Table 12 Phase behavior of triphenylene-containing polyacrylates and methacrylate (Ref 6: Hüser
and Spiess 1988; Ref 23: Werth and Spiess 1993; Ref 25: Boden et al. 1998; Ref 26: Stewart et al.
1998)
Mesogen
R
x
Z
Phase behavior
Ref
50.1
(CH 2 ) 2 O(CH 2 ) 2 OCH 3
0
(CH 2 CH 2 O) 3
g À 6 I
6
50.2
C 5 H 11
11
O
g À 8 Col h 39 I
23
50.3
C 6 H 13
6
O
g 5 Col 84 I
25
50.4
C 6 H 13
0
(CH 2 CH 2 O) 2
Col 117 I
25
51.1
C 5 H 11
6
O
g30I
6
51.2
C 5 H 11
11
O
g À 16
23
51.3
C 6 H 13
11
O
g 2 Col 45 I
26
Table 10 Phase behavior of pentaalkynylbenzene-based side-chain copolymers (Ref 21: Kouwer
et al. 2001)
Mesogen
R
x
y
Phase behavior
39.1
CH 3
0
0.90
g 43 N c 164 N 235 I
39.2
CH 3
0
0.64
N c 165 N 233 I
39.3
CH 3
0
0.48
g 92 N c 158 N 204 I
39.4
CH 3
0
0.31
g 62 N c 149 N 148 I
39.5
C 5 H 11
0.31
0.69
g 77 N c 157 N 209 I
39.6
C 5 H 11
0.43
0.41
g 70 N c 169 I
39.7
C 5 H 11
0.50
0.42
g 51 N c 157 I
39.8
C 12 H 25
0.11
0.61
g 86 N c 155 N 210 I
39.9
C 12 H 25
0.45
0.45
g 50 N c 154 I
39.10
C 12 H 25
0.42
0.33
g 49 N c 136 I
Table 11 Phase behavior of triphenylene-containing polysiloxanes (Ref 22: Kreuder and
Ringsdorf 1983; Ref 6: Hüser and Spiess 1988; Ref 23: Werth and Spiess 1993; Ref 24: Hüser
et al. 1989)
Mesogen
R
x
Phase behavior
Ref
46.1
C 5 H 11
9
gÀ 19 Col 39 I
22
g À 41 Col h 75 I
23
46.1
0
C 5 H 11
9
gÀ 35 Col 75 I
6
46.2
C 5 H 11
3
gÀ 53 Col h 141 I
23
46.3
C 5 H 11
6
gÀ 52 Col h 131 I
23
47
C 5 H 11
9
gÀ29 Col 36 I
23
48
C 5 H 11
9
gÀ 35 Col 75 I
24
49.1
C 5 H 11
3
gÀ 54 Col h 171 I
23
49.2
C 5 H 11
6
gÀ 51 Col h 186 I
23
49.3
C 5 H 11
9
gÀ 37 Col h 112 I
23
49.4
C 7 H 15
9
gÀ 62 Col h 112 I
23
49.5
CH 2 CH 2 CH(CH 3 ) 2
9
Col h 81 I
23
3 Liquid Crystalline Polymers Derived from Disc-Shaped Molecules
79