32
63. Li H, Li M, Nie H (2014) Tailoring the surface characteristic of alumina for preparation of
highly active NiMo/Al 2 O 3 hydrodesulfurization catalyst. Microporous Mesoporous Mater
188:30–36
64. Dong Y, Xu Y, Zhang Y, Lian X, Yi X, Zhou Y, Fang W (2018) Synthesis of hierarchically
structured alumina support with adjustable nanocrystalline aggregation towards efficient
hydrodesulfurization. Appl Catal A Gen 559:30–39
65. Peng C, Guo R, Feng X, Fang X (2019) Tailoring the structure of Co-Mo/mesoporous γ-Al 2 O 3
catalysts by adding multi-hydroxyl compound: a 3000 kt/a industrial-scale diesel ultra-deep
hydrodesulfurization study. Chem Eng J 377:119706
66. Tang T, Zhang L, Wenqian F, Ma Y, Xu J, Jiang J, Fang G, Xiao F-S (2013) Design and synthesis of metal sulfide catalysts supported on zeolite nanofiber bundles with unprecedented
hydrodesulfurization activities. J Am Chem Soc 135(31):11437–11440
67. Dugulan AI, van Veen JAR, Hensen EJM (2013) On the structure and hydrotreating performance of carbon-supported CoMo- and NiMo-sulfides. Appl Catal B Environ
142–143:178–186
68. AL-Hammadi SA, Al-Amer AM, Saleh TA (2018) Alumina-carbon nanofiber composite as a
support for MoCo catalysts in hydrodesulfurization reactions. Chem Eng J 345:242–251
69. Rayo P, Torres-Mancera P, Centeno G, Alonso F, Munoz JAD, Ancheyta J (2019) Effect of
silicon incorporation method in the supports of NiMo catalysts for hydrotreating reactions.
Fuel 239:1293–1303
70. Saleh TA, Sulaiman KO, AL-Hammadi SA (2020) Effect of carbon on the hydrodesulfurization activity of MoCo catalysts supported on zeolite/ active carbon hybrid supports. Appl Catal
B Environ 263:117661. https://doi.org/10.1016/j.apcatb.2019.04.062
71. Liu X, Li X, Yan Z (2012) Facile route to prepare bimodal mesoporous γ-Al 2 O 3 as support for
highly active CoMo-based hydrodesulfurization catalyst. Appl Catal B Environ 121–122:50–56
72. Zhang M-h, Fan J-y, Chi K, Duan A-j, Zhao Z, Meng X-l, Zhang H-l (2017) Synthesis, characterization, and catalytic performance of NiMo catalysts supported on different crystal alumina
materials in the hydrodesulfurization of diesel. Fuel Process Technol 156:446–453
73. Gao Y, Han W, Long X, Nie H, Li D (2018) Preparation of hydrodesulfurization catalysts
using MoS 3 nanoparticles as a precursor. Appl Catal B Environ 224:330–340
74. Naboulsi I, Lebeau B, Linares CF, Aponte SB, Mallet M, Michelin L, Bonne M, Carteret C,
Blin J-L (2018) Selective direct desulfurization way (DDS) with CoMoS supported over mesostructured titania for the deep hydrodesulfurization of 4,6- dimethydibenzothiophene. Appl
Catal A Gen 563:91–97
75. Asadi AA, Alavi SM, Royaee SJ, Bazmi M (2018) Ultra-deep hydrodesulfurization of feedstock containing cracked gasoil through NiMo/γ-Al 2 O 3 catalyst pore size optimization. Energy
Fuel 32(2):2203–2212
76. Xie K, Fang Y, Liu B, Li C (2018) Enhanced catalytic activity of monodispersed porous Al 2 O 3
colloidal spheres with NiMo for simultaneous hydrodesulfurization and hydrogenation. RSC
Adv 8:18059
77. Valles VA, Sa-ngasaeng Y, Martínez ML, Jongpatiwut S, Beltramone AR (2019) HDT of the
model diesel feed over Ir-modified Zr-SBA-15 catalysts. Fuel 240:138–152
78. Zheng P, Hu D, Meng Q, Liu C, Wang X, Fan J, Duan A, Xu C (2019) Influence of support acidity on the HDS performance over β-SBA-16 and Al-SBA-16 substrates: a combined
experimental and theoretical study. Energy Fuel 33:1479–1488
79. Wang X, Mei J, Zhao Z, Chen Z, Zheng P, Jianye F, Li H, Fan J, Duan A, Xu C (2018)
Controllable synthesis of spherical Al-SBA-16 mesoporous materials with different crystal
sizes and its high isomerization performance for hydrodesulfurization of dibenzothiophene
and 4,6-dimethyldibenzothiophene. Ind Eng Chem Res 57(7):2498–2507
80. Asadi AA, Royaee SJ, Mahdi S, Bazmi M (2019) Ultra-deep hydrodesulfurization of cracked
and atmospheric gasoil blend: direct and interactive impacts of support composition, chelating
agent, metal and promoter loadings. Fuel Process Technol 187:36–51
G. Valavarasu and B. Ramachandrarao
