474
Table 1 (continued)
Model
Catalyst
Reaction conditions
(i) H
2 O
inhibition
(ii) CO
2
inhibition
(iii) WGS
reaction
(iv) Unassisted
CO
dissociation
(v) H
2 -
assisted CO
dissociation
References
r
k P P
P
P
FT
CO
H
H O
H
=
(
)
+
















−0 2 0 5
2
2
2
1 0 93
.
.
.
Co/Al
2 O
3
T:
220 °C
P:
1.99 MPa
H
2 /CO: 1–2.4
√
Das et al. [73]
r
k P P
P
a
P P
P
FT
CO H
HO
CO H
H O
=
(
)
+
















2
2
2
2
1 5
2
1
.
/
Fe, Co
T:
190–310 °C
P
H
2
: 0.01–1.93
P
CO : 0.05–2.54
√
√
Van Steen and
Schulz [50]
− =
+
+
(
)
r
kP P
dP
cP
a
b
CO
CO H
CO
H O
2
2
2
1
Fe, Co
Generalized
Model
√
√
√
Ma et al. [74]
− =
+
(
)
r
kP P
aP
CO
CO H
CO
2
0 75
2
1
.
Fe, Co
Generalized
Model
Mousavi et al.
[75]
− =
∗ ∗ ∗
+
(
)
(
)
r
k a b P P
aP
FT
CO H
CO
2
1 2
0 5
2
.
Nanostructured
Fe-Co-Ce
T:250–330 °C
P:
0.2–1.0 MPa H
2 /
CO:1
√
Eshraghi et al.
[76]
− =
∗ ∗ ∗
+
(
) +
(
)
r
k a b P P
aP
bP
FT
CO H
CO
H
2
2
1 2
0 5
3
.
Fe-Co-Mn
catalyst
T:220–250 °C
P:
0.5–2.0 MPa H
2 /
CO:0.67–2.0
√
Mirzei et al.
[77]
− =
∗ ∗ ∗
+
+
(
)
r
k a b P P
aP
bP
FT
CO H
CO
H
2
2
1
2
Fe-Co-Ni
T:250–270 °C
P:
0.1–0.7 MPa H
2 /
CO: 1–2.5
√
Mirzei et al.
[78]
r
kP P
aP
bP
FT
CO H
CO
H
2
2
1 2
1 2
2
1
/
/
+
+
(
)
Fe-Co/SiO
2
T:200–280 °C
P:
1.0–3.0 MPa H
2 /
CO: 0.5–2.5
√, CO
dissociates
via interaction
with H
Pant et al. [79]
Sonal et al.