2 Atomically Precise Nanoclusters as Electrocatalysts
61
Fig. 2.16 a Total current density of CO 2 reduction and b Faradaic efficiency (FE) for CO production
over the Au 25 nanosphere and nanorod; c FE for CO and H 2 at the potential of −1.07 and −1.17 V
over Au 25 nanosphere and nanorod, d CO formation rates over Au 25 nanosphere and nanorod.
Adapted from Ref. [71]. Copyright 2018 American Chemical Society
Fig. 2.17 a G for ligand removal (eV) from the NCs at 0 V versus RHE, b free energy diagrams
for CO 2 reduction to CO on the ligand-removed NCs at 0 V versus RHE. Adapted from Ref. [71].
Copyright 2018 American Chemical Society
61
Fig. 2.16 a Total current density of CO 2 reduction and b Faradaic efficiency (FE) for CO production
over the Au 25 nanosphere and nanorod; c FE for CO and H 2 at the potential of −1.07 and −1.17 V
over Au 25 nanosphere and nanorod, d CO formation rates over Au 25 nanosphere and nanorod.
Adapted from Ref. [71]. Copyright 2018 American Chemical Society
Fig. 2.17 a G for ligand removal (eV) from the NCs at 0 V versus RHE, b free energy diagrams
for CO 2 reduction to CO on the ligand-removed NCs at 0 V versus RHE. Adapted from Ref. [71].
Copyright 2018 American Chemical Society