375
103. Sharifi Pajaie H, Taghizadeh M (2016) Methanol conversion to light olefins over surfactantmodified nanosized SAPO-34. React Kinet Mech Catal 118:701. https://doi.org/10.1007/
s11144- 016- 1023- 8
104. Zhu X et al (2016) Trimodal porous hierarchical SSZ-13 zeolite with improved catalytic
performance in the methanol-to-olefins reaction. ACS Catal 6:2163. https://doi.org/10.1021/
acscatal.5b02480
105. Chen H et al (2019) Organosilane surfactant-directed synthesis of nanosheet-assembled
SAPO-34 zeolites with improved MTO catalytic performance. J Mater Sci 54:8202. https://
doi.org/10.1007/s10853- 019- 03485- w
106. Kang EA et al (2013) Synthesis of mesoporous SAPO-34 zeolite from mesoporous silica materials for methanol to light olefins. J Nanosci Nanotechnol 13:7498. https://doi.
org/10.1166/jnn.2013.7905
107. Li Y et al (2014) Hierarchical SAPO-34/18 zeolite with low acid site density for converting
methanol to olefins. Catal Today 233:2. https://doi.org/10.1016/j.cattod.2014.03.038
108. Chen X et al (2016) A top-down approach to hierarchical SAPO-34 zeolites with improved
selectivity of olefin. Microporous Mesoporous Mater 234:401. https://doi.org/10.1016/j.
micromeso.2016.07.045
109. Jin W et al (2018) Selective Desilication, Mesopores formation, and MTO reaction enhancement via citric acid treatment of zeolite SAPO-34. Ind Eng Chem Res 57:4231. https://doi.
org/10.1021/acs.iecr.8b00632
110. Liu Z et al (2018) Melting-assisted solvent-free synthesis of hierarchical SAPO-34 with
enhanced methanol to olefins (MTO) performance. Cat Sci Technol 8:423. https://doi.
org/10.1039/c7cy02283b
111. Yang ST et al (2012) Microwave synthesis of mesoporous SAPO-34 with a hierarchical pore
structure. Mater Res Bull 47:3888. https://doi.org/10.1016/j.materresbull.2012.08.041
112. Galadima A, Muraza O (2015) From synthesis gas production to methanol synthesis and
potential upgrade to gasoline range hydrocarbons: a review. J Nat Gas Sci Eng 25:303.
https://doi.org/10.1016/j.jngse.2015.05.012
113. Jasper S, El-Halwagi MM (2015) A techno-economic comparison between two methanol-topropylene processes. PRO 3:684. https://doi.org/10.3390/pr3030684
114. Dusselier M, Davis ME (2018) Small-pore zeolites: synthesis and catalysis. Chem Rev
118:5265. https://doi.org/10.1021/acs.chemrev.7b00738
115. Mei C et al (2008) Selective production of propylene from methanol: Mesoporosity development in high silica HZSM-5. J Catal 258:243. https://doi.org/10.1016/j.jcat.2008.06.019
116. Yarulina I et al (2018) Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process. Nat Chem 10:804. https://doi.org/10.1038/
s41557- 018- 0081- 0
117. Rownaghi AA, Hedlund J (2011) Methanol to gasoline-range hydrocarbons: influence of
nanocrystal size and mesoporosity on catalytic performance and product distribution of
ZSM-5. Ind Eng Chem Res 50:11872. https://doi.org/10.1021/ie201549j
118. Jang HG, Min HK, Lee JK, Hong SB, Seo G (2012) SAPO-34 and ZSM-5 nanocrystals’ size
effects on their catalysis of methanol-to-olefin reactions. Appl Catal A Gen 437-438:120.
https://doi.org/10.1016/j.apcata.2012.06.023
119. Wang CM, Wang YD, Du YJ, Yang G, Xie ZK (2016) Computational insights into the reaction mechanism of methanol-to-olefins conversion in H-ZSM-5: nature of hydrocarbon pool.
Cat Sci Technol 6:3279. https://doi.org/10.1039/c5cy01419k
120. Müller S et al (2015) Coke formation and deactivation pathways on H-ZSM-5 in the conversion of methanol to olefins. J Catal 325:48. https://doi.org/10.1016/j.jcat.2015.02.013
121. Sun X et al (2014) On reaction pathways in the conversion of methanol to hydrocarbons on
HZSM-5. J Catal 317:185. https://doi.org/10.1016/j.jcat.2014.06.017
122. Li J et al (2011) Comparative study of MTO conversion over SAPO-34, H-ZSM-5 and
H-ZSM-22: correlating catalytic performance and reaction mechanism to zeolite topology.
