218
R. V. Jagadeesh
18. Martin A, Kalevaru VN (2010) Heterogeneously catalyzed ammoxidation: a valuable tool for
one-step synthesis of nitriles. ChemCatChem 2:1504–1522. https://doi.org/10.1002/cctc.201
000173
19. Chen F, Surkus A-E, He L, Pohl M-M, Radnik J, Topf C, Junge K, Beller M (2015) Selective catalytic hydrogenation of heteroarenes with N-graphene-modified cobalt nanoparticles
(Co3O4–Co/NGr@α-Al 2 O 3 ). J Am Chem Soc 137:11718–11724. https://doi.org/10.1021/jacs.
5b06496
20. Chen F, Topf C, Radnik J, Kreyenschulte C, Lund H, Schneider M, Surkus A-E, He L, Junge K,
Beller M (2016) Stable and inert cobalt catalysts for highly selective and practical hydrogenation
of C≡N and C=O bonds. J Am Chem Soc 138:8781–8788. https://doi.org/10.1021/jacs.6b0
3439
21. Chen F, Kreyenschulte C, Radnik J, Lund H, Surkus A-E, Junge K, Beller M (2017) Selective
semihydrogenation of alkynes with N-graphitic-modified cobalt nanoparticles supported on
silica. ACS Catal 7:1526–1532. https://doi.org/10.1021/acscatal.6b03140
22. Oger C, Balas L, Durand T, Galano J-M (2013) Are alkyne reductions chemo-, regio-, and
stereoselective enough to provide pure (Z)-olefins in polyfunctionalized bioactive molecules.
Chem Rev 113:1313–1350. https://doi.org/10.1021/cr3001753
23. Patai S (1964) The chemistry of alkenes. Interscience
24. Tang C, Surkus A-E, Chen F, Pohl M-M, Agostini G, Schneider M, Junge H, Beller M (2017)
A stable nanocobalt catalyst with highly dispersed CoNx active sites for the selective dehydrogenation of formic acid. Angew Chem Int Ed 56:16616–16620. https://doi.org/10.1002/anie.
201710766
25. Mellmann D, Sponholz P, Junge H, Beller M (2016) Formic acid as a hydrogen storage materialdevelopment of homogeneous catalysts for selective hydrogen release. Chem Soc Rev 45:3954–
3988. https://doi.org/10.1039/C5CS00618J
26. Staffell I, Scamman D, Abad AV, Balcombe P, Dodds PE, Ekins P, Shah N, Ward KR (2019) The
role of hydrogen and fuel cells in the global energy system. Energy Environ Sci 12:463–491.
https://doi.org/10.1039/C8EE01157E
27. Han Y, Wang Z, Xu R, Zhang W, Chen W, Zheng L, Zhang J, Luo J, Wu K, Zhu Y, Chen C,
Peng Q, Liu Q, Hu P, Wang D, Li Y (2018) Ordered porous nitrogen-doped carbon matrix
with atomically dispersed cobalt sites as an efficient catalyst for dehydrogenation and transfer
hydrogenation of N-heterocycles. Angew Chem Int Ed 57:11262–11266. https://doi.org/10.
1002/anie.201805467
28. Dang S, Zhu Q-L (2017) Nanomaterials derived from metal–organic frameworks. Nat Rev
Mater 3:17075. https://doi.org/10.1038/natrevmats.2017.75
29. Shen K, Chen X, Chen J, Li Y (2016) Development of MOF-derived carbon-based nanomaterials for efficient catalysis. ACS Catal 6:5887–5903. https://doi.org/10.1021/acscatal.6b0
1222
30. Long J, Shen K, Li Y (2017) Bifunctional N-doped Co@C catalysts for base-free transfer
hydrogenations of nitriles: controllable selectivity to primary amines vs imines. ACS Catal
7:275–284. https://doi.org/10.1021/acscatal.6b02327
31. Jagadeesh RV, Murugesan K, Alshammari AS, Neumann H, Pohl M-M, Radnik J, Beller
M (2017) MOF-derived cobalt nanoparticles catalyze a general synthesis of amines. Science
358:326–332. https://doi.org/10.1126/science.aan6245
32. Corma A, Garcı´a H, Llabrés i Xamena FX (2010) Engineering metal organic frameworks for
heterogeneous catalysis. Chem Rev 110:4606–4655. https://doi.org/10.1021/cr9003924
33. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of
metal-organic frameworks. Science 341:1230444. https://doi.org/10.1126/science.1230444
34. Lawrence SA (2004) Amines: synthesis, properties and applications. Cambridge University
Press, Cambridge
35. Ricci A (2008) Amino group chemistry: from synthesis to the life sciences. Wiley-VCH,
Weinheim
36. http://njardarson.lab.arizona.edu/sites/njardarson.lab.arizona.edu/files/Top200Pharmaceutic
alProductsRetailSales2015LowRes.pdf
R. V. Jagadeesh
18. Martin A, Kalevaru VN (2010) Heterogeneously catalyzed ammoxidation: a valuable tool for
one-step synthesis of nitriles. ChemCatChem 2:1504–1522. https://doi.org/10.1002/cctc.201
000173
19. Chen F, Surkus A-E, He L, Pohl M-M, Radnik J, Topf C, Junge K, Beller M (2015) Selective catalytic hydrogenation of heteroarenes with N-graphene-modified cobalt nanoparticles
(Co3O4–Co/NGr@α-Al 2 O 3 ). J Am Chem Soc 137:11718–11724. https://doi.org/10.1021/jacs.
