478
Table 2 (continued)
Rate expression
Reaction condition
References
R
k K K K
P P
P
CH
M
H
C O
H O
4
2
2
7
4 6 3
3
2
=








∗
[ ]
R
kK K K
P P
P
n
n
n
n
j
j
C H
H
C O
H O
2 2
2
2
7 4 6 3
3
2
2
2
+
=








∏
∗
[ ] ≥
=
α
R
k
n
n
n
n
n
j
j
C H
2
8
2
1
2
=
−
(
)∏ ∗
[ ] ≥
+
=
β
α
∗
[ ] =
+
+
+
+
+
1
1
4
1
2 1
3
2
6 4
0 5
3
2
2
2
2
2
2
K P
K P
K K P P
K P P
P
K K K P
H
C O
C O H
H
C O
H O
H
.
.
5 5
6
2
6
4
2
2
2
2
2
2
1
P
P
K P P
P
K K P
n
i
i
j
j
CO
H O
H
C O
H O
H
+
+
(
) ∑ ∏






=
=
α
α
β
n
n
k K P P
P
k K P P
P
kK K P
k
=
(
)
(
) +
+
−
(
+
5 3
2
5 3
2
7 6 4
8
2
2
2
2
2
1
CO H
HO
CO H
HO
H
/
/
) ) ∗
[ ]
≥
/
n
2
α
A
CO H
HO
CO H
HO
H
=
∗
[ ]
(
)
∗
[ ]
(
) +
∗
[ ]
k K P P
P
k K P P
P
kK K P
5 3
2
5 3
2
7 6 4
2
2
2
2
2
/
/
+ +
≥
+
k
n
8
2
β
α
α
n
n
i
n
i
k P
k
K P P
P
k
P
n
n
n i
n i
=
+
∑
−
−
−
=
−
− +
− +
8
8
1
3
2
8
2
2
2
2
2
2
C H
A
CO H
H O
A
C
H
2 2
2
2
2
5 3
2
7 6 4
8
k K P P
P
kK K P
k
CO H
HO
H
/
)
∗
[ ] +
∗
[ ] +
(
)








+
Reduced Fe-Mn
Fixed bed reactor
T—267–327 °C
P—1.0–3.0 MPa,
H
2 /
CO-1.0–3.0
Yang et al. [53]
Sonal et al.