107
Jackstell CFR, Beller M (2010) Modern catalysts for the hydrogenation of carbon dioxide. Angew
Chem 122:6392–6395. https://doi.org/10.1002/ange.201000533
Jessop PG, Ikariya T, Noyori R (1999) Homogeneous catalysis in supercritical fluids. Chem Rev
99:475–493. https://doi.org/10.1021/cr970037a
Jin Z, Li P, Liu G, Zheng B, Yuan H, Xiao D (2013) Enhancing catalytic formaldehyde oxidation
on CuO–Ag 2 O nanowires for gas sensing and hydrogen evolution. J Mater Chem A 1:14736–
14743. https://doi.org/10.1039/C3TA13277C
Johnson TC, Morris DJ, Wills M (2009) Hydrogen generation from formic acid and alcohols using
homogeneous catalysts. Chem Soc Rev 39:81–88. https://doi.org/10.1039/B904495G
Kortlever R, Balemans C, Kwon Y, Koper MTM (2014) Electrochemical CO
+ reduction to formic acid on a Pd-based formic acid oxidation catalyst. Catal Today 244:58–62. https://doi.
org/10.1016/j.cattod.2014.08.001
Kortlever R, Peters I, Koper S, Koper MTM (2015) Electrochemical CO 2 reduction to formic acid
at low Overpotential and with high faradaic efficiency on carbon-supported bimetallic Pd−Pt
nanoparticles. ACS Catal 5:3916–3923. https://doi.org/10.1021/acscatal.5b00602
Kumar S, Yadav RK, Ram K, Aguiar A, Koh J, Sobral AJFN (2018) Graphene oxide modified
cobalt metallated porphyrin photocatalyst for conversion of formic acid from carbon dioxide.
J CO 2 Util 27:107–114. https://doi.org/10.1016/j.jcou.2018.07.008
Kyoung-Jin Jeong, Craig M Miesse, Jong-Ho Choi, Jaeyoung Lee, Jonghee Han, Sung Pil Yoon
Suk Woo Nam, Tae-Hoon Lim, Tai Gyu Lee (2007) Fuel crossover in direct formic acid fuel
cells. J Power Sources 119:168. https://doi.org/10.1016/j.jpowsour.2007.02.062
Lal R (2008) Sequestration of atmospheric CO 2 in global carbon Pool. Energy Environ Sci 1:86–
100. https://doi.org/10.1039/B809492F
Lim RJ, Xie M, Sk MA, Lee J-M, Fisher A, Wang X, Lim KH (2013) A review on the electrochemical reduction of CO 2 in fuel cells, metal electrodes and molecular catalysts. Catal Today
233:69–180. https://doi.org/10.1016/j.cattod.2013.11.037
Liu Q, Yang X, Lin L, Miao S, Li Y, Li Y, Wang X, Huang Y, Zhang T (2017) Direct catalytic
hydrogenation of CO 2 to formate over a Schiff-base-mediated gold nanocatalyst. Nat Commun
8:1407. https://doi.org/10.1038/S41467-017-01673-3
Loges A, Boddien HJ, Beller M (2008) Controlled hydrogen production from formic acid amine
adducts at room temperature and direct use in H 2 /O 2 fuel cells. Angew Chem 120:4026–4029.
https://doi.org/10.1002/ange.200705972
Lu X, Leung DYC, Wang H, Leung MKH, Xuan J (2014) Electrochemical reduction of carbon
dioxide to formic acid. ChemElectroChem 1:836–849. https://doi.org/10.1002/celc.201300206
Manbeck GF, Fujita E (2015) A review of Iron and cobalt porphyrins, Phthalocyanines, and related
complexes for electrochemical and photochemical reduction of carbon dioxide. J Porphyrins
Phthalocyanines 19:45–64. https://doi.org/10.1142/S1088424615300013
Marshall RJ, Walsh FC (1985) A review of some recent electrolytic cell designs. Surf Technol
24:45–77. https://doi.org/10.1016/0376-4583(85)90015-9
Mele G, CosimoAnnese LD’A, De Riccardis A, Fusco C, Palmisano L, Scarlino A, Vasapollo G
(2015) Photoreduction of carbon dioxide to formic acid in aqueous suspension: a comparison
between phthalocyanine/TiO 2 and porphyrin/TiO 2 catalysed processes. Molecules 20:396–415.
https://doi.org/10.3390/molecules20010396
Min X, Kanan MW (2015) Pd-catalyzed Electrohydrogenation of carbon dioxide to Formate: high
mass activity at low Overpotential and identification of the deactivation pathway. J Am Chem
Soc 137:4701–4708. https://doi.org/10.1021/ja511890h
Moret S, Dyson PJ, Laurenczy G (2014) Direct synthesis of formic acid from carbon dioxide
by hydrogenation in acidic media. Nat Commun 5:4017. https://doi.org/10.1038/ncomms5017
Mori K, Taga T, Yamashita H (2017) Isolated single-atomic Ru catalyst bound on a layered double hydroxide for hydrogenation of CO 2 to formic acid. ACS Catal 7:3147–3151. https://doi.
