376
123. Yang Y et al (2012) The synthesis of endurable B-Al-ZSM-5 catalysts with tunable acidity for methanol to propylene reaction. Catal Commun 24:44. https://doi.org/10.1016/j.
catcom.2012.03.013
124. Zhang HR et al (2017) A durable and highly selective PbO/HZSM-5 catalyst for methanol
to propylene (MTP) conversion. Microporous Mesoporous Mater. https://doi.org/10.1016/j.
micromeso.2017.04.031
125. Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A (2015) Effect of boron incorporation
on the structure, products selectivities and lifetime of H-ZSM-5 nanocatalyst designed for
application in methanol-to-olefins (MTO) reaction. Microporous Mesoporous Mater. https://
doi.org/10.1016/j.micromeso.2014.10.024
126. Knott BC et al (2018) Consideration of the aluminum distribution in zeolites in theoretical and
experimental catalysis research. ACS Catal 8:770. https://doi.org/10.1021/acscatal.7b03676
127. Dědeček J, Tabor E, Sklenak S (2019) Tuning the aluminum distribution in zeolites to
increase their performance in acid-catalyzed reactions. ChemSusChem 12:556. https://doi.
org/10.1002/cssc.201801959
128. Nordvang EC, Borodina E, Ruiz-Martínez J, Fehrmann R, Weckhuysen BM (2015) Effects
of coke deposits on the catalytic performance of large zeolite H-ZSM-5 crystals during
alcohol- to-hydrocarbon reactions as investigated by a combination of optical spectroscopy
and microscopy. Chem A Eur J 21:17324. https://doi.org/10.1002/chem.201503136
129. Hwang A, Kumar M, Rimer JD, Bhan A (2017) Implications of methanol disproportionation
on catalyst lifetime for methanol-to-olefins conversion by HSSZ-13. J Catal 346:154. https://
doi.org/10.1016/j.jcat.2016.12.003
130. Hwang A, Bhan A (2019) Deactivation of zeolites and Zeotypes in methanol-to-hydrocarbons
catalysis: mechanisms and circumvention. Acc Chem Res 52:2647. https://doi.org/10.1021/
acs.accounts.9b00204
131. Hwang A, Bhan A (2017) Bifunctional strategy coupling Y2O3-catalyzed Alkanal decomposition with methanol-to-olefins catalysis for enhanced lifetime. ACS Catal 7:4417. https://doi.
org/10.1021/acscatal.7b00894
132. Olsbye U et al (2012) Conversion of methanol to hydrocarbons: how zeolite cavity and
pore size controls product selectivity. Angew Chem Int Ed 51:5810. https://doi.org/10.1002/
anie.201103657
133. Svelle S et al (2006) Conversion of methanol into hydrocarbons over zeolite H-ZSM-5: ethene formation is mechanistically separated from the formation of higher alkenes. J Am Chem
Soc 128:14770. https://doi.org/10.1021/ja065810a
134. Dahl IM, Kolboe S (1996) On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: 2. Isotopic labeling studies of the co-reaction of propene and methanol.
J Catal 161:304. https://doi.org/10.1006/jcat.1996.0188
135. Schulz H (2010) ‘Coking’ of zeolites during methanol conversion: basic reactions of
the MTO-, MTP- and MTG processes. Catal Today 154:183. https://doi.org/10.1016/j.
cattod.2010.05.012
136. Van Speybroeck V et al (2011) First principle kinetic studies of zeolite-catalyzed methylation
reactions. J Am Chem Soc 133:888. https://doi.org/10.1021/ja1073992
137. Hemelsoet K, Van Der Mynsbrugge J, De Wispelaere K, Waroquier M, Van Speybroeck V
(2013) Unraveling the reaction mechanisms governing methanol-to-olefins catalysis by theory and experiment. ChemPhysChem 14:1526. https://doi.org/10.1002/cphc.201201023
M. Kumar
123. Yang Y et al (2012) The synthesis of endurable B-Al-ZSM-5 catalysts with tunable acidity for methanol to propylene reaction. Catal Commun 24:44. https://doi.org/10.1016/j.