5b06496
20. Chen F, Topf C, Radnik J, Kreyenschulte C, Lund H, Schneider M, Surkus A-E, He L, Junge K,
Beller M (2016) Stable and inert cobalt catalysts for highly selective and practical hydrogenation
of C≡N and C=O bonds. J Am Chem Soc 138:8781–8788. https://doi.org/10.1021/jacs.6b0
3439
21. Chen F, Kreyenschulte C, Radnik J, Lund H, Surkus A-E, Junge K, Beller M (2017) Selective
semihydrogenation of alkynes with N-graphitic-modified cobalt nanoparticles supported on
silica. ACS Catal 7:1526–1532. https://doi.org/10.1021/acscatal.6b03140
22. Oger C, Balas L, Durand T, Galano J-M (2013) Are alkyne reductions chemo-, regio-, and
stereoselective enough to provide pure (Z)-olefins in polyfunctionalized bioactive molecules.
Chem Rev 113:1313–1350. https://doi.org/10.1021/cr3001753
23. Patai S (1964) The chemistry of alkenes. Interscience
24. Tang C, Surkus A-E, Chen F, Pohl M-M, Agostini G, Schneider M, Junge H, Beller M (2017)
A stable nanocobalt catalyst with highly dispersed CoNx active sites for the selective dehydrogenation of formic acid. Angew Chem Int Ed 56:16616–16620. https://doi.org/10.1002/anie.
201710766
25. Mellmann D, Sponholz P, Junge H, Beller M (2016) Formic acid as a hydrogen storage materialdevelopment of homogeneous catalysts for selective hydrogen release. Chem Soc Rev 45:3954–
3988. https://doi.org/10.1039/C5CS00618J
26. Staffell I, Scamman D, Abad AV, Balcombe P, Dodds PE, Ekins P, Shah N, Ward KR (2019) The
role of hydrogen and fuel cells in the global energy system. Energy Environ Sci 12:463–491.
https://doi.org/10.1039/C8EE01157E
27. Han Y, Wang Z, Xu R, Zhang W, Chen W, Zheng L, Zhang J, Luo J, Wu K, Zhu Y, Chen C,
Peng Q, Liu Q, Hu P, Wang D, Li Y (2018) Ordered porous nitrogen-doped carbon matrix
with atomically dispersed cobalt sites as an efficient catalyst for dehydrogenation and transfer
hydrogenation of N-heterocycles. Angew Chem Int Ed 57:11262–11266. https://doi.org/10.
1002/anie.201805467
28. Dang S, Zhu Q-L (2017) Nanomaterials derived from metal–organic frameworks. Nat Rev
Mater 3:17075. https://doi.org/10.1038/natrevmats.2017.75
29. Shen K, Chen X, Chen J, Li Y (2016) Development of MOF-derived carbon-based nanomaterials for efficient catalysis. ACS Catal 6:5887–5903. https://doi.org/10.1021/acscatal.6b0
1222
30. Long J, Shen K, Li Y (2017) Bifunctional N-doped Co@C catalysts for base-free transfer
hydrogenations of nitriles: controllable selectivity to primary amines vs imines. ACS Catal
7:275–284. https://doi.org/10.1021/acscatal.6b02327
31. Jagadeesh RV, Murugesan K, Alshammari AS, Neumann H, Pohl M-M, Radnik J, Beller
M (2017) MOF-derived cobalt nanoparticles catalyze a general synthesis of amines. Science
358:326–332. https://doi.org/10.1126/science.aan6245
32. Corma A, Garcı´a H, Llabrés i Xamena FX (2010) Engineering metal organic frameworks for
heterogeneous catalysis. Chem Rev 110:4606–4655. https://doi.org/10.1021/cr9003924
33. Furukawa H, Cordova KE, O’Keeffe M, Yaghi OM (2013) The chemistry and applications of
metal-organic frameworks. Science 341:1230444. https://doi.org/10.1126/science.1230444
34. Lawrence SA (2004) Amines: synthesis, properties and applications. Cambridge University
Press, Cambridge
35. Ricci A (2008) Amino group chemistry: from synthesis to the life sciences. Wiley-VCH,
Weinheim
36. http://njardarson.lab.arizona.edu/sites/njardarson.lab.arizona.edu/files/Top200Pharmaceutic
alProductsRetailSales2015LowRes.pdf