496
24. Wang CJ, Ekerdt JG (1984) Evidence for alkyl intermediates during Fischer-Tropsch
synthesis and their relation to hydrocarbon products. J Catal 86:239–244. https://doi.
org/10.1016/0021- 9517(84)90369- 5
25. Schulz H, Erich E, Gorre H, van Steen E (1990) Regularities of selectivity as a key for discriminating FT-surface reactions and formation of the dynamic system. Catal Lett 7:157–167.
https://doi.org/10.1007/BF00764499
26. Ertl, G. (Gerhard), International Union of Pure and Applied Chemistry., Federation of
European Chemical Societies., European Federation of Chemical Engineering., & Dechema.
(1984). 8th International Congress on Catalysis, Berlin (West), 2–6 July 1984:proceedings.
Verlag Chemie.
27. Maitlis PM (2004) Fischer-Tropsch, organometallics, and other friends. J Organomet Chem
689:4366–4374. https://doi.org/10.1016/j.jorganchem.2004.05.037
28. Chang J, Bai L, Teng B, Zhang R, Yang J, Xu Y et al (2007) Kinetic modeling of FischerTropsch synthesis over Fe – Cu – K – SiO 2 catalyst in slurry phase reactor. Chem Eng Sci
62:4983–4991. https://doi.org/10.1016/j.ces.2006.12.031
29. Sari A, Zamani Y, Taheri SA (2009) Intrinsic kinetics of Fischer-Tropsch reactions over an
industrial Co-Ru/γ-Al 2 O 3 catalyst in slurry phase reactor. Fuel Process Technol 90:1305–1313.
https://doi.org/10.1016/j.fuproc.2009.06.024
30. Turner ML, Long HC, Shenton A, Byers PK, Maitlis PM (1995) The Alkenyl mechanism
for Fischer - Tropsch surface methylene polymerisation; the reactions of vinylic probes with
CO/H, over rhodium catalysts. Chem Eur J 1:549–556
31. Ndlovu SB, Phala NS, Hearshaw-Timme M, Beagly P, Moss JR, Claeys M et al (2002) Some
evidence refuting the alkenyl mechanism for chain growth in iron-based Fischer-Tropsch
synthesis. Catal Today 71:343–349. https://doi.org/10.1016/S0920- 5861(01)00461- 8
32. Storch HH (1951) In: Storch HH, Golumbic N, Anderson RB (eds) In the Fischer-Tropsch
and related synthesis. Wiley, New York
33. Anderson RB, Hofer LJE, Storch HH (1958) The reaction mechanism of Fischer-Tropsch
synthesis. Chem Ing Tech 30:560–566. https://doi.org/10.1002/cite.330300903.
34. Davis BH (2001) Fischer-Tropsch synthesis: current mechanism and futuristic needs. Fuel
Process Technol 71:157–166. https://doi.org/10.1016/S0378- 3820(01)00144- 8
35. Kokes SJ, Keith Hall W, Emmett PH (1957) Fischer-Tropsch synthesis mechanism studies.
The addition of radioactive ethanol to the synthesis gas. Preprints 2:127–138
36. Kummer JT, Emmett PH (1953) Fischer—Tropsch synthesis mechanism studies. The addition of radioactive alcohols to the synthesis gas. J Am Chem Soc 75:5177–5183. https://doi.
org/10.1021/ja01117a008
37. Kummer JT, Podgurski HH, Spencer WB, Emmett PH (1951) Mechanism studies of the
Fischer—Tropsch synthesis. The addition of radioactive alcohol. J Am Chem Soc 73:564–569.
https://doi.org/10.1021/ja01146a018
38. Hall WK, Kokes RJ, Emmett PH (1957) Mechanism studies of the Fischer-Tropsch synthesis.
The addition of radioactive methanol, carbon dioxide and gaseous formaldehyde. J Am Chem
Soc 79:2983–2989. https://doi.org/10.1021/ja01569a001
39. Hall WK, Kokes RJ, Emmett PH (1960) Mechanism studies of the Fischer-Tropsch synthesis:
the incorporation of radioactive ethylene, propionaldehyde and propanol. J Am Chem Soc
82:1027–1037. https://doi.org/10.1021/ja01490a005
40. Dry ME (1990) Fischer-Tropsch process. Commercial aspects. Catal Today 6:183–206.
https://doi.org/10.1016/0920- 5861(90)85002- 6.
41. Anderson KG, Ekerdt JG (1985) Study of Fischer-Tropsch synthesis over Fe SiO2: effect
of diethylamine on hydrocarbon and alcohol production. J Catal 95:602–604. https://doi.
org/10.1016/0021- 9517(85)90138- 1
42. Botes FG, Breman BB (2006) Development and testing of a new macro kinetic expression for
the iron-based low-temperature Fischer-Tropsch reaction. Ind Eng Chem Res 45:7415–7426.
https://doi.org/10.1021/ie060491h
Sonal et al.
