336
J. A. Delgado and C. Godard
30. Roucoux A, Schulz J, Patin H (2002) Reduced transition metal colloids: a novel family of
reusable catalysts? Chem Rev 102(10):3757–3778. https://doi.org/10.1021/cr010350j
31. Ott LS, Finke RG (2007) Transition-metal nanocluster stabilization for catalysis: a critical
review of ranking methods and putative stabilizers. Coord Chem Rev 251(9–10):1075–1100.
https://doi.org/10.1016/j.ccr.2006.08.016
32. Astruc D, Lu F, Aranzaes JR (2005) Nanoparticles as recyclable catalysts: the frontier between
homogeneous and heterogeneous catalysis. Angew Chem Int Ed 44(48):7852–7872. https://
doi.org/10.1002/anie.200500766
33. Bond GC (1991) Supported metal catalysts: some unsolved problems. Chem Soc Rev
20(4):441–475. https://doi.org/10.1039/CS9912000441
34. Semagina N, Renken A, Kiwi-Minsker L (2007) Palladium nanoparticle size effect in 1hexyne selective hydrogenation. J Phys Chem C 111(37):13933–13937. https://doi.org/10.
1021/jp073944k
35. Semagina N, Renken A, Laub D, Kiwi-Minsker L (2007) Synthesis of monodispersed palladium nanoparticles to study structure sensitivity of solvent-free selective hydrogenation of
2-methyl-3-butyn-2-ol. J Catal 246(2):308–314. https://doi.org/10.1016/j.jcat.2006.12.011
36. Hu J, Zhou Z, Zhang R, Li L, Cheng Z (2014) Selective hydrogenation of phenylacetylene
over a nano-Pd/α-Al2O3 catalyst. J Mol Catal A Chem 381:61–69. https://doi.org/10.1016/j.
molcata.2013.10.008
37. Ruta M, Semagina N, Kiwi-Minsker L (2008) Monodispersed Pd nanoparticles for acetylene
selective hydrogenation: particle size and support effects. J Phys Chem C 112(35):13635–
13641. https://doi.org/10.1021/jp803800w
38. Teschner D, Vass E, Hävecker M, Zafeiratos S, Schnörch P, Sauer H, Knop-Gericke A, Schlögl
R, Chamam M, Wootsch A, Canning AS, Gamman JJ, Jackson SD, McGregor J, Gladden
LF (2006) Alkyne hydrogenation over Pd catalysts: a new paradigm. J Catal 242(1):26–37.
https://doi.org/10.1016/j.jcat.2006.05.030
39. Lamey D, Prokopyeva I, Cárdenas-Lizana F, Kiwi-Minsker L (2014) Impact of organicligand shell on catalytic performance of colloidal Pd nanoparticles for alkyne gas-phase
hydrogenation. Catal Today 235:79–89. https://doi.org/10.1016/j.cattod.2014.03.006
40. Crespo-Quesada M, Yarulin A, Jin M, Xia Y, Kiwi-Minsker L (2011) Structure sensitivity of
alkynol hydrogenation on shape- and size-controlled palladium nanocrystals: which sites are
most active and selective? J Am Chem Soc 133(32):12787–12794. https://doi.org/10.1021/
ja204557m
41. Zhang L, Zhou M, Wang A, Zhang T (2020) Selective hydrogenation over supported metal
catalysts: from nanoparticles to single atoms. Chem Rev 120(2):683–733. https://doi.org/10.
1021/acs.chemrev.9b00230
42. Pei GX, Liu XY, Yang X, Zhang L, Wang A, Li L, Wang H, Wang X, Zhang T (2017)
Performance of Cu-alloyed Pd single-atom catalyst for semihydrogenation of acetylene under
simulated front-end conditions. ACS Catal 7(2):1491–1500. https://doi.org/10.1021/acscatal.
6b03293
43. Feng Q, Zhao S, Wang Y, Dong J, Chen W, He D, Wang D, Yang J, Zhu Y, Zhu H, Gu L, Li Z,
Liu Y, Yu R, Li J, Li Y (2017) Isolated single-atom Pd sites in intermetallic nanostructures: high
catalytic selectivity for semihydrogenation of alkynes. J Am Chem Soc 139(21):7294–7301.
https://doi.org/10.1021/jacs.7b01471
44. Huang F, Deng Y, Chen Y, Cai X, Peng M, Jia Z, Ren P, Xiao D, Wen X, Wang N, Liu H, Ma D
(2018) Atomically dispersed Pd on nanodiamond/graphene hybrid for selective hydrogenation
of acetylene. J Am Chem Soc 140(41):13142–13146. https://doi.org/10.1021/jacs.8b07476
45. Dai X, Chen Z, Yao T, Zheng L, Lin Y, Liu W, Ju H, Zhu J, Hong X, Wei S, Wu Y, Li Y (2017)
Single Ni sites distributed on N-doped carbon for selective hydrogenation of acetylene. Chem
Commun 53(84):11568–11571. https://doi.org/10.1039/C7CC04820C
46. Lin R, Albani D, Fako E, Kaiser SK, Safonova OV, López N, Pérez-Ramírez J (2019) Design
of single gold atoms on nitrogen-doped carbon for molecular recognition in alkyne semihydrogenation. Angew Chem Int Ed 58(2):504–509. https://doi.org/10.1002/anie.201805820
J. A. Delgado and C. Godard
30. Roucoux A, Schulz J, Patin H (2002) Reduced transition metal colloids: a novel family of
reusable catalysts? Chem Rev 102(10):3757–3778. https://doi.org/10.1021/cr010350j
31. Ott LS, Finke RG (2007) Transition-metal nanocluster stabilization for catalysis: a critical
review of ranking methods and putative stabilizers. Coord Chem Rev 251(9–10):1075–1100.
