10 Progress in the Selective Semi-hydrogenation of Alkynes …
337
47. Huang F, Deng Y, Chen Y, Cai X, Peng M, Jia Z, Xie J, Xiao D, Wen X, Wang N, Jiang Z, Liu
H, Ma D (2019) Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation
of acetylene. Nat Commun 10(1):4431. https://doi.org/10.1038/s41467-019-12460-7
48. Ji S, Chen Y, Zhao S, Chen W, Shi L, Wang Y, Dong J, Li Z, Li F, Chen C, Peng Q, Li J, Wang
D, Li Y (2019) Atomically dispersed ruthenium species inside metal-organic frameworks:
combining the high activity of atomic sites and the molecular sieving effect of MOFs. Angew
Chem Int Ed 58(13):4271–4275. https://doi.org/10.1002/anie.201814182
49. Chai Y, Wu G, Liu X, Ren Y, Dai W, Wang C, Xie Z, Guan N, Li L (2019) Acetyleneselective hydrogenation catalyzed by cationic nickel confined in zeolite. J Am Chem Soc
141(25):9920–9927. https://doi.org/10.1021/jacs.9b03361
50. Hamilton JF, Baetzold RC (1979) Catalysis by small metal clusters. Science 205(4412):1213–
1220. https://doi.org/10.1126/science.205.4412.1213
51. Abdollahi T, Farmanzadeh D (2018) Selective hydrogenation of acetylene in the presence of
ethylene on palladium nanocluster surfaces: a DFT study. Appl Surf Sci 433:513–529. https://
doi.org/10.1016/j.apsusc.2017.10.085
52. Abdollahi T, Farmanzadeh D (2018) Graphene-supported Cu11 nanocluster as a candidate
catalyst for the selective hydrogenation of acetylene: a density functional study. J Alloys
Compd 735:117–130. https://doi.org/10.1016/j.jallcom.2017.11.051
53. Abdollahi T, Farmanzadeh D (2018) Activity and selectivity of Ni nanoclusters in the selective
hydrogenation of acetylene: a computational investigation. C R Chim 21(5):484–493. https://
doi.org/10.1016/j.crci.2018.01.002
54. Naoki T, Hu Y, Yiukihide S (2008) Recent progress in bimetallic nanoparticles: their preparation, structures and functions. In: Metal nanoclusters in catalysis and materials science.
Elsevier, Amsterdam, pp 49–75. http://dx.doi.org/10.1016/B978-044453057-8.50005-2
55. Bronstein LM, Chernyshov DM, Volkov IO, Ezernitskaya MG, Valetsky PM, Matveeva VG,
Sulman EM (2000) Structure and properties of bimetallic colloids formed in polystyreneblock-poly-4-vinylpyridine micelles: catalytic behavior in selective hydrogenation of dehydrolinalool. J Catal 196(2):302–314. https://doi.org/10.1006/jcat.2000.3039
56. Rieker T, Hanprasopwattana A, Datye A, Hubbard P (1999) Langmuir 15:638
57. Yarulin A, Yuranov I, Cárdenas-Lizana F, Alexander DTL, Kiwi-Minsker L (2014) How to
increase the selectivity of Pd-based catalyst in alkynol hydrogenation: effect of second metal.
App Catal A Gen 478:186–193. https://doi.org/10.1016/j.apcata.2014.04.003
58. Calver CF, Dash P, Scott RWJ (2011) Selective hydrogenations with Ag–Pd catalysts prepared
by galvanic exchange reactions. ChemCatChem 3(4):695–697. https://doi.org/10.1002/cctc.
201000346
59. Mitsudome T, Urayama T, Yamazaki K, Maehara Y, Yamasaki J, Gohara K, Maeno Z, Mizugaki T, Jitsukawa K, Kaneda K (2016) Design of core-Pd/shell-Ag nanocomposite catalyst for
selective semihydrogenation of alkynes. ACS Catal 6(2):666–670. https://doi.org/10.1021/acs
catal.5b02518
60. Sulman E, Matveeva V, Usanov A, Kosivtsov Y, Demidenko G, Bronstein L, Chernyshov
D, Valetsky P (1999) Hydrogenation of acetylene alcohols with novel Pd colloidal catalysts
prepared in block copolymers micelles. J Mol Catal A Chem 146(1–2):265–269. https://doi.
org/10.1016/S1381-1169(99)00100-4
61. Diaz de los Bernardos M, Perez-Rodriguez S, Gual A, Claver C, Godard C (2017) Facile
synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective
hydrogenation of alkynes. Chem Commun 53(56):7894–7897. http://dx.doi.org/10.1039/c7c
c01779k
62. Lomelí-Rosales DA, Delgado JA, Díaz de los Bernardos M, Pérez-Rodríguez S, Gual
A, Claver C, Godard C (2019) A general one-pot methodology for the preparation of
mono- and bimetallic nanoparticles supported on carbon nanotubes: application in the semihydrogenation of alkynes and acetylene. Chem Eur J 25(35):8321–8331. http://dx.doi.org/10.
1002/chem.201901041
63. Buxaderas E, Volpe MA, Radivoy G (2019) Selective semi-hydrogenation of terminal alkynes
promoted by bimetallic Cu–Pd nanoparticles. Synthesis 51(6):1466–1472. https://doi.org/10.
