Roberts AL, Sanborn PN, Gschwend PM (1992) Nucleophilic substitution reactions of
dihalomethanes with hydrogen sulfide species. Environ Sci Technol 26:2263–2274. https://
doi.org/10.1021/es00035a027
Roberts AL, Totten LA, Arnold WA et al (1996) Reductive elimination of chlorinated ethylenes by
zero-valent metals. Environ Sci Technol 30:2654–2659. https://doi.org/10.1021/es9509644
Roden EE, Zachara JM (1996) Microbial reduction of crystalline iron(III) oxides: influence of oxide
surface area and potential for cell growth. Environ Sci Technol 30:1618–1628. https://doi.org/
10.1021/es9506216
Rodrigues R, Betelu S, Colombano S et al (2017a) Influence of temperature and surfactants on the
solubilization of hexachlorobutadiene and hexachloroethane. J Chem Eng Data 62:3252–3260.
https://doi.org/10.1021/acs.jced.7b00320
Rodrigues R, Betelu S, Colombano S et al (2017b) Reductive dechlorination of
hexachlorobutadiene by a Pd/Fe microparticle suspension in dissolved lactic acid polymers:
degradation mechanism and kinetics. Ind Eng Chem Res 56:12092–12100. https://doi.org/10.
1021/acs.iecr.7b03012
Rosen MJ, Kunjappu JT (2012) Surfactants and interfacial phenomena, 4th edn. Wiley-Blackwell,
Hoboken, NJ
Ruder AM (2006) Potential health effects of occupational chlorinated solvent exposure. Ann N Y
Acad Sci 1076:207–227. https://doi.org/10.1196/annals.1371.050
Saif S, Tahir A, Chen Y (2016) Green synthesis of iron nanoparticles and their environmental
applications and implications. Nanomaterials 6:209. https://doi.org/10.3390/nano6110209
Saleh N, Sirk K, Liu Y et al (2007) Surface modifications enhance nanoiron transport and napl
targeting in saturated porous media. Environ Eng Sci 24:45–57. https://doi.org/10.1089/ees.
2007.24.45
Saleh N, Kim H-J, Phenrat T et al (2008) Ionic strength and composition affect the mobility of
surface-modified Fe0 nanoparticles in water-saturated sand columns. Environ Sci Technol
42:3349–3355. https://doi.org/10.1021/es071936b
San Román I, Galdames A, Alonso ML et al (2016) Effect of coating on the environmental
applications of zero valent iron nanoparticles: the lindane case. Sci Total Environ
565:795–803. https://doi.org/10.1016/j.scitotenv.2016.04.034
Sarathy V, Tratnyek PG, Nurmi JT et al (2008) Aging of iron nanoparticles in aqueous solution:
effects on structure and reactivity. J Phys Chem C 112:2286–2293. https://doi.org/10.1021/
JP0777418
Sarathy V, Salter AJ, Nurmi JT et al (2010) Degradation of 1,2,3-trichloropropane (TCP): hydrolysis, elimination, and reduction by iron and zinc. Environ Sci Technol 44:787–793. https://doi.
org/10.1021/es902595j
Scherer MM, Balko BA, Gallagher DA, Tratnyek PG (1998) Correlation analysis of rate constants
for dechlorination by zero-valent iron. Environ Sci Technol 32:3026–3033. https://doi.org/10.
1021/es9802551
Scherer MM, Balko BA, Tratnyek PG (1999) The role of oxides in reduction reactions at the metalwater interface. In: Sparks DL, Grundl T (eds) Mineral-water interfacial reactions: kinetics and
mechanisms. American Chemical Society, Washington, DC, pp 301–322
Scherer M, Cwiertny D, Deeb R, et al (2014) Biologically mediated abiotic degradation of
chlorinated ethenes: a new conceptual framework. Strategic Environmental Research and
Development Program ER01-026
Schlicker O, Ebert M, Fruth M et al (2000) Degradation of TCE with iron: the role of competing
chromate and nitrate reduction. Ground Water 38:403–409. https://doi.org/10.1111/j.17456584.2000.tb00226.x
Schöftner P, Waldner G, Lottermoser W et al (2015) Electron efficiency of nZVI does not change
with variation of environmental parameters. Sci Total Environ 535:69–78. https://doi.org/10.
