6 Catalysis with MNPs on N-Doped Carbon
217
References
1. Jagadeesh RV, Surkus A-E, Junge H, Pohl M-M, Radnik J, Rabeah J, Huan H, Schünemann V,
Brückner A, Beller M (2013) Nanoscale Fe 2 O 3 -based catalysts for selective hydrogenation of
nitroarenes to anilines. Science 342:1073–1076. https://doi.org/10.1126/science.1242005
2. Jagadeesh RV, Stemmler T, Surkus A-E, Junge H, Junge K, Beller M (2015) Hydrogenation
using iron oxide-based nanocatalysts for the synthesis of amines. Nat Protoc 10:548–557.
https://doi.org/10.1038/nprot.2015.025
3. Ono N (2001) The nitro group in organic synthesis. Wiley-VCH, New York
4. Natte K, Neumann H, Jagadeesh RV, Beller M (2017) Convenient iron-catalyzed reductive
aminations without hydrogen for selective synthesis of N-methylamines. Nat Commun 8:1344.
https://doi.org/10.1038/s41467-017-01428-0
5. Jagadeesh RV, Junge H, Beller M (2014) Green synthesis of nitriles using non-noble metal
oxides-based nanocatalysts. Nat Commun 5:4123. https://doi.org/10.1038/ncomms5123
6. Jagadeesh RV, Junge H, Beller M (2015) “Nanorust”-catalyzed benign oxidation of amines for
selective synthesis of nitriles. Chemsuschem 8:92–96. https://doi.org/10.1002/cssc.201402613
7. Cui X, Li Y, Bachmann S, Scalone M, Surkus A-E, Junge K, Topf C, Beller M (2015) Synthesis
and characterization of iron–nitrogen-doped graphene/core–shell catalysts: Efficient oxidative
dehydrogenation of N-heterocycles. J Am Chem Soc 137(10652):10658. https://doi.org/10.
1021/jacs.5b05674
8. Jaiswal G, Landge VG, Jagadeesan D, Balaraman E (2017) Iron-based nanocatalyst for the
acceptorless dehydrogenation reactions. Nat Commun 88:2147. https://doi.org/10.1038/s41
467-017-01603-3
9. Lefèvre M, Proietti E, Jaouen F, Dodelet J-P (2009) Iron-based catalysts with improved oxygen
reduction activity in polymer electrolyte fuel cells. Science 324:71–74. https://doi.org/10.1126/
science.1170051
10. Sahoo B, Kreyenschulte C, Agostini G, Lund H, Bachmann S, Scalone M, Junge K, Beller M
(2018) A robust iron catalyst for the selective hydrogenation of substituted (iso)quinolones.
Chem. Sci. 9:81348141. https://doi.org/10.1039/C8SC02744G
11. Sridharan V, Suryavanshi PA, Menéndez JC (2011) Advances in the chemistry of tetrahydroquinolines. Chem Rev 111:7157–7259. https://doi.org/10.1021/cr100307m
12. Westerhaus FA, Jagadeesh RV, Wienhöfer G, Pohl M-M, Radnik J, Surkus A-E, Rabeah J, Junge
K, Junge H, Nielsen M, Brückner A, Beller M (2013) Heterogenized cobalt oxide catalysts
for nitroarene reduction by pyrolysis of molecularly defined complexes. Nat Chem 5:537–543.
https://doi.org/10.1038/nchem.1645
13. Jagadeesh RV, Stemmler T, Surkus A-E, Bauer M, Pohl M-M, Radnik J, Junge K, Junge H,
Brückner A, Beller M (2015) Nature protocols. Cobalt-based nanocatalysts for green oxidation
and hydrogenation processes 10:916–926. https://doi.org/10.1038/nprot.2015.049
14. Jagadeesh RV, Junge H, Pohl M-M, Radnik J, Brückner A, Beller M (2013) Selective oxidation
of alcohols to esters using heterogeneous Co 3 O 4 -N@C catalysts under mild conditions. J Am
Chem Soc 135(29):10776–10782. https://doi.org/10.1021/ja403615c
15. Otera J (2003) Esterification: methods, reactions, and applications. Wiley-VCH, Weinheim
16. Fraser FF, Lihua Y, Ravikumar PC, Funk L, Shook BC (2010) Nitrile-containing pharmaceuticals: efficacious roles of the nitrile pharmacophore. J Med Chem 53:7902–7917. https://doi.
org/10.1021/jm100762r
17. Anbarasan P, Schareina T, Beller M (2011) Recent developments and perspectives in palladiumcatalyzed cyanation, of aryl halides: synthesis of benzonitriles. Chem Soc Rev 40:5049–5067.
