338
J. A. Delgado and C. Godard
64. Ren M, Li C, Chen J, Wei M, Shi S (2014) Preparation of a ternary Pd-Rh-P amorphous
alloy and its catalytic performance in selective hydrogenation of alkynes. Catal Sci Technol
4(7):1920–1924. https://doi.org/10.1039/c4cy00338a
65. Miyazaki M, Furukawa S, Takayama T, Yamazoe S, Komatsu T (2019) Surface modification
of PdZn nanoparticles via galvanic replacement for the selective hydrogenation of terminal
alkynes. ACS Appl Nano Mater 2(5):3307–3314. https://doi.org/10.1021/acsanm.9b00761
66. Hu M, Zhao S, Chen C, Chen W, Zhu W, Cheong W-C, Wang Y, Peng Q, Li J, Li Y, Hu M,
Zhou K, Zhao S, Liu S, Liang C, Yu Y (2018) MOF-confined Sub-2 nm atomically ordered
intermetallic PdZn nanoparticles as high-performance catalysts for selective hydrogenation
of acetylene. Adv Mater e1801878
67. Mashkovsky IS, Markov PV, Bragina GO, Rassolov AV, Baeva GN, Stakheev AY (2017)
Intermetallic Pd1-Zn1 nanoparticles in the selective liquid-phase hydrogenation of substituted
alkynes. Kinet Catal 58(4):480–491. https://doi.org/10.1134/S0023158417040139
68. Zimmermann RR, Hahn T, Reschetilowski W, Armbruester M (2017) Kinetic parameters for
the selective hydrogenation of acetylene on GaPd2 and GaPd. ChemPhysChem 18(18):2517–
2525. https://doi.org/10.1002/cphc.201700535
69. Johnston SK, Bryant TA, Strong J, Lazzarini L, Ibhadon AO, Francesconi MG (2019) Stabilization of Pd 3−x In 1+x polymorphs with Pd-like crystal structure and their superior performance as catalysts for semi-hydrogenation of alkynes. ChemCatChem (Ahead of Print).
https://doi.org/10.1002/cctc.201900391
70. Rao D-M, Zhang S-T, Li C-M, Chen Y-D, Pu M, Yan H, Wei M (2018) The reaction mechanism
and selectivity of acetylene hydrogenation over Ni–Ga intermetallic compound catalysts: a
density functional theory study. Dalton Trans 47(12):4198–4208. https://doi.org/10.1039/C7D
T04726F
71. Aviziotis IG, Duguet T, Soussi K, Heggen M, Lafont M-C, Morfin F, Mishra S, Daniele
S, Boudouvis AG, Vahlas C (2018) Chemical vapor deposition of Al 13 Fe 4 highly selective
catalytic films for the semi-hydrogenation of acetylene. Phys Status Solidi A 215(2). https://
doi.org/10.1002/pssa.201700692
72. Kojima T, Kojima T, Kameoka S, Tsai A-P, Fujii S, Ueda S, Ueda S (2018) Catalysis-tunable
Heusler alloys in selective hydrogenation of alkynes: a new potential for old materials. Sci
Adv 4(10):eaat6063
73. Xiu J-h, Chen X, Yang Z-h, Cao H, Bai Z-x, Liang C-h (2017) Chemical synthesis of AlCo intermetallic compound catalysts for selective hydrogenation of alkyne. Fenzi Cuihua
31(4):325–333
74. Chan CWA, Mahadi AH, Li MM-J, Corbos EC, Tang C, Jones G, Kuo WCH, Cookson J,
Brown CM, Bishop PT, Tsang SCE (2014) Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation. Nat Commun 5:5787.
https://doi.org/10.1038/ncomms6787. http://www.nature.com/articles/ncomms6787#supple
mentary-information
75. Burch R, Lewis FA (1970) Absorption of hydrogen by palladium + boron and palladium +
silver + boron alloys. Trans Faraday Soc 66:727–735. https://doi.org/10.1039/TF9706600727
76. Zhang Y, Wen X, Shi Y, Yue R, Bai L, Liu Q, Ba X (2019) Sulfur-containing polymer as a
platform for synthesis of size-controlled pd nanoparticles for selective semihydrogenation of
alkynes. Ind Eng Chem Res 58(3):1142–1149. https://doi.org/10.1021/acs.iecr.8b04913
77. Albani D, Chen Z, Mitchell S, Perez-Ramirez J, Shahrokhi M, Lopez N, Hauert R (2018) Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation.