1016/j.scitotenv.2015.05.033
6 In Situ Chemical Reduction of Chlorinated Organic Compounds
391
dihalomethanes with hydrogen sulfide species. Environ Sci Technol 26:2263–2274. https://
doi.org/10.1021/es00035a027
Roberts AL, Totten LA, Arnold WA et al (1996) Reductive elimination of chlorinated ethylenes by
zero-valent metals. Environ Sci Technol 30:2654–2659. https://doi.org/10.1021/es9509644
Roden EE, Zachara JM (1996) Microbial reduction of crystalline iron(III) oxides: influence of oxide
surface area and potential for cell growth. Environ Sci Technol 30:1618–1628. https://doi.org/
10.1021/es9506216
Rodrigues R, Betelu S, Colombano S et al (2017a) Influence of temperature and surfactants on the
solubilization of hexachlorobutadiene and hexachloroethane. J Chem Eng Data 62:3252–3260.
https://doi.org/10.1021/acs.jced.7b00320
Rodrigues R, Betelu S, Colombano S et al (2017b) Reductive dechlorination of
hexachlorobutadiene by a Pd/Fe microparticle suspension in dissolved lactic acid polymers:
degradation mechanism and kinetics. Ind Eng Chem Res 56:12092–12100. https://doi.org/10.
1021/acs.iecr.7b03012
Rosen MJ, Kunjappu JT (2012) Surfactants and interfacial phenomena, 4th edn. Wiley-Blackwell,
Hoboken, NJ
Ruder AM (2006) Potential health effects of occupational chlorinated solvent exposure. Ann N Y
Acad Sci 1076:207–227. https://doi.org/10.1196/annals.1371.050
Saif S, Tahir A, Chen Y (2016) Green synthesis of iron nanoparticles and their environmental
applications and implications. Nanomaterials 6:209. https://doi.org/10.3390/nano6110209
Saleh N, Sirk K, Liu Y et al (2007) Surface modifications enhance nanoiron transport and napl
targeting in saturated porous media. Environ Eng Sci 24:45–57. https://doi.org/10.1089/ees.
2007.24.45
Saleh N, Kim H-J, Phenrat T et al (2008) Ionic strength and composition affect the mobility of
surface-modified Fe0 nanoparticles in water-saturated sand columns. Environ Sci Technol
42:3349–3355. https://doi.org/10.1021/es071936b
San Román I, Galdames A, Alonso ML et al (2016) Effect of coating on the environmental
applications of zero valent iron nanoparticles: the lindane case. Sci Total Environ
565:795–803. https://doi.org/10.1016/j.scitotenv.2016.04.034
Sarathy V, Tratnyek PG, Nurmi JT et al (2008) Aging of iron nanoparticles in aqueous solution:
effects on structure and reactivity. J Phys Chem C 112:2286–2293. https://doi.org/10.1021/
JP0777418
Sarathy V, Salter AJ, Nurmi JT et al (2010) Degradation of 1,2,3-trichloropropane (TCP): hydrolysis, elimination, and reduction by iron and zinc. Environ Sci Technol 44:787–793. https://doi.
org/10.1021/es902595j
Scherer MM, Balko BA, Gallagher DA, Tratnyek PG (1998) Correlation analysis of rate constants
for dechlorination by zero-valent iron. Environ Sci Technol 32:3026–3033. https://doi.org/10.
1021/es9802551
Scherer MM, Balko BA, Tratnyek PG (1999) The role of oxides in reduction reactions at the metalwater interface. In: Sparks DL, Grundl T (eds) Mineral-water interfacial reactions: kinetics and
mechanisms. American Chemical Society, Washington, DC, pp 301–322
Scherer M, Cwiertny D, Deeb R, et al (2014) Biologically mediated abiotic degradation of
chlorinated ethenes: a new conceptual framework. Strategic Environmental Research and
Development Program ER01-026
Schlicker O, Ebert M, Fruth M et al (2000) Degradation of TCE with iron: the role of competing
chromate and nitrate reduction. Ground Water 38:403–409. https://doi.org/10.1111/j.17456584.2000.tb00226.x
Schöftner P, Waldner G, Lottermoser W et al (2015) Electron efficiency of nZVI does not change
with variation of environmental parameters. Sci Total Environ 535:69–78. https://doi.org/10.
1016/j.scitotenv.2015.05.033
6 In Situ Chemical Reduction of Chlorinated Organic Compounds
391