499
79. Sonal, Pant KK, Upadhyayula S (2017) Synergistic effect of Fe–Co bimetallic catalyst on
FTS and WGS activity in the Fischer–Tropsch process: a kinetic study. Ind Eng Chem Res
56:4659–4671. https://doi.org/10.1021/acs.iecr.6b04517
80. van der Laan GP, Beenackers AACM (1999) Kinetics and selectivity of the Fischer-Tropsch
synthesis: a literature review. Catal Rev Sci Eng 41:255–318. https://doi.org/10.1016/j.
apcata.2013.10.061
81. Rautavuoma AOI, Vanderbaan HS (1981) Kinetics and mechanism of the Fischer-Tropsch
hydrocarbon synthesis on a cobalt on alumina catalyst. Appl Catal 1:247–272
82. Satterfield CN, Huff GA, Longwell JP (1982) Product distribution from iron catalysts in
Fischer-Tropsch slurry reactors. Ind Eng Chem Process Des Dev 21:465–470. https://doi.
org/10.1021/i200018a020
83. Deng L-J, Huo C-F, Liu X-W, Zhao X-H, Li Y-W, Wang J et al (2010) Density functional
theory study on surface CxHy formation from CO activation on Fe3C(100). J Phys Chem C
114:21585–21592. https://doi.org/10.1021/jp108480e
84. Gracia JM, Prinsloo FF, Niemantsverdriet JW (2009) Mars-van Krevelen-like mechanism of CO hydrogenation on an iron carbide surface. Catal Lett 133:257–261. https://doi.
org/10.1007/s10562- 009- 0179- 5
85. Dijk V (2001) The Fischer-Tropsch synthesis: A mechanistic study using transient isotopic
tracing , Eindhoven University of Technology, (Thesis)
86. Anderson RB, Karn FS (1960) A rate equation for the Fischer-Tropsch synthesis on iron
catalysts. J Phys Chem 64:805–808. https://doi.org/10.1021/j100835a025
87. van der Laan GP, Beenackers AACM, Krishna R (1999) Multicomponent reaction engineering
model for Fe-catalyzed Fischer–Tropsch synthesis in commercial scale slurry bubble column
reactors. Chem Eng Sci 54:5013–5019. https://doi.org/10.1016/S0009- 2509(99)00225- 0
88. Yates IC, Satterfield CN (1989) Effect of carbon dioxide on the kinetics of the FischerTropsch synthesis on iron catalysts. Ind Eng Chem Res 28:9–12. https://doi.org/10.1021/
ie00085a003
89. Teng BT, Chang J, Zhang CH, Cao DB, Yang J, Liu Y et al (2006) A comprehensive kinetics model of Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst. Appl Catal A Gen
301:39–50. https://doi.org/10.1016/j.apcata.2005.11.014
90. Sonal, Pant KK, Upadhyayula S (2019) Detailed kinetics of Fischer Tropsch synthesis
over Fe-Co bimetallic catalyst considering chain length dependent olefin desorption. Fuel
236:1263. https://doi.org/10.1016/j.fuel.2018.09.087
91. Todic B, Bhatelia T, Froment GF, Ma W, Jacobs G, Davis BH et al (2013) Kinetic model of
Fischer–Tropsch synthesis in a slurry reactor on co–re/Al 2 O 3 catalyst. Ind Eng Chem Res
52:669–679. https://doi.org/10.1021/ie3028312
92. Zhang R, Chang J, Xu Y, Cao L, Li Y, Zhou J (2009) Kinetic model of product distribution over fe catalyst for Fischer-Tropsch synthesis. Energy Fuel 23:4740–4747. https://doi.
org/10.1021/ef801079u
93. Qian W, Zhang H, Ying W, Fang D (2013) The comprehensive kinetics of Fischer-Tropsch
synthesis over a Co/AC catalyst on the basis of CO insertion mechanism. Chem Eng J
228:526–534. https://doi.org/10.1016/j.cej.2013.05.039
94. Arsalanfar M, Mirzaei AA, Atashi H, Bozorgzadeh HR, Vahid S, Zare A (2012) An investigation of the kinetics and mechanism of Fischer–Tropsch synthesis on Fe–Co–Mn supported
catalyst. Fuel Process Technol 96:150–159. https://doi.org/10.1016/j.fuproc.2011.12.018.
95. Arsalanfar M, Mirzaei AA, Bozorgzadeh HR (2013) Effect of preparation method on catalytic
performance, structure and surface reaction rates of MgO supported Fe–Co–Mn catalyst for
CO hydrogenation. J Ind Eng Chem 19:478–487. https://doi.org/10.1016/j.jiec.2012.08.030
96. Anderson RB, Friedel RA, Storch HH (1951) Fischer-Tropsch reaction mechanism involving
stepwise growth of carbon chain. J Chem Phys 19:313. https://doi.org/10.1063/1.1748201.