Nat Commun 9(1):2634
78. McCue AJ, Guerrero-Ruiz A, Ramirez-Barria C, Rodriguez-Ramos I, Anderson JA (2017)
Selective hydrogenation of mixed alkyne/alkene streams at elevated pressure over a palladium
sulfide catalyst. J Catal 355:40–52. https://doi.org/10.1016/j.jcat.2017.09.004
79. Phua P-H, Lefort L, Boogers JAF, Tristany M, de Vries JG (2009) Soluble iron nanoparticles as
cheap and environmentally benign alkene and alkyne hydrogenation catalysts. Chem Commun
25:3747–3749. https://doi.org/10.1039/b820048c
J. A. Delgado and C. Godard
64. Ren M, Li C, Chen J, Wei M, Shi S (2014) Preparation of a ternary Pd-Rh-P amorphous
alloy and its catalytic performance in selective hydrogenation of alkynes. Catal Sci Technol
4(7):1920–1924. https://doi.org/10.1039/c4cy00338a
65. Miyazaki M, Furukawa S, Takayama T, Yamazoe S, Komatsu T (2019) Surface modification
of PdZn nanoparticles via galvanic replacement for the selective hydrogenation of terminal
alkynes. ACS Appl Nano Mater 2(5):3307–3314. https://doi.org/10.1021/acsanm.9b00761
66. Hu M, Zhao S, Chen C, Chen W, Zhu W, Cheong W-C, Wang Y, Peng Q, Li J, Li Y, Hu M,
Zhou K, Zhao S, Liu S, Liang C, Yu Y (2018) MOF-confined Sub-2 nm atomically ordered
intermetallic PdZn nanoparticles as high-performance catalysts for selective hydrogenation
of acetylene. Adv Mater e1801878
67. Mashkovsky IS, Markov PV, Bragina GO, Rassolov AV, Baeva GN, Stakheev AY (2017)
Intermetallic Pd1-Zn1 nanoparticles in the selective liquid-phase hydrogenation of substituted
alkynes. Kinet Catal 58(4):480–491. https://doi.org/10.1134/S0023158417040139
68. Zimmermann RR, Hahn T, Reschetilowski W, Armbruester M (2017) Kinetic parameters for
the selective hydrogenation of acetylene on GaPd2 and GaPd. ChemPhysChem 18(18):2517–
2525. https://doi.org/10.1002/cphc.201700535
69. Johnston SK, Bryant TA, Strong J, Lazzarini L, Ibhadon AO, Francesconi MG (2019) Stabilization of Pd 3−x In 1+x polymorphs with Pd-like crystal structure and their superior performance as catalysts for semi-hydrogenation of alkynes. ChemCatChem (Ahead of Print).
https://doi.org/10.1002/cctc.201900391
70. Rao D-M, Zhang S-T, Li C-M, Chen Y-D, Pu M, Yan H, Wei M (2018) The reaction mechanism
and selectivity of acetylene hydrogenation over Ni–Ga intermetallic compound catalysts: a
density functional theory study. Dalton Trans 47(12):4198–4208. https://doi.org/10.1039/C7D
T04726F
71. Aviziotis IG, Duguet T, Soussi K, Heggen M, Lafont M-C, Morfin F, Mishra S, Daniele
S, Boudouvis AG, Vahlas C (2018) Chemical vapor deposition of Al 13 Fe 4 highly selective
catalytic films for the semi-hydrogenation of acetylene. Phys Status Solidi A 215(2). https://
doi.org/10.1002/pssa.201700692
72. Kojima T, Kojima T, Kameoka S, Tsai A-P, Fujii S, Ueda S, Ueda S (2018) Catalysis-tunable
Heusler alloys in selective hydrogenation of alkynes: a new potential for old materials. Sci
Adv 4(10):eaat6063
73. Xiu J-h, Chen X, Yang Z-h, Cao H, Bai Z-x, Liang C-h (2017) Chemical synthesis of AlCo intermetallic compound catalysts for selective hydrogenation of alkyne. Fenzi Cuihua
31(4):325–333
74. Chan CWA, Mahadi AH, Li MM-J, Corbos EC, Tang C, Jones G, Kuo WCH, Cookson J,
Brown CM, Bishop PT, Tsang SCE (2014) Interstitial modification of palladium nanoparticles with boron atoms as a green catalyst for selective hydrogenation. Nat Commun 5:5787.
https://doi.org/10.1038/ncomms6787. http://www.nature.com/articles/ncomms6787#supple
mentary-information
75. Burch R, Lewis FA (1970) Absorption of hydrogen by palladium + boron and palladium +
silver + boron alloys. Trans Faraday Soc 66:727–735. https://doi.org/10.1039/TF9706600727
76. Zhang Y, Wen X, Shi Y, Yue R, Bai L, Liu Q, Ba X (2019) Sulfur-containing polymer as a
platform for synthesis of size-controlled pd nanoparticles for selective semihydrogenation of
alkynes. Ind Eng Chem Res 58(3):1142–1149. https://doi.org/10.1021/acs.iecr.8b04913
77. Albani D, Chen Z, Mitchell S, Perez-Ramirez J, Shahrokhi M, Lopez N, Hauert R (2018) Selective ensembles in supported palladium sulfide nanoparticles for alkyne semi-hydrogenation.
Nat Commun 9(1):2634
78. McCue AJ, Guerrero-Ruiz A, Ramirez-Barria C, Rodriguez-Ramos I, Anderson JA (2017)
Selective hydrogenation of mixed alkyne/alkene streams at elevated pressure over a palladium
sulfide catalyst. J Catal 355:40–52. https://doi.org/10.1016/j.jcat.2017.09.004
79. Phua P-H, Lefort L, Boogers JAF, Tristany M, de Vries JG (2009) Soluble iron nanoparticles as
cheap and environmentally benign alkene and alkyne hydrogenation catalysts. Chem Commun
25:3747–3749. https://doi.org/10.1039/b820048c