1055/s-0037-1610318
337
47. Huang F, Deng Y, Chen Y, Cai X, Peng M, Jia Z, Xie J, Xiao D, Wen X, Wang N, Jiang Z, Liu
H, Ma D (2019) Anchoring Cu1 species over nanodiamond-graphene for semi-hydrogenation
of acetylene. Nat Commun 10(1):4431. https://doi.org/10.1038/s41467-019-12460-7
48. Ji S, Chen Y, Zhao S, Chen W, Shi L, Wang Y, Dong J, Li Z, Li F, Chen C, Peng Q, Li J, Wang
D, Li Y (2019) Atomically dispersed ruthenium species inside metal-organic frameworks:
combining the high activity of atomic sites and the molecular sieving effect of MOFs. Angew
Chem Int Ed 58(13):4271–4275. https://doi.org/10.1002/anie.201814182
49. Chai Y, Wu G, Liu X, Ren Y, Dai W, Wang C, Xie Z, Guan N, Li L (2019) Acetyleneselective hydrogenation catalyzed by cationic nickel confined in zeolite. J Am Chem Soc
141(25):9920–9927. https://doi.org/10.1021/jacs.9b03361
50. Hamilton JF, Baetzold RC (1979) Catalysis by small metal clusters. Science 205(4412):1213–
1220. https://doi.org/10.1126/science.205.4412.1213
51. Abdollahi T, Farmanzadeh D (2018) Selective hydrogenation of acetylene in the presence of
ethylene on palladium nanocluster surfaces: a DFT study. Appl Surf Sci 433:513–529. https://
doi.org/10.1016/j.apsusc.2017.10.085
52. Abdollahi T, Farmanzadeh D (2018) Graphene-supported Cu11 nanocluster as a candidate
catalyst for the selective hydrogenation of acetylene: a density functional study. J Alloys
Compd 735:117–130. https://doi.org/10.1016/j.jallcom.2017.11.051
53. Abdollahi T, Farmanzadeh D (2018) Activity and selectivity of Ni nanoclusters in the selective
hydrogenation of acetylene: a computational investigation. C R Chim 21(5):484–493. https://
doi.org/10.1016/j.crci.2018.01.002
54. Naoki T, Hu Y, Yiukihide S (2008) Recent progress in bimetallic nanoparticles: their preparation, structures and functions. In: Metal nanoclusters in catalysis and materials science.
Elsevier, Amsterdam, pp 49–75. http://dx.doi.org/10.1016/B978-044453057-8.50005-2
55. Bronstein LM, Chernyshov DM, Volkov IO, Ezernitskaya MG, Valetsky PM, Matveeva VG,
Sulman EM (2000) Structure and properties of bimetallic colloids formed in polystyreneblock-poly-4-vinylpyridine micelles: catalytic behavior in selective hydrogenation of dehydrolinalool. J Catal 196(2):302–314. https://doi.org/10.1006/jcat.2000.3039
56. Rieker T, Hanprasopwattana A, Datye A, Hubbard P (1999) Langmuir 15:638
57. Yarulin A, Yuranov I, Cárdenas-Lizana F, Alexander DTL, Kiwi-Minsker L (2014) How to
increase the selectivity of Pd-based catalyst in alkynol hydrogenation: effect of second metal.
App Catal A Gen 478:186–193. https://doi.org/10.1016/j.apcata.2014.04.003
58. Calver CF, Dash P, Scott RWJ (2011) Selective hydrogenations with Ag–Pd catalysts prepared
by galvanic exchange reactions. ChemCatChem 3(4):695–697. https://doi.org/10.1002/cctc.
201000346
59. Mitsudome T, Urayama T, Yamazaki K, Maehara Y, Yamasaki J, Gohara K, Maeno Z, Mizugaki T, Jitsukawa K, Kaneda K (2016) Design of core-Pd/shell-Ag nanocomposite catalyst for
selective semihydrogenation of alkynes. ACS Catal 6(2):666–670. https://doi.org/10.1021/acs
catal.5b02518
60. Sulman E, Matveeva V, Usanov A, Kosivtsov Y, Demidenko G, Bronstein L, Chernyshov
D, Valetsky P (1999) Hydrogenation of acetylene alcohols with novel Pd colloidal catalysts
prepared in block copolymers micelles. J Mol Catal A Chem 146(1–2):265–269. https://doi.
org/10.1016/S1381-1169(99)00100-4
61. Diaz de los Bernardos M, Perez-Rodriguez S, Gual A, Claver C, Godard C (2017) Facile
synthesis of NHC-stabilized Ni nanoparticles and their catalytic application in the Z-selective
hydrogenation of alkynes. Chem Commun 53(56):7894–7897. http://dx.doi.org/10.1039/c7c
c01779k
62. Lomelí-Rosales DA, Delgado JA, Díaz de los Bernardos M, Pérez-Rodríguez S, Gual
A, Claver C, Godard C (2019) A general one-pot methodology for the preparation of
mono- and bimetallic nanoparticles supported on carbon nanotubes: application in the semihydrogenation of alkynes and acetylene. Chem Eur J 25(35):8321–8331. http://dx.doi.org/10.
1002/chem.201901041
63. Buxaderas E, Volpe MA, Radivoy G (2019) Selective semi-hydrogenation of terminal alkynes
promoted by bimetallic Cu–Pd nanoparticles. Synthesis 51(6):1466–1472. https://doi.org/10.
1055/s-0037-1610318