Catal Today 171:221. https://doi.org/10.1016/j.cattod.2011.02.027
Shifting Trend of Rational Design Heuristics for Methanol-to-Olefins (MTO) Catalysts
103. Sharifi Pajaie H, Taghizadeh M (2016) Methanol conversion to light olefins over surfactantmodified nanosized SAPO-34. React Kinet Mech Catal 118:701. https://doi.org/10.1007/
s11144- 016- 1023- 8
104. Zhu X et al (2016) Trimodal porous hierarchical SSZ-13 zeolite with improved catalytic
performance in the methanol-to-olefins reaction. ACS Catal 6:2163. https://doi.org/10.1021/
acscatal.5b02480
105. Chen H et al (2019) Organosilane surfactant-directed synthesis of nanosheet-assembled
SAPO-34 zeolites with improved MTO catalytic performance. J Mater Sci 54:8202. https://
doi.org/10.1007/s10853- 019- 03485- w
106. Kang EA et al (2013) Synthesis of mesoporous SAPO-34 zeolite from mesoporous silica materials for methanol to light olefins. J Nanosci Nanotechnol 13:7498. https://doi.
org/10.1166/jnn.2013.7905
107. Li Y et al (2014) Hierarchical SAPO-34/18 zeolite with low acid site density for converting
methanol to olefins. Catal Today 233:2. https://doi.org/10.1016/j.cattod.2014.03.038
108. Chen X et al (2016) A top-down approach to hierarchical SAPO-34 zeolites with improved
selectivity of olefin. Microporous Mesoporous Mater 234:401. https://doi.org/10.1016/j.
micromeso.2016.07.045
109. Jin W et al (2018) Selective Desilication, Mesopores formation, and MTO reaction enhancement via citric acid treatment of zeolite SAPO-34. Ind Eng Chem Res 57:4231. https://doi.
org/10.1021/acs.iecr.8b00632
110. Liu Z et al (2018) Melting-assisted solvent-free synthesis of hierarchical SAPO-34 with
enhanced methanol to olefins (MTO) performance. Cat Sci Technol 8:423. https://doi.
org/10.1039/c7cy02283b
111. Yang ST et al (2012) Microwave synthesis of mesoporous SAPO-34 with a hierarchical pore
structure. Mater Res Bull 47:3888. https://doi.org/10.1016/j.materresbull.2012.08.041
112. Galadima A, Muraza O (2015) From synthesis gas production to methanol synthesis and
potential upgrade to gasoline range hydrocarbons: a review. J Nat Gas Sci Eng 25:303.
https://doi.org/10.1016/j.jngse.2015.05.012
113. Jasper S, El-Halwagi MM (2015) A techno-economic comparison between two methanol-topropylene processes. PRO 3:684. https://doi.org/10.3390/pr3030684
114. Dusselier M, Davis ME (2018) Small-pore zeolites: synthesis and catalysis. Chem Rev
118:5265. https://doi.org/10.1021/acs.chemrev.7b00738
115. Mei C et al (2008) Selective production of propylene from methanol: Mesoporosity development in high silica HZSM-5. J Catal 258:243. https://doi.org/10.1016/j.jcat.2008.06.019
116. Yarulina I et al (2018) Structure–performance descriptors and the role of Lewis acidity in the methanol-to-propylene process. Nat Chem 10:804. https://doi.org/10.1038/
s41557- 018- 0081- 0
117. Rownaghi AA, Hedlund J (2011) Methanol to gasoline-range hydrocarbons: influence of
nanocrystal size and mesoporosity on catalytic performance and product distribution of
ZSM-5. Ind Eng Chem Res 50:11872. https://doi.org/10.1021/ie201549j
118. Jang HG, Min HK, Lee JK, Hong SB, Seo G (2012) SAPO-34 and ZSM-5 nanocrystals’ size
effects on their catalysis of methanol-to-olefin reactions. Appl Catal A Gen 437-438:120.
https://doi.org/10.1016/j.apcata.2012.06.023
119. Wang CM, Wang YD, Du YJ, Yang G, Xie ZK (2016) Computational insights into the reaction mechanism of methanol-to-olefins conversion in H-ZSM-5: nature of hydrocarbon pool.
Cat Sci Technol 6:3279. https://doi.org/10.1039/c5cy01419k
120. Müller S et al (2015) Coke formation and deactivation pathways on H-ZSM-5 in the conversion of methanol to olefins. J Catal 325:48. https://doi.org/10.1016/j.jcat.2015.02.013
121. Sun X et al (2014) On reaction pathways in the conversion of methanol to hydrocarbons on
HZSM-5. J Catal 317:185. https://doi.org/10.1016/j.jcat.2014.06.017
122. Li J et al (2011) Comparative study of MTO conversion over SAPO-34, H-ZSM-5 and
H-ZSM-22: correlating catalytic performance and reaction mechanism to zeolite topology.
Catal Today 171:221. https://doi.org/10.1016/j.cattod.2011.02.027
Shifting Trend of Rational Design Heuristics for Methanol-to-Olefins (MTO) Catalysts