Q
Quantum dots (QDs), 373
Quartz crystal microbalance (QCM), 130
Quenching, 218–219
R
Rare earth, 10, 33, 37, 42
Reactive oxygen species (ROS), 387
Resonance energy transfer, 208
Rho zeolite (RHO), 88, 92
Ruthenium(II) polyimines, see Metal organic
frameworks (MOFs)
S
Saponite surface, 199
Secondary building unit (SBU), 112
Self-assembly, ZL crystals, 23–25
Sensing, 2, 3, 42, 59, 63
Sensor applications, 158–159, 230
Sensor materials, 107
Ship-in-a-bottle strategy
lanthanide complexes, 13
ligands, organolanthanide complexes, 9
Pb clusters, 97
preparation of composites, 14
rare earth complexes, 10
Res-ZL composites, 15
sequential synthesis, 13
space-confinement, silver clusters, 83
zeolite A monolayer, 24
Silver clusters
Ag-carboxylate nanoclusters, 80
characterization (see Characterization
techniques, Ag-exchanged zeolites)
DNA-templated, 78–80
in glassy substrates, 81–82
mass-selected oligoatomic, 78
MOFs, 82
peptide-protected, 80–81
photoluminescence, 77
physicochemical properties, 87
polymer-encapsulated, 81
stabilization protocols, 78
Silver-exchanged zeolites, 82–83
Silver-zeolite composite-based LED
(ZEOLED), 97
Singlet oxygen
Jablonski diagram, 352
molecular orbital energy diagram, 351
photosensitizer, 352
TB-B, 353
Singlet oxygen generation (SOG), 353, 354
Smart materials, 107, 146
Smectites
absorption spectra, methylene blue, 264
clay minerals, 253
dye-smectite hybridization, 254
layered alkali silicates, 255
molecular structures, cationic azobenzenes,
278
MV2
+ co-adsorbed, 270
nanoporous pillared, 255
organic cationic dyes, 255
surface modification, 255, 256
synthetic analogs, 254
Sodalite zeolite (SOD), 98
Solid solvents, 147
Solid-state switching, 123, 124
Solute-solvent interactions, 111
Solvatochromic properties, 112
Solvatochromism, 110–112, 136
Spirooxazines, 110, 112
bimolecular processes, 142
dye molecules, 142
IR spectra, 145
isomerization, 145
photochromic and solvatochromic response,
144
photographic images, 144
SP-Nitro@MOF composites, 145
SP-O@MOF-5, 145–146
UV light irradiation, 142
XPS measurements, 144
Spiropyran (SP), 108, 110, 136–138, 282–283
Stilbenes, 110, 116–117, 134
Stopcock principle, 15–18
Sub-nanometer silver clusters, 77, 82, 87
Supramolecular photochemistry, 324
Supramolecular system, 199
Surface-fixation induced emission (S-FIE),
196–198
Switch@MOF systems, 146
Synthetic clays, 257
Synthetic procedures, 147
T
Theragnosis
cancer diagnosis, 390
cutting-edge nanotheranostic agents, 388
infrared thermal imaging, 390
innocuous tracking, 390, 391
in vitro assays, 390
MRI and CT, 391
404
Index
Quantum dots (QDs), 373
Quartz crystal microbalance (QCM), 130
Quenching, 218–219
R
Rare earth, 10, 33, 37, 42
Reactive oxygen species (ROS), 387
Resonance energy transfer, 208
Rho zeolite (RHO), 88, 92
Ruthenium(II) polyimines, see Metal organic
frameworks (MOFs)
S
Saponite surface, 199
Secondary building unit (SBU), 112
Self-assembly, ZL crystals, 23–25
Sensing, 2, 3, 42, 59, 63
Sensor applications, 158–159, 230
Sensor materials, 107
Ship-in-a-bottle strategy
lanthanide complexes, 13
ligands, organolanthanide complexes, 9
Pb clusters, 97
preparation of composites, 14
rare earth complexes, 10
Res-ZL composites, 15
sequential synthesis, 13
space-confinement, silver clusters, 83
zeolite A monolayer, 24
Silver clusters
Ag-carboxylate nanoclusters, 80
characterization (see Characterization
techniques, Ag-exchanged zeolites)
DNA-templated, 78–80
in glassy substrates, 81–82
mass-selected oligoatomic, 78
MOFs, 82
peptide-protected, 80–81
photoluminescence, 77
physicochemical properties, 87
polymer-encapsulated, 81
stabilization protocols, 78
Silver-exchanged zeolites, 82–83
Silver-zeolite composite-based LED
(ZEOLED), 97
Singlet oxygen
Jablonski diagram, 352
molecular orbital energy diagram, 351
photosensitizer, 352
TB-B, 353
Singlet oxygen generation (SOG), 353, 354
Smart materials, 107, 146
Smectites
absorption spectra, methylene blue, 264
clay minerals, 253
dye-smectite hybridization, 254
layered alkali silicates, 255
molecular structures, cationic azobenzenes,
278
MV2
+ co-adsorbed, 270
nanoporous pillared, 255
organic cationic dyes, 255
surface modification, 255, 256
synthetic analogs, 254
Sodalite zeolite (SOD), 98
Solid solvents, 147
Solid-state switching, 123, 124
Solute-solvent interactions, 111
Solvatochromic properties, 112
Solvatochromism, 110–112, 136
Spirooxazines, 110, 112
bimolecular processes, 142
dye molecules, 142
IR spectra, 145
isomerization, 145
photochromic and solvatochromic response,
144
photographic images, 144
SP-Nitro@MOF composites, 145
SP-O@MOF-5, 145–146
UV light irradiation, 142
XPS measurements, 144
Spiropyran (SP), 108, 110, 136–138, 282–283
Stilbenes, 110, 116–117, 134
Stopcock principle, 15–18
Sub-nanometer silver clusters, 77, 82, 87
Supramolecular photochemistry, 324
Supramolecular system, 199
Surface-fixation induced emission (S-FIE),
196–198
Switch@MOF systems, 146
Synthetic clays, 257
Synthetic procedures, 147
T
Theragnosis
cancer diagnosis, 390
cutting-edge nanotheranostic agents, 388
infrared thermal imaging, 390
innocuous tracking, 390, 391
in vitro assays, 390
MRI and CT, 391
404
Index