472
Table 1 (continued)
Model
Catalyst
Reaction conditions
(i) H
2 O
inhibition
(ii) CO
2
inhibition
(iii) WGS
reaction
(iv) Unassisted
CO
dissociation
(v) H
2 -
assisted CO
dissociation
References
r
kP P
P P
bP
FT
H CO
H CO
HO
=
+
(
)
2
2
2
2
Reduced
precipitated
Fe/K
T:
220–260 °C
P:
–H
2 /CO: 0.5–2
√
√
Deckwer et al.
[68]
r
kP P
aP
FT
H
C O
CO
=
+
(
)
2
0 5
2
1
.
Fe-based
catalyst
T:
260 °C
P:
1.0–3.0 MPa
H
2 /CO: 0.8–3.2
√
√ adsorbed
CO reacts
with
dissociated
H2
Zhou et al.
[54]
r
kP P
aP
FT
H CO
CO
=
+
(
)
2
1
Fe based
catalyst
T:
260 °C
P:
1.0–3.0 MPa
H
2 /CO: 0.8–3.2
√
√, adsorbed
CO reacts
with
molecular H2
Zhou et al.
[54]
r
kP P
aP
bP
FT
H
C O
CO
H O
=
+
+
(
)
2
2
0 5
2
1
.
Prec. Fe
T:
220–260 °C
P:
0.5–4
H
2 /CO: 0.5–2
√
√
Botes et al.
[42]
r
kP P
aP
FT
CO H
CO
=
+
(
)
0 5 0 875
0 5
2
2
1
.
.
.
FeCuK/AlSi
T:
250 °C
P
H
2
: 0.2–0.9 MPa
P
CO : 0.3–0.89
H
2 /CO: 0.7–1.5
√
Okeson et al.
[69]
r
kP P
aP
bP
FT
CO H
CO
H
=
+
+
(
)
0 5
0 5
1 5
2
2
1
.
.
.
Co/alumina
T:
250 °C
P:
0.015–0.1
H
2 /CO: 0.25–5
√
Outi et al. [59]
r
kP P
aP
bP
FT
CO H
CO
H
=
+
+
(
)
0 5 0 5
0 5
0 5
2
2
2
1
.
.
.
.
Co/Kieselguhr T:
190 °C
P:
0.2–1.5
H
2 /CO: 0.5–8.3
√
Sarup and
Wojciechowski
[70]
Sonal et al.