J, Ge Q, Liu C (2015) “Effect of PdIn bimetallic particle formation on CO 2 reduction over
the Pd–In/SiO 2 catalyst” Chem Eng Sci 135(2):193–201
94. Rungtaweevoranit B, Baek J, Araujo JR, Archanjo BS, Choi KM, Yaghi OM, Somorjai GA
(2016) “Copper nanocrystals encapsulated in Zr-based metal organic frameworks for highly
selective CO 2 hydrogenation to methanol” Nano Lett 16(12):7645–7649
95. Kobayashi H, Taylor JM, Mitsuka Y, Ogiwara N, Yamamoto T, Toriyama T, Matsumura
S, Kitagawa H (2019) “Charge transfer dependence on CO 2 hydrogenation activity to
methanol in Cu nanoparticles covered with metal–organic framework systems” Chem Sci
10(11):3289–3294
96. An B, Zhang J, Cheng K, Ji P, Wang C, Lin W (2017) “Confinement of ultrasmall Cu/ZnOx
nanoparticles in metal organic frameworks for selective methanol synthesis from catalytic
hydrogenation of CO 2 ” J Am Chem Soc 139(10):3834–3840
97. Kunkel C, Vin F (2016) “Transition metal carbides as novel materials for CO 2 capture, storage, and activation” Energ Environ Sci 9:141–144
98. Vidal AB, Feria L, Evans J, Takahashi Y, Liu P, Nakamura K, Illas F, Rodriguez JA (2012)
“CO 2 activation and methanol synthesis on novel Au/TiC and Cu/TiC catalysts” J Phys Chem
Lett 3(16):2275–2280
99. Rodriguez JA, Evans J, Feria L, Vidal AB, Liu P, Nakamura K (2013) “CO 2 hydrogenation
on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane” J Catal
307:162–169
100. Posada-Pérez S, Ramírez PJ, Gutiérrez RA, Stacchiola DJ, Viñes F, Liu P, Llas F, Rodriguez
JA (2016) “The conversion of CO 2 to methanol on orthorhombic β-Mo 2 C and Cu/β-Mo 2 C
catalysts: mechanism for admetal induced change in the selectivity and activity” Cat Sci
Technol 6:6766–6777
101. Geng W, Han H, Liu F, Liu X, Xiao L, Wu W (2017) “N,P,S-codoped C@nano-Mo 2 C as an
efficient catalyst for high selective synthesis of methanol from CO 2 hydrogenation” J CO 2
Util 21:64–71
Perspectives in Carbon Oxides Conversion to Methanol/Dimethyl Ether: Distinctive…
nol, and DME by heterogeneously catalyzed CO 2 hydrogenation processes” Chem Rev
117(14):9804–9838
83. Li MMJ, Tsang SCE (2018) “Bimetallic catalysts for green methanol production via CO 2 and
renewable hydrogen: a mini-review and prospects” Cat Sci Technol 8:3450–3464
84. Ye J, Liu C, Mei D, Ge Q (2013) “Active oxygen vacancy site for methanol synthesis from
CO 2 hydrogenation on In 2 O 3 (110): A DFT study” ACS Catal 3(6):1296–1306
85. Ye J, Liu C, Ge Q (2012) “DFT study of CO 2 adsorption and hydrogenation on the In 2 O 3
surface” J Phys Chem C 116(14):7817–7825
86. Sun K, Fan Z, Ye J, Yan J, Ge Q, Li Y, He W, Yang W, Liu CJ (2015) “Hydrogenation of CO 2
to methanol over In 2 O 3 catalyst” J CO 2 Util 12:1–6
87. Martin O, Martin AJ, Mondelli C, Mitchell S, Segawa TF, Hauert R, Drouilly C, CurullaFerré D, Pérez-Ramírez J (2016) “Indium oxide as a superior catalyst for methanol synthesis
by CO 2 hydrogenation” Angew Chem Int Ed 55:6261–6265