97. Zhan X, Davis BH (2000) Two alpha Fischer-Tropsch product distribution. A role
for vapor- liquid equilibrium. Pet Sci Technol 18:1037–1053. https://doi.org/10.1080/
10916460008949890
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…
79. Sonal, Pant KK, Upadhyayula S (2017) Synergistic effect of Fe–Co bimetallic catalyst on
FTS and WGS activity in the Fischer–Tropsch process: a kinetic study. Ind Eng Chem Res
56:4659–4671. https://doi.org/10.1021/acs.iecr.6b04517
80. van der Laan GP, Beenackers AACM (1999) Kinetics and selectivity of the Fischer-Tropsch
synthesis: a literature review. Catal Rev Sci Eng 41:255–318. https://doi.org/10.1016/j.
apcata.2013.10.061
81. Rautavuoma AOI, Vanderbaan HS (1981) Kinetics and mechanism of the Fischer-Tropsch
hydrocarbon synthesis on a cobalt on alumina catalyst. Appl Catal 1:247–272
82. Satterfield CN, Huff GA, Longwell JP (1982) Product distribution from iron catalysts in
Fischer-Tropsch slurry reactors. Ind Eng Chem Process Des Dev 21:465–470. https://doi.
org/10.1021/i200018a020
83. Deng L-J, Huo C-F, Liu X-W, Zhao X-H, Li Y-W, Wang J et al (2010) Density functional
theory study on surface CxHy formation from CO activation on Fe3C(100). J Phys Chem C
114:21585–21592. https://doi.org/10.1021/jp108480e
84. Gracia JM, Prinsloo FF, Niemantsverdriet JW (2009) Mars-van Krevelen-like mechanism of CO hydrogenation on an iron carbide surface. Catal Lett 133:257–261. https://doi.
org/10.1007/s10562- 009- 0179- 5
85. Dijk V (2001) The Fischer-Tropsch synthesis: A mechanistic study using transient isotopic
tracing , Eindhoven University of Technology, (Thesis)
86. Anderson RB, Karn FS (1960) A rate equation for the Fischer-Tropsch synthesis on iron
catalysts. J Phys Chem 64:805–808. https://doi.org/10.1021/j100835a025
87. van der Laan GP, Beenackers AACM, Krishna R (1999) Multicomponent reaction engineering
model for Fe-catalyzed Fischer–Tropsch synthesis in commercial scale slurry bubble column
reactors. Chem Eng Sci 54:5013–5019. https://doi.org/10.1016/S0009- 2509(99)00225- 0
88. Yates IC, Satterfield CN (1989) Effect of carbon dioxide on the kinetics of the FischerTropsch synthesis on iron catalysts. Ind Eng Chem Res 28:9–12. https://doi.org/10.1021/
ie00085a003
89. Teng BT, Chang J, Zhang CH, Cao DB, Yang J, Liu Y et al (2006) A comprehensive kinetics model of Fischer-Tropsch synthesis over an industrial Fe-Mn catalyst. Appl Catal A Gen
301:39–50. https://doi.org/10.1016/j.apcata.2005.11.014
90. Sonal, Pant KK, Upadhyayula S (2019) Detailed kinetics of Fischer Tropsch synthesis
over Fe-Co bimetallic catalyst considering chain length dependent olefin desorption. Fuel
236:1263. https://doi.org/10.1016/j.fuel.2018.09.087
91. Todic B, Bhatelia T, Froment GF, Ma W, Jacobs G, Davis BH et al (2013) Kinetic model of
Fischer–Tropsch synthesis in a slurry reactor on co–re/Al 2 O 3 catalyst. Ind Eng Chem Res
52:669–679. https://doi.org/10.1021/ie3028312
92. Zhang R, Chang J, Xu Y, Cao L, Li Y, Zhou J (2009) Kinetic model of product distribution over fe catalyst for Fischer-Tropsch synthesis. Energy Fuel 23:4740–4747. https://doi.
org/10.1021/ef801079u
93. Qian W, Zhang H, Ying W, Fang D (2013) The comprehensive kinetics of Fischer-Tropsch
synthesis over a Co/AC catalyst on the basis of CO insertion mechanism. Chem Eng J
228:526–534. https://doi.org/10.1016/j.cej.2013.05.039
94. Arsalanfar M, Mirzaei AA, Atashi H, Bozorgzadeh HR, Vahid S, Zare A (2012) An investigation of the kinetics and mechanism of Fischer–Tropsch synthesis on Fe–Co–Mn supported
catalyst. Fuel Process Technol 96:150–159. https://doi.org/10.1016/j.fuproc.2011.12.018.
95. Arsalanfar M, Mirzaei AA, Bozorgzadeh HR (2013) Effect of preparation method on catalytic
performance, structure and surface reaction rates of MgO supported Fe–Co–Mn catalyst for
CO hydrogenation. J Ind Eng Chem 19:478–487. https://doi.org/10.1016/j.jiec.2012.08.030
96. Anderson RB, Friedel RA, Storch HH (1951) Fischer-Tropsch reaction mechanism involving
stepwise growth of carbon chain. J Chem Phys 19:313. https://doi.org/10.1063/1.1748201.
97. Zhan X, Davis BH (2000) Two alpha Fischer-Tropsch product distribution. A role
for vapor- liquid equilibrium. Pet Sci Technol 18:1037–1053. https://doi.org/10.1080/
10916460008949890
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…