https://doi.org/10.1039/c1cs15004a
217
References
1. Jagadeesh RV, Surkus A-E, Junge H, Pohl M-M, Radnik J, Rabeah J, Huan H, Schünemann V,
Brückner A, Beller M (2013) Nanoscale Fe 2 O 3 -based catalysts for selective hydrogenation of
nitroarenes to anilines. Science 342:1073–1076. https://doi.org/10.1126/science.1242005
2. Jagadeesh RV, Stemmler T, Surkus A-E, Junge H, Junge K, Beller M (2015) Hydrogenation
using iron oxide-based nanocatalysts for the synthesis of amines. Nat Protoc 10:548–557.
https://doi.org/10.1038/nprot.2015.025
3. Ono N (2001) The nitro group in organic synthesis. Wiley-VCH, New York
4. Natte K, Neumann H, Jagadeesh RV, Beller M (2017) Convenient iron-catalyzed reductive
aminations without hydrogen for selective synthesis of N-methylamines. Nat Commun 8:1344.
https://doi.org/10.1038/s41467-017-01428-0
5. Jagadeesh RV, Junge H, Beller M (2014) Green synthesis of nitriles using non-noble metal
oxides-based nanocatalysts. Nat Commun 5:4123. https://doi.org/10.1038/ncomms5123
6. Jagadeesh RV, Junge H, Beller M (2015) “Nanorust”-catalyzed benign oxidation of amines for
selective synthesis of nitriles. Chemsuschem 8:92–96. https://doi.org/10.1002/cssc.201402613
7. Cui X, Li Y, Bachmann S, Scalone M, Surkus A-E, Junge K, Topf C, Beller M (2015) Synthesis
and characterization of iron–nitrogen-doped graphene/core–shell catalysts: Efficient oxidative
dehydrogenation of N-heterocycles. J Am Chem Soc 137(10652):10658. https://doi.org/10.
1021/jacs.5b05674
8. Jaiswal G, Landge VG, Jagadeesan D, Balaraman E (2017) Iron-based nanocatalyst for the
acceptorless dehydrogenation reactions. Nat Commun 88:2147. https://doi.org/10.1038/s41
467-017-01603-3
9. Lefèvre M, Proietti E, Jaouen F, Dodelet J-P (2009) Iron-based catalysts with improved oxygen
reduction activity in polymer electrolyte fuel cells. Science 324:71–74. https://doi.org/10.1126/
science.1170051
10. Sahoo B, Kreyenschulte C, Agostini G, Lund H, Bachmann S, Scalone M, Junge K, Beller M
(2018) A robust iron catalyst for the selective hydrogenation of substituted (iso)quinolones.
Chem. Sci. 9:81348141. https://doi.org/10.1039/C8SC02744G
11. Sridharan V, Suryavanshi PA, Menéndez JC (2011) Advances in the chemistry of tetrahydroquinolines. Chem Rev 111:7157–7259. https://doi.org/10.1021/cr100307m
12. Westerhaus FA, Jagadeesh RV, Wienhöfer G, Pohl M-M, Radnik J, Surkus A-E, Rabeah J, Junge
K, Junge H, Nielsen M, Brückner A, Beller M (2013) Heterogenized cobalt oxide catalysts
for nitroarene reduction by pyrolysis of molecularly defined complexes. Nat Chem 5:537–543.
https://doi.org/10.1038/nchem.1645
13. Jagadeesh RV, Stemmler T, Surkus A-E, Bauer M, Pohl M-M, Radnik J, Junge K, Junge H,
Brückner A, Beller M (2015) Nature protocols. Cobalt-based nanocatalysts for green oxidation
and hydrogenation processes 10:916–926. https://doi.org/10.1038/nprot.2015.049
14. Jagadeesh RV, Junge H, Pohl M-M, Radnik J, Brückner A, Beller M (2013) Selective oxidation
of alcohols to esters using heterogeneous Co 3 O 4 -N@C catalysts under mild conditions. J Am
Chem Soc 135(29):10776–10782. https://doi.org/10.1021/ja403615c
15. Otera J (2003) Esterification: methods, reactions, and applications. Wiley-VCH, Weinheim
16. Fraser FF, Lihua Y, Ravikumar PC, Funk L, Shook BC (2010) Nitrile-containing pharmaceuticals: efficacious roles of the nitrile pharmacophore. J Med Chem 53:7902–7917. https://doi.
org/10.1021/jm100762r
17. Anbarasan P, Schareina T, Beller M (2011) Recent developments and perspectives in palladiumcatalyzed cyanation, of aryl halides: synthesis of benzonitriles. Chem Soc Rev 40:5049–5067.
https://doi.org/10.1039/c1cs15004a