catcom.2012.03.013
124. Zhang HR et al (2017) A durable and highly selective PbO/HZSM-5 catalyst for methanol
to propylene (MTP) conversion. Microporous Mesoporous Mater. https://doi.org/10.1016/j.
micromeso.2017.04.031
125. Yaripour F, Shariatinia Z, Sahebdelfar S, Irandoukht A (2015) Effect of boron incorporation
on the structure, products selectivities and lifetime of H-ZSM-5 nanocatalyst designed for
application in methanol-to-olefins (MTO) reaction. Microporous Mesoporous Mater. https://
doi.org/10.1016/j.micromeso.2014.10.024
126. Knott BC et al (2018) Consideration of the aluminum distribution in zeolites in theoretical and
experimental catalysis research. ACS Catal 8:770. https://doi.org/10.1021/acscatal.7b03676
127. Dědeček J, Tabor E, Sklenak S (2019) Tuning the aluminum distribution in zeolites to
increase their performance in acid-catalyzed reactions. ChemSusChem 12:556. https://doi.
org/10.1002/cssc.201801959
128. Nordvang EC, Borodina E, Ruiz-Martínez J, Fehrmann R, Weckhuysen BM (2015) Effects
of coke deposits on the catalytic performance of large zeolite H-ZSM-5 crystals during
alcohol- to-hydrocarbon reactions as investigated by a combination of optical spectroscopy
and microscopy. Chem A Eur J 21:17324. https://doi.org/10.1002/chem.201503136
129. Hwang A, Kumar M, Rimer JD, Bhan A (2017) Implications of methanol disproportionation
on catalyst lifetime for methanol-to-olefins conversion by HSSZ-13. J Catal 346:154. https://
doi.org/10.1016/j.jcat.2016.12.003
130. Hwang A, Bhan A (2019) Deactivation of zeolites and Zeotypes in methanol-to-hydrocarbons
catalysis: mechanisms and circumvention. Acc Chem Res 52:2647. https://doi.org/10.1021/
acs.accounts.9b00204
131. Hwang A, Bhan A (2017) Bifunctional strategy coupling Y2O3-catalyzed Alkanal decomposition with methanol-to-olefins catalysis for enhanced lifetime. ACS Catal 7:4417. https://doi.
org/10.1021/acscatal.7b00894
132. Olsbye U et al (2012) Conversion of methanol to hydrocarbons: how zeolite cavity and
pore size controls product selectivity. Angew Chem Int Ed 51:5810. https://doi.org/10.1002/
anie.201103657
133. Svelle S et al (2006) Conversion of methanol into hydrocarbons over zeolite H-ZSM-5: ethene formation is mechanistically separated from the formation of higher alkenes. J Am Chem
Soc 128:14770. https://doi.org/10.1021/ja065810a
134. Dahl IM, Kolboe S (1996) On the reaction mechanism for hydrocarbon formation from methanol over SAPO-34: 2. Isotopic labeling studies of the co-reaction of propene and methanol.
J Catal 161:304. https://doi.org/10.1006/jcat.1996.0188
135. Schulz H (2010) ‘Coking’ of zeolites during methanol conversion: basic reactions of
the MTO-, MTP- and MTG processes. Catal Today 154:183. https://doi.org/10.1016/j.
cattod.2010.05.012
136. Van Speybroeck V et al (2011) First principle kinetic studies of zeolite-catalyzed methylation
reactions. J Am Chem Soc 133:888. https://doi.org/10.1021/ja1073992
137. Hemelsoet K, Van Der Mynsbrugge J, De Wispelaere K, Waroquier M, Van Speybroeck V
(2013) Unraveling the reaction mechanisms governing methanol-to-olefins catalysis by theory and experiment. ChemPhysChem 14:1526. https://doi.org/10.1002/cphc.201201023
M. Kumar