473
Model
Catalyst
Reaction conditions
(i) H
2 O
inhibition
(ii) CO
2
inhibition
(iii) WGS
reaction
(iv) Unassisted
CO
dissociation
(v) H
2 -
assisted CO
dissociation
References
r
kP P
aP
bP
FT
CO H
CO
H
=
+
+
(
)
2
2
0 5
1 5
2
1
.
.
Co/Kieselguhr T:
190 °C
P:
0.2–1.5
H
2 /CO: 0.5–8.3
√
Sarup and
Wojciechowski
[70]
r
kP P
aP
FT
H CO
CO
=
+
(
)
2
1
2
Co/MgO/SiO
2
T:
220–240 °C
P:
1.5–3.5
H
2 /CO: 1.5–3.5
√
Yates and
Satterfield [9]
r
kP P
P
aP
FT
H CO
CO
H O
=
+
2
2
Prep Co/MnO
3 T:
210–250 °C
P:
0.6–2.6 MPa
H
2 /CO: 1.6–4.1
√
√
√
Keyser et al.
[57]
r
kP P
aP
FT
H
C O
CO
=
+
(
)
2
0 74
2
1
.
Co/TiO
2
T:
180–240 °C
P:
2.06 MPa
H
2 /CO: 1–3.5
√
Zonnero et al.
[62]
r
kP P
P P
aP
FT
H CO
CO H
H O
=
+
2
2
2
2
Co/Zr/SiO
2
T:
220–280 °C
P:
2.1 MPa
H
2 /CO: 0.5–2
√
√
Withers et al.
[10]
− =
+
(
)
r
kP P
bP P
FT
H CO
CO H
2
2
1
0 5
2
.
Co/Ni/Al
2 O
3
catalyst
T:
230–270 °C
P:0.2–1.2 MPa
H
2 /CO: 1–3
√, CO
dissociates
via interaction
with H
Fazlollahi
et al. [71]
− =
+
(
)
r
kP P
bP
FT
H
C O
CO
2
0 75 05
0 5
2
1
.
.
.
Co/Pt/Al
2 O
3
T:
230–270 °C
P:
0.5–4 MPa
H
2 /CO: 1.6–3.2
√
Botes at al
[72].
− =
+
(
)
r
kP P
bP
FT
H
C O
CO
2
0 98 05
0 5
2
1
.
.
.
Co–Ru/γAl
2 O
3
T:
200–240 °C
P:
2–3.5 MPa
H
2 /CO: 1–2.5
√
Sari et al. [29]
(continued)
Recent Advancements and Detailed Understanding of Kinetics for Synthesis Gas…