31
45. Ramírez J, Macías G, Cedeño L, Gutiérrez-Alejandre A, Cuevas R, Castillo P (2004) The role
of titania in supported Mo, CoMo, NiMo, and NiW hydrodesulfurization catalysts: analysis of
past and new evidences. Catal Today 98:19–30
46. Castillo-Villalón P, Ramírez J, Cuevas R, Vázquez P, Castañeda R (2016) Influence of the support on the catalytic performance of Mo, CoMo, and NiMo catalysts supported on Al 2 O 3 and
TiO 2 during the HDS of thiophene, dibenzothiophene, or 4,6-dimethyldibenzothiophene. Catal
Today 259:140–149
47. Ganiyu SA, Alhooshani K, Ali SA (2017) Single-pot synthesis of Ti-SBA-15-NiMo hydrodesulfurization catalysts: role of calcination temperature on dispersion and activity. Appl Catal B
Environ 203:428–441
48. Fujikawa T, Kimura H, Kiriyama K, Hagiwara K (2006) Development of ultra-deep HDS
catalyst for production of clean diesel fuels. Catal Today 111(3–4):188–193
49. Ding L, Zheng Y, Zhang Z, Chen J (2007) Hydrotreating of light cycle oil using WNi catalysts
containing hydrothermally and chemically treated zeolite Y. Catal Today 125:229–238
50. Nakano K, Ali SA, Kimd H-J, Kim T, Alhooshani K, Park J-I, Mochida I (2013) Deep desulfurization of gas oil over NiMoS catalysts supported on alumina coated USY-zeolite. Fuel
Process Technol 116:44–51
51. Wang Y, Yin C, Zhao X, Liu C (2017) Synthesis of bifunctional highly-loaded NiMoW catalysts and their catalytic performance of 4,6-DMDBT HDS. Catal Commun 88:13–17
52. Han W, Nie H, Long X, Li M, Yang Q, Li D (2017) Effects of the support Brønsted acidity on
the hydrodesulfurization and hydrodenitrogenation activity of sulfided NiMo/Al 2 O 3 catalysts.
Catal Today 292:58–66
53. Zhang L, Dai Q, Wenqian F, Tang T, Dong P, He M, Chen Q (2018) CoMo catalyst
on zeolite TS-1 nanorod assemblies with high activity in the hydrodesulfurization of
4,6- dimethyldibenzothiophene. J Catal 359:130–142
54. Sun H, Sun H, Zhang X, Yu Q, Zeng P, Guo Q, Wang D, Wen G, Zhang W, He S, Shen B (2019)
Effect of divalent tin on the SnSAPO-5 molecular sieve and its modulation to alumina support to
form a highly efficient NiW catalyst for deep desulfurization of 4,6-Dimethyldibenzothiophene.
ACS Catal 9:6613–6623
55. Meng Q, Peng D, Duan A, Zhao Z, Liu J, Shang D, Wang B, Jia Y, Liu C, Hu D (2020) Trimetallic
catalyst supported zirconium modified Threedimensional mesoporous silica material and its
Hydrodesulfurization performance of dibenzothiophene and 4,6- dimethydibenzothiophene.
Ind Eng Chem Res 59(2):654–667
56. Klimova T, Ramirez J, Calderon M, Dominguez JM (1998) New Mo and NiMo catalysts
supported on MCM-41/alumina for thiophene hydrodesulfurization. Stud Surf Sci Catal
117:493–500
57. Song C, Reddy KM (1999) Mesoporous molecular sieve MCM-41 supported co-Mo catalyst
for hydrodesulfurization of dibenzothiophene in distillate fuels. Appl Catal A Gen 176:1–10
58. Klimova T, Calderon M, Ramirez J (2003) Ni and Mo interaction with Al-containing MCM-41
support and its effect on the catalytic behavior in DBT hydrodesulfurization. Appl Catal A Gen
240:29–40
59. Kouzu M, Kuriki Y, Hamdy F, Sakanishi K, Sugimoto Y, Saito I (2004) Catalytic potential of
carbon-supported NiMo-sulfide for ultra-deep hydrodesulfurization of diesel fuel. Appl. Catal
A Gen 265:61–67
60. Gutierrez OY, Perez F, Fuentes GA, Bokhimi X, Klimova T (2008) Deep HDS over NiMo/
Zr-SBA-15 catalysts with varying MoO 3 loading. Catal Today 130:292–301
61. Han D, Li X, Zhang L, Wang Y, Yan Z, Liu S (2012) Hierarchically ordered meso/macroporous γ-alumina for enhanced hydrodesulfurization performance. Microporous Mesoporous
Mater 158:1–6
62. Badoga S, Sharma RV, Dalai AK, Adjaye J (2015) Synthesis and characterization of mesoporous aluminas with different pore sizes: application in NiMo supported catalyst for hydrotreating of heavy gas oil. Appl Catal A Gen 489:86–97
Recent Advances in Hydrotreating/Hydrodesulfurization Catalysts: Part I: Nature…
