16
diameter of 10 mm and a plastic-resin reaction chamber
30 × 30 × 25 cm
3
) equipped with a vacuum pumping system,
with inlet and outlet gas valves, gas pressure and flow controllers, and a ZnSe lens system for adjusting the beam intensity.
2. A 50 mm long graphite target rod with a 30 mm diameter and
purity 99.99%, with no catalytic metal inclusions.
3. Cylindrical filters, 50 mm in diameter and 150 mm long.
1. Tetrahydrofuran (THF).
2. Dichloromethane (DCM).
3. Nitrogen gas.
4. Metal sodium.
5. Benzophenone.
6. Calcium chloride.
1. p-Nitrobenzoyl chloride.
2. tert-Butyl 2-(2-(2 aminoethoxy)ethoxy)-ethylcarbamate.
3. NaOH pellets.
4. Anhydrous Na 2 SO 4 .
5. Pt/C 10 wt%.
6. H 2 gas.
7. Celite
®
.
1. CNHs powder.
2. BOC-aniline derivative.
3. Isoamyl nitrite.
4. 1,2-Dichlorobenzene.
5. N 2 gas.
6. Acetonitrile.
7. Dimethyl formamide.
8. Dichloromethane.
9. HCl gas.
10. Polytetrafluoroethylene (PTFE) membrane filters with pore
size of 0.2 μm.
11. Glass apparatus for vacuum filtration.
12. Vacuum pump.
13. A microwave reactor up to 300 W power (optional—see Note 3).
1. CNH powder.
2. A high-temperature (600 °C) pressurized furnace equipped
with gas inlet.
2.2 Drying Solvents
2.3 Synthesis
of BOC-Aniline
Derivative
2.4 Synthesis
of BOC-CNHs
and the Corresponding
NH 2 -CNHs
2.5 Oxidation
of CNHs
Anastasios Stergiou and Nikos Tagmatarchis
diameter of 10 mm and a plastic-resin reaction chamber
30 × 30 × 25 cm
3
) equipped with a vacuum pumping system,
with inlet and outlet gas valves, gas pressure and flow controllers, and a ZnSe lens system for adjusting the beam intensity.
2. A 50 mm long graphite target rod with a 30 mm diameter and
purity 99.99%, with no catalytic metal inclusions.
3. Cylindrical filters, 50 mm in diameter and 150 mm long.
1. Tetrahydrofuran (THF).
2. Dichloromethane (DCM).
3. Nitrogen gas.
4. Metal sodium.
5. Benzophenone.
6. Calcium chloride.
1. p-Nitrobenzoyl chloride.
2. tert-Butyl 2-(2-(2 aminoethoxy)ethoxy)-ethylcarbamate.
3. NaOH pellets.
4. Anhydrous Na 2 SO 4 .
5. Pt/C 10 wt%.
6. H 2 gas.
7. Celite
®
.
1. CNHs powder.
2. BOC-aniline derivative.
3. Isoamyl nitrite.
4. 1,2-Dichlorobenzene.
5. N 2 gas.
6. Acetonitrile.
7. Dimethyl formamide.
8. Dichloromethane.
9. HCl gas.
10. Polytetrafluoroethylene (PTFE) membrane filters with pore
size of 0.2 μm.
11. Glass apparatus for vacuum filtration.
12. Vacuum pump.
13. A microwave reactor up to 300 W power (optional—see Note 3).
1. CNH powder.
2. A high-temperature (600 °C) pressurized furnace equipped
with gas inlet.
2.2 Drying Solvents
2.3 Synthesis
of BOC-Aniline
Derivative
2.4 Synthesis
of BOC-CNHs
and the Corresponding
NH 2 -CNHs
2.5 Oxidation
of CNHs
Anastasios Stergiou and Nikos Tagmatarchis