479
Rate expression
Reaction condition
References
R
k K K K K P P
CH OH
CO H
3
2
9 1 1 4 7 8
2
2
=
∗
[ ]
,
R
k K P
CH
H
T
4
2
11 1 2
1
2
=
∗
[ ]
,
,
α
R
kK K K K P P
n
n
n
i
i
C H
OH
CO H
T
2 1
2
9 1 4 7 8
2
1
1
2
+
=
∏
∗
[ ]
−
=
α
,
R
k K K P P
K
n
n
n
i
i
C H
OOH
CO H O
T
2 1
2
10 1 7
6
1
1
2
−
=
∏
∗
[ ]
−
=
α
,
R
k K P
n
n
n
i
i
C H
H
T
2 2
2
11 4
1
1
2
+
=
∏
∗
[ ]
−
=
α
,
R
k K P
n
n
n
i
i
n
C H
H
T
2
2
12
4
1
1
=
∏
−
(
)∗
[ ]
=
α
β
,
β
α
n
i
n
i
k P
K P
k K P
n
n
=
∗
[ ]
∏
∗
[ ]
−
=
10
4
10
4
1
2
2
2
C H
H
H
T ,
∗
[ ] =
+ +
+
+
+
+
1
1
1
4
1 7
4
1 7 8
4
6 4 2
2
2
2
2
K P
K P
K K P K P
K K K P P K P
K K K K
CO
H
C O
H
CO H
H
1 1
64 3 2 1
2
6
4
4
1
2
2
2
2
2
2
2
P P
P
K K K K K P P
P
P
K
K P
K P
i
H CO
H O
H CO
H O
H O
H
H
+
+
(
)
+
∑
=
n n
i
i
T i
K K K P P K P
K K P K P
∏
+
+
(
)













=1
17 8
4
1 7
4
1
2
2
2
α
,
C O H
H
C O
H
 


Fe/Mn and Fe/Cu/K
Spinning basket
reactor
T—260–300 °C
P—1.1–2.6 MPa,
H
2 /
CO-0.67–2.05
Teng et al. [89]
(continued)
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…