org/10.1021/acscatal.7b00312
Morton O (2008) Eating the Sun: how plants power the planet. Harper, New York
4 Conversion of Carbon Dioxide into Formic Acid
Jackstell CFR, Beller M (2010) Modern catalysts for the hydrogenation of carbon dioxide. Angew
Chem 122:6392–6395. https://doi.org/10.1002/ange.201000533
Jessop PG, Ikariya T, Noyori R (1999) Homogeneous catalysis in supercritical fluids. Chem Rev
99:475–493. https://doi.org/10.1021/cr970037a
Jin Z, Li P, Liu G, Zheng B, Yuan H, Xiao D (2013) Enhancing catalytic formaldehyde oxidation
on CuO–Ag 2 O nanowires for gas sensing and hydrogen evolution. J Mater Chem A 1:14736–
14743. https://doi.org/10.1039/C3TA13277C
Johnson TC, Morris DJ, Wills M (2009) Hydrogen generation from formic acid and alcohols using
homogeneous catalysts. Chem Soc Rev 39:81–88. https://doi.org/10.1039/B904495G
Kortlever R, Balemans C, Kwon Y, Koper MTM (2014) Electrochemical CO
+ reduction to formic acid on a Pd-based formic acid oxidation catalyst. Catal Today 244:58–62. https://doi.
org/10.1016/j.cattod.2014.08.001
Kortlever R, Peters I, Koper S, Koper MTM (2015) Electrochemical CO 2 reduction to formic acid
at low Overpotential and with high faradaic efficiency on carbon-supported bimetallic Pd−Pt
nanoparticles. ACS Catal 5:3916–3923. https://doi.org/10.1021/acscatal.5b00602
Kumar S, Yadav RK, Ram K, Aguiar A, Koh J, Sobral AJFN (2018) Graphene oxide modified
cobalt metallated porphyrin photocatalyst for conversion of formic acid from carbon dioxide.
J CO 2 Util 27:107–114. https://doi.org/10.1016/j.jcou.2018.07.008
Kyoung-Jin Jeong, Craig M Miesse, Jong-Ho Choi, Jaeyoung Lee, Jonghee Han, Sung Pil Yoon
Suk Woo Nam, Tae-Hoon Lim, Tai Gyu Lee (2007) Fuel crossover in direct formic acid fuel
cells. J Power Sources 119:168. https://doi.org/10.1016/j.jpowsour.2007.02.062
Lal R (2008) Sequestration of atmospheric CO 2 in global carbon Pool. Energy Environ Sci 1:86–
100. https://doi.org/10.1039/B809492F
Lim RJ, Xie M, Sk MA, Lee J-M, Fisher A, Wang X, Lim KH (2013) A review on the electrochemical reduction of CO 2 in fuel cells, metal electrodes and molecular catalysts. Catal Today
233:69–180. https://doi.org/10.1016/j.cattod.2013.11.037
Liu Q, Yang X, Lin L, Miao S, Li Y, Li Y, Wang X, Huang Y, Zhang T (2017) Direct catalytic
hydrogenation of CO 2 to formate over a Schiff-base-mediated gold nanocatalyst. Nat Commun
8:1407. https://doi.org/10.1038/S41467-017-01673-3
Loges A, Boddien HJ, Beller M (2008) Controlled hydrogen production from formic acid amine
adducts at room temperature and direct use in H 2 /O 2 fuel cells. Angew Chem 120:4026–4029.
https://doi.org/10.1002/ange.200705972
Lu X, Leung DYC, Wang H, Leung MKH, Xuan J (2014) Electrochemical reduction of carbon
dioxide to formic acid. ChemElectroChem 1:836–849. https://doi.org/10.1002/celc.201300206
Manbeck GF, Fujita E (2015) A review of Iron and cobalt porphyrins, Phthalocyanines, and related
complexes for electrochemical and photochemical reduction of carbon dioxide. J Porphyrins
Phthalocyanines 19:45–64. https://doi.org/10.1142/S1088424615300013
Marshall RJ, Walsh FC (1985) A review of some recent electrolytic cell designs. Surf Technol
24:45–77. https://doi.org/10.1016/0376-4583(85)90015-9
Mele G, CosimoAnnese LD’A, De Riccardis A, Fusco C, Palmisano L, Scarlino A, Vasapollo G
(2015) Photoreduction of carbon dioxide to formic acid in aqueous suspension: a comparison
between phthalocyanine/TiO 2 and porphyrin/TiO 2 catalysed processes. Molecules 20:396–415.
https://doi.org/10.3390/molecules20010396
Min X, Kanan MW (2015) Pd-catalyzed Electrohydrogenation of carbon dioxide to Formate: high
mass activity at low Overpotential and identification of the deactivation pathway. J Am Chem
Soc 137:4701–4708. https://doi.org/10.1021/ja511890h
Moret S, Dyson PJ, Laurenczy G (2014) Direct synthesis of formic acid from carbon dioxide
by hydrogenation in acidic media. Nat Commun 5:4017. https://doi.org/10.1038/ncomms5017
Mori K, Taga T, Yamashita H (2017) Isolated single-atomic Ru catalyst bound on a layered double hydroxide for hydrogenation of CO 2 to formic acid. ACS Catal 7:3147–3151. https://doi.
org/10.1021/acscatal.7b00312
Morton O (2008) Eating the Sun: how plants power the planet. Harper, New York
4 Conversion of Carbon Dioxide into Formic Acid