477
Table 2 Published comprehensive kinetic models for rate of product formation
Rate expression
Reaction condition
References
R
k P K P
CH
M H
H
4
2
2
5
0
1
=
∗
[ ]
α
R
kP K P
n
n
n
n
i
i
j
j
C H
H
H
2 2
2
2
5
0
1 1
2
+
=
∑ ∏
∗
[ ] ≥
= =
α
R
k K P
n
n
n
n
i
i
j
j
n
C H
o H
2
2
6
1 1
1
2
=
∑ ∏
−
(
)∗
[ ] ≥
= =
α
β
∗
[ ] =
+
+ +
+
+








∑
1
1
1
1
1
0
3 2 4
2
4 4
4
0
2
2
2
2
2
K P
P
K K K P
K K P
K
K P
O
i
H
H
H
H
H
/
= =
=
∏
(
)
1
1
n
j
i
j
α
α
1
1
1
5
2
1
=
+
=
(
)
k P
k P
k P
n
CO
CO
M H
α
β
n
n
k P
k P
k P
k
n
=
+
+
−
(
)
(
)
≥
(
)
1
1
5
6
2
1
2
CO
CO
H
β
α
α
n
n
i
n
i
k P
k
k P
k P
k P
k
P
n
n
n i
n
=
+
+
∑
−
−
−
=
−
− +
6
6
1
1
1
5
6
2
2
2
2
2
C H
A
CO
CO
H
A
C
H
− − +
+
+








i
k P
k P
k
2
2
1
5
6
CO
H
α
A
CO
CO
H
=
+
+
(
)
k P
k P
k P
k
1
1
5
6
2
Fixed bed reactor
T—220–270 °C
P—1.1–3.1 MPa,
H
2 /
CO-1.0–3.0
Wang et al. [51]
(continued)
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…