88. Dou M, Zhang M, Chen Y, Yu Y (2018) “Theoretical study of methanol synthesis from CO 2
and CO hydrogenation on the surface of ZrO 2 supported In 2 O 3 catalyst” Surf Sci 672-673:7–12
89. Akkharaphatthawon N, Chanlek N, Cheng CK, Chareonpanich M, limtrakul J, Witoon T
(2019) “Tuning adsorption properties of Ga x In 2−x O 3 catalysts for enhancement of methanol synthesis activity from CO 2 hydrogenation at high reaction temperature” Appl Surf Sci
489(30):278–286
90. Chou CY, Lobo RF (2019) “Direct conversion of CO 2 into methanol over promoted indium
oxide-based catalysts” Appl Catal A Gen 583:117144
91. Men YL, Liu Y, Wang Q, Luo Z, Shao S, Li Y, Pan Y (2019) “Highly dispersed Pt-based
catalysts for selective CO 2 hydrogenation to methanol at atmospheric pressure” Chem Eng
Sci 200:167–175
92. Ye J, Liu CJ, Mei D, Ge Q (2014) “Methanol synthesis from CO 2 hydrogenation over a Pd 4 /
In 2 O 3 model catalyst: A combined DFT and kinetic study” J Catal 317:44–53
93. Ye J, Ge Q, Liu C (2015) “Effect of PdIn bimetallic particle formation on CO 2 reduction over
the Pd–In/SiO 2 catalyst” Chem Eng Sci 135(2):193–201
94. Rungtaweevoranit B, Baek J, Araujo JR, Archanjo BS, Choi KM, Yaghi OM, Somorjai GA
(2016) “Copper nanocrystals encapsulated in Zr-based metal organic frameworks for highly
selective CO 2 hydrogenation to methanol” Nano Lett 16(12):7645–7649
95. Kobayashi H, Taylor JM, Mitsuka Y, Ogiwara N, Yamamoto T, Toriyama T, Matsumura
S, Kitagawa H (2019) “Charge transfer dependence on CO 2 hydrogenation activity to
methanol in Cu nanoparticles covered with metal–organic framework systems” Chem Sci
10(11):3289–3294
96. An B, Zhang J, Cheng K, Ji P, Wang C, Lin W (2017) “Confinement of ultrasmall Cu/ZnOx
nanoparticles in metal organic frameworks for selective methanol synthesis from catalytic
hydrogenation of CO 2 ” J Am Chem Soc 139(10):3834–3840
97. Kunkel C, Vin F (2016) “Transition metal carbides as novel materials for CO 2 capture, storage, and activation” Energ Environ Sci 9:141–144
98. Vidal AB, Feria L, Evans J, Takahashi Y, Liu P, Nakamura K, Illas F, Rodriguez JA (2012)
“CO 2 activation and methanol synthesis on novel Au/TiC and Cu/TiC catalysts” J Phys Chem
Lett 3(16):2275–2280
99. Rodriguez JA, Evans J, Feria L, Vidal AB, Liu P, Nakamura K (2013) “CO 2 hydrogenation
on Au/TiC, Cu/TiC, and Ni/TiC catalysts: Production of CO, methanol, and methane” J Catal
307:162–169
100. Posada-Pérez S, Ramírez PJ, Gutiérrez RA, Stacchiola DJ, Viñes F, Liu P, Llas F, Rodriguez
JA (2016) “The conversion of CO 2 to methanol on orthorhombic β-Mo 2 C and Cu/β-Mo 2 C
catalysts: mechanism for admetal induced change in the selectivity and activity” Cat Sci
Technol 6:6766–6777
101. Geng W, Han H, Liu F, Liu X, Xiao L, Wu W (2017) “N,P,S-codoped C@nano-Mo 2 C as an
efficient catalyst for high selective synthesis of methanol from CO 2 hydrogenation” J CO 2
Util 21:64–71
Perspectives in Carbon Oxides Conversion to Methanol/Dimethyl Ether: Distinctive…