https://doi.org/10.1016/j.ccr.2006.08.016
32. Astruc D, Lu F, Aranzaes JR (2005) Nanoparticles as recyclable catalysts: the frontier between
homogeneous and heterogeneous catalysis. Angew Chem Int Ed 44(48):7852–7872. https://
doi.org/10.1002/anie.200500766
33. Bond GC (1991) Supported metal catalysts: some unsolved problems. Chem Soc Rev
20(4):441–475. https://doi.org/10.1039/CS9912000441
34. Semagina N, Renken A, Kiwi-Minsker L (2007) Palladium nanoparticle size effect in 1hexyne selective hydrogenation. J Phys Chem C 111(37):13933–13937. https://doi.org/10.
1021/jp073944k
35. Semagina N, Renken A, Laub D, Kiwi-Minsker L (2007) Synthesis of monodispersed palladium nanoparticles to study structure sensitivity of solvent-free selective hydrogenation of
2-methyl-3-butyn-2-ol. J Catal 246(2):308–314. https://doi.org/10.1016/j.jcat.2006.12.011
36. Hu J, Zhou Z, Zhang R, Li L, Cheng Z (2014) Selective hydrogenation of phenylacetylene
over a nano-Pd/α-Al2O3 catalyst. J Mol Catal A Chem 381:61–69. https://doi.org/10.1016/j.
molcata.2013.10.008
37. Ruta M, Semagina N, Kiwi-Minsker L (2008) Monodispersed Pd nanoparticles for acetylene
selective hydrogenation: particle size and support effects. J Phys Chem C 112(35):13635–
13641. https://doi.org/10.1021/jp803800w
38. Teschner D, Vass E, Hävecker M, Zafeiratos S, Schnörch P, Sauer H, Knop-Gericke A, Schlögl
R, Chamam M, Wootsch A, Canning AS, Gamman JJ, Jackson SD, McGregor J, Gladden
LF (2006) Alkyne hydrogenation over Pd catalysts: a new paradigm. J Catal 242(1):26–37.
https://doi.org/10.1016/j.jcat.2006.05.030
39. Lamey D, Prokopyeva I, Cárdenas-Lizana F, Kiwi-Minsker L (2014) Impact of organicligand shell on catalytic performance of colloidal Pd nanoparticles for alkyne gas-phase
hydrogenation. Catal Today 235:79–89. https://doi.org/10.1016/j.cattod.2014.03.006
40. Crespo-Quesada M, Yarulin A, Jin M, Xia Y, Kiwi-Minsker L (2011) Structure sensitivity of
alkynol hydrogenation on shape- and size-controlled palladium nanocrystals: which sites are
most active and selective? J Am Chem Soc 133(32):12787–12794. https://doi.org/10.1021/
ja204557m
41. Zhang L, Zhou M, Wang A, Zhang T (2020) Selective hydrogenation over supported metal
catalysts: from nanoparticles to single atoms. Chem Rev 120(2):683–733. https://doi.org/10.
1021/acs.chemrev.9b00230
42. Pei GX, Liu XY, Yang X, Zhang L, Wang A, Li L, Wang H, Wang X, Zhang T (2017)
Performance of Cu-alloyed Pd single-atom catalyst for semihydrogenation of acetylene under
simulated front-end conditions. ACS Catal 7(2):1491–1500. https://doi.org/10.1021/acscatal.
6b03293
43. Feng Q, Zhao S, Wang Y, Dong J, Chen W, He D, Wang D, Yang J, Zhu Y, Zhu H, Gu L, Li Z,
Liu Y, Yu R, Li J, Li Y (2017) Isolated single-atom Pd sites in intermetallic nanostructures: high
catalytic selectivity for semihydrogenation of alkynes. J Am Chem Soc 139(21):7294–7301.
https://doi.org/10.1021/jacs.7b01471
44. Huang F, Deng Y, Chen Y, Cai X, Peng M, Jia Z, Ren P, Xiao D, Wen X, Wang N, Liu H, Ma D
(2018) Atomically dispersed Pd on nanodiamond/graphene hybrid for selective hydrogenation
of acetylene. J Am Chem Soc 140(41):13142–13146. https://doi.org/10.1021/jacs.8b07476
45. Dai X, Chen Z, Yao T, Zheng L, Lin Y, Liu W, Ju H, Zhu J, Hong X, Wei S, Wu Y, Li Y (2017)
Single Ni sites distributed on N-doped carbon for selective hydrogenation of acetylene. Chem
Commun 53(84):11568–11571. https://doi.org/10.1039/C7CC04820C
46. Lin R, Albani D, Fako E, Kaiser SK, Safonova OV, López N, Pérez-Ramírez J (2019) Design
of single gold atoms on nitrogen-doped carbon for molecular recognition in alkyne semihydrogenation. Angew Chem Int Ed 58(2):504–509. https://doi.org/10.1002/anie.201805820