63. Li H, Li M, Nie H (2014) Tailoring the surface characteristic of alumina for preparation of
highly active NiMo/Al 2 O 3 hydrodesulfurization catalyst. Microporous Mesoporous Mater
188:30–36
64. Dong Y, Xu Y, Zhang Y, Lian X, Yi X, Zhou Y, Fang W (2018) Synthesis of hierarchically
structured alumina support with adjustable nanocrystalline aggregation towards efficient
hydrodesulfurization. Appl Catal A Gen 559:30–39
65. Peng C, Guo R, Feng X, Fang X (2019) Tailoring the structure of Co-Mo/mesoporous γ-Al 2 O 3
catalysts by adding multi-hydroxyl compound: a 3000 kt/a industrial-scale diesel ultra-deep
hydrodesulfurization study. Chem Eng J 377:119706
66. Tang T, Zhang L, Wenqian F, Ma Y, Xu J, Jiang J, Fang G, Xiao F-S (2013) Design and synthesis of metal sulfide catalysts supported on zeolite nanofiber bundles with unprecedented
hydrodesulfurization activities. J Am Chem Soc 135(31):11437–11440
67. Dugulan AI, van Veen JAR, Hensen EJM (2013) On the structure and hydrotreating performance of carbon-supported CoMo- and NiMo-sulfides. Appl Catal B Environ
142–143:178–186
68. AL-Hammadi SA, Al-Amer AM, Saleh TA (2018) Alumina-carbon nanofiber composite as a
support for MoCo catalysts in hydrodesulfurization reactions. Chem Eng J 345:242–251
69. Rayo P, Torres-Mancera P, Centeno G, Alonso F, Munoz JAD, Ancheyta J (2019) Effect of
silicon incorporation method in the supports of NiMo catalysts for hydrotreating reactions.
Fuel 239:1293–1303
70. Saleh TA, Sulaiman KO, AL-Hammadi SA (2020) Effect of carbon on the hydrodesulfurization activity of MoCo catalysts supported on zeolite/ active carbon hybrid supports. Appl Catal
B Environ 263:117661. https://doi.org/10.1016/j.apcatb.2019.04.062
71. Liu X, Li X, Yan Z (2012) Facile route to prepare bimodal mesoporous γ-Al 2 O 3 as support for
highly active CoMo-based hydrodesulfurization catalyst. Appl Catal B Environ 121–122:50–56
72. Zhang M-h, Fan J-y, Chi K, Duan A-j, Zhao Z, Meng X-l, Zhang H-l (2017) Synthesis, characterization, and catalytic performance of NiMo catalysts supported on different crystal alumina
materials in the hydrodesulfurization of diesel. Fuel Process Technol 156:446–453
73. Gao Y, Han W, Long X, Nie H, Li D (2018) Preparation of hydrodesulfurization catalysts
using MoS 3 nanoparticles as a precursor. Appl Catal B Environ 224:330–340
74. Naboulsi I, Lebeau B, Linares CF, Aponte SB, Mallet M, Michelin L, Bonne M, Carteret C,
Blin J-L (2018) Selective direct desulfurization way (DDS) with CoMoS supported over mesostructured titania for the deep hydrodesulfurization of 4,6- dimethydibenzothiophene. Appl
Catal A Gen 563:91–97
75. Asadi AA, Alavi SM, Royaee SJ, Bazmi M (2018) Ultra-deep hydrodesulfurization of feedstock containing cracked gasoil through NiMo/γ-Al 2 O 3 catalyst pore size optimization. Energy
Fuel 32(2):2203–2212
76. Xie K, Fang Y, Liu B, Li C (2018) Enhanced catalytic activity of monodispersed porous Al 2 O 3
colloidal spheres with NiMo for simultaneous hydrodesulfurization and hydrogenation. RSC
Adv 8:18059
77. Valles VA, Sa-ngasaeng Y, Martínez ML, Jongpatiwut S, Beltramone AR (2019) HDT of the
model diesel feed over Ir-modified Zr-SBA-15 catalysts. Fuel 240:138–152
78. Zheng P, Hu D, Meng Q, Liu C, Wang X, Fan J, Duan A, Xu C (2019) Influence of support acidity on the HDS performance over β-SBA-16 and Al-SBA-16 substrates: a combined
experimental and theoretical study. Energy Fuel 33:1479–1488
79. Wang X, Mei J, Zhao Z, Chen Z, Zheng P, Jianye F, Li H, Fan J, Duan A, Xu C (2018)
Controllable synthesis of spherical Al-SBA-16 mesoporous materials with different crystal
sizes and its high isomerization performance for hydrodesulfurization of dibenzothiophene
and 4,6-dimethyldibenzothiophene. Ind Eng Chem Res 57(7):2498–2507
80. Asadi AA, Royaee SJ, Mahdi S, Bazmi M (2019) Ultra-deep hydrodesulfurization of cracked
and atmospheric gasoil blend: direct and interactive impacts of support composition, chelating
agent, metal and promoter loadings. Fuel Process Technol 187:36–51
G. Valavarasu and B. Ramachandrarao