45. Ramírez J, Macías G, Cedeño L, Gutiérrez-Alejandre A, Cuevas R, Castillo P (2004) The role
of titania in supported Mo, CoMo, NiMo, and NiW hydrodesulfurization catalysts: analysis of
past and new evidences. Catal Today 98:19–30
46. Castillo-Villalón P, Ramírez J, Cuevas R, Vázquez P, Castañeda R (2016) Influence of the support on the catalytic performance of Mo, CoMo, and NiMo catalysts supported on Al 2 O 3 and
TiO 2 during the HDS of thiophene, dibenzothiophene, or 4,6-dimethyldibenzothiophene. Catal
Today 259:140–149
47. Ganiyu SA, Alhooshani K, Ali SA (2017) Single-pot synthesis of Ti-SBA-15-NiMo hydrodesulfurization catalysts: role of calcination temperature on dispersion and activity. Appl Catal B
Environ 203:428–441
48. Fujikawa T, Kimura H, Kiriyama K, Hagiwara K (2006) Development of ultra-deep HDS
catalyst for production of clean diesel fuels. Catal Today 111(3–4):188–193
49. Ding L, Zheng Y, Zhang Z, Chen J (2007) Hydrotreating of light cycle oil using WNi catalysts
containing hydrothermally and chemically treated zeolite Y. Catal Today 125:229–238
50. Nakano K, Ali SA, Kimd H-J, Kim T, Alhooshani K, Park J-I, Mochida I (2013) Deep desulfurization of gas oil over NiMoS catalysts supported on alumina coated USY-zeolite. Fuel
Process Technol 116:44–51
51. Wang Y, Yin C, Zhao X, Liu C (2017) Synthesis of bifunctional highly-loaded NiMoW catalysts and their catalytic performance of 4,6-DMDBT HDS. Catal Commun 88:13–17
52. Han W, Nie H, Long X, Li M, Yang Q, Li D (2017) Effects of the support Brønsted acidity on
the hydrodesulfurization and hydrodenitrogenation activity of sulfided NiMo/Al 2 O 3 catalysts.
Catal Today 292:58–66
53. Zhang L, Dai Q, Wenqian F, Tang T, Dong P, He M, Chen Q (2018) CoMo catalyst
on zeolite TS-1 nanorod assemblies with high activity in the hydrodesulfurization of
4,6- dimethyldibenzothiophene. J Catal 359:130–142
54. Sun H, Sun H, Zhang X, Yu Q, Zeng P, Guo Q, Wang D, Wen G, Zhang W, He S, Shen B (2019)
Effect of divalent tin on the SnSAPO-5 molecular sieve and its modulation to alumina support to
form a highly efficient NiW catalyst for deep desulfurization of 4,6-Dimethyldibenzothiophene.
ACS Catal 9:6613–6623
55. Meng Q, Peng D, Duan A, Zhao Z, Liu J, Shang D, Wang B, Jia Y, Liu C, Hu D (2020) Trimetallic
catalyst supported zirconium modified Threedimensional mesoporous silica material and its
Hydrodesulfurization performance of dibenzothiophene and 4,6- dimethydibenzothiophene.
Ind Eng Chem Res 59(2):654–667
56. Klimova T, Ramirez J, Calderon M, Dominguez JM (1998) New Mo and NiMo catalysts
supported on MCM-41/alumina for thiophene hydrodesulfurization. Stud Surf Sci Catal
117:493–500
57. Song C, Reddy KM (1999) Mesoporous molecular sieve MCM-41 supported co-Mo catalyst
for hydrodesulfurization of dibenzothiophene in distillate fuels. Appl Catal A Gen 176:1–10
58. Klimova T, Calderon M, Ramirez J (2003) Ni and Mo interaction with Al-containing MCM-41
support and its effect on the catalytic behavior in DBT hydrodesulfurization. Appl Catal A Gen
240:29–40
59. Kouzu M, Kuriki Y, Hamdy F, Sakanishi K, Sugimoto Y, Saito I (2004) Catalytic potential of
carbon-supported NiMo-sulfide for ultra-deep hydrodesulfurization of diesel fuel. Appl. Catal
A Gen 265:61–67
60. Gutierrez OY, Perez F, Fuentes GA, Bokhimi X, Klimova T (2008) Deep HDS over NiMo/
Zr-SBA-15 catalysts with varying MoO 3 loading. Catal Today 130:292–301
61. Han D, Li X, Zhang L, Wang Y, Yan Z, Liu S (2012) Hierarchically ordered meso/macroporous γ-alumina for enhanced hydrodesulfurization performance. Microporous Mesoporous
Mater 158:1–6
62. Badoga S, Sharma RV, Dalai AK, Adjaye J (2015) Synthesis and characterization of mesoporous aluminas with different pore sizes: application in NiMo supported catalyst for hydrotreating of heavy gas oil. Appl Catal A Gen 489:86–97
Recent Advances in Hydrotreating/Hydrodesulfurization Catalysts: Part I: Nature…