24. Wang CJ, Ekerdt JG (1984) Evidence for alkyl intermediates during Fischer-Tropsch
synthesis and their relation to hydrocarbon products. J Catal 86:239–244. https://doi.
org/10.1016/0021- 9517(84)90369- 5
25. Schulz H, Erich E, Gorre H, van Steen E (1990) Regularities of selectivity as a key for discriminating FT-surface reactions and formation of the dynamic system. Catal Lett 7:157–167.
https://doi.org/10.1007/BF00764499
26. Ertl, G. (Gerhard), International Union of Pure and Applied Chemistry., Federation of
European Chemical Societies., European Federation of Chemical Engineering., & Dechema.
(1984). 8th International Congress on Catalysis, Berlin (West), 2–6 July 1984:proceedings.
Verlag Chemie.
27. Maitlis PM (2004) Fischer-Tropsch, organometallics, and other friends. J Organomet Chem
689:4366–4374. https://doi.org/10.1016/j.jorganchem.2004.05.037
28. Chang J, Bai L, Teng B, Zhang R, Yang J, Xu Y et al (2007) Kinetic modeling of FischerTropsch synthesis over Fe – Cu – K – SiO 2 catalyst in slurry phase reactor. Chem Eng Sci
62:4983–4991. https://doi.org/10.1016/j.ces.2006.12.031
29. Sari A, Zamani Y, Taheri SA (2009) Intrinsic kinetics of Fischer-Tropsch reactions over an
industrial Co-Ru/γ-Al 2 O 3 catalyst in slurry phase reactor. Fuel Process Technol 90:1305–1313.
https://doi.org/10.1016/j.fuproc.2009.06.024
30. Turner ML, Long HC, Shenton A, Byers PK, Maitlis PM (1995) The Alkenyl mechanism
for Fischer - Tropsch surface methylene polymerisation; the reactions of vinylic probes with
CO/H, over rhodium catalysts. Chem Eur J 1:549–556
31. Ndlovu SB, Phala NS, Hearshaw-Timme M, Beagly P, Moss JR, Claeys M et al (2002) Some
evidence refuting the alkenyl mechanism for chain growth in iron-based Fischer-Tropsch
synthesis. Catal Today 71:343–349. https://doi.org/10.1016/S0920- 5861(01)00461- 8
32. Storch HH (1951) In: Storch HH, Golumbic N, Anderson RB (eds) In the Fischer-Tropsch
and related synthesis. Wiley, New York
33. Anderson RB, Hofer LJE, Storch HH (1958) The reaction mechanism of Fischer-Tropsch
synthesis. Chem Ing Tech 30:560–566. https://doi.org/10.1002/cite.330300903.
34. Davis BH (2001) Fischer-Tropsch synthesis: current mechanism and futuristic needs. Fuel
Process Technol 71:157–166. https://doi.org/10.1016/S0378- 3820(01)00144- 8
35. Kokes SJ, Keith Hall W, Emmett PH (1957) Fischer-Tropsch synthesis mechanism studies.
The addition of radioactive ethanol to the synthesis gas. Preprints 2:127–138
36. Kummer JT, Emmett PH (1953) Fischer—Tropsch synthesis mechanism studies. The addition of radioactive alcohols to the synthesis gas. J Am Chem Soc 75:5177–5183. https://doi.
org/10.1021/ja01117a008
37. Kummer JT, Podgurski HH, Spencer WB, Emmett PH (1951) Mechanism studies of the
Fischer—Tropsch synthesis. The addition of radioactive alcohol. J Am Chem Soc 73:564–569.
https://doi.org/10.1021/ja01146a018
38. Hall WK, Kokes RJ, Emmett PH (1957) Mechanism studies of the Fischer-Tropsch synthesis.
The addition of radioactive methanol, carbon dioxide and gaseous formaldehyde. J Am Chem
Soc 79:2983–2989. https://doi.org/10.1021/ja01569a001
39. Hall WK, Kokes RJ, Emmett PH (1960) Mechanism studies of the Fischer-Tropsch synthesis:
the incorporation of radioactive ethylene, propionaldehyde and propanol. J Am Chem Soc
82:1027–1037. https://doi.org/10.1021/ja01490a005
40. Dry ME (1990) Fischer-Tropsch process. Commercial aspects. Catal Today 6:183–206.
https://doi.org/10.1016/0920- 5861(90)85002- 6.
41. Anderson KG, Ekerdt JG (1985) Study of Fischer-Tropsch synthesis over Fe SiO2: effect
of diethylamine on hydrocarbon and alcohol production. J Catal 95:602–604. https://doi.
org/10.1016/0021- 9517(85)90138- 1
42. Botes FG, Breman BB (2006) Development and testing of a new macro kinetic expression for
the iron-based low-temperature Fischer-Tropsch reaction. Ind Eng Chem Res 45:7415–7426.
https://doi.org/10.1021/ie060491h
Sonal et al.