intersystem, 331
Jablonski diagram, 332
RTP efficiency, 334
Phosphors, 94–96, 99
Photoactive guests, 159–160, 325
Photoactive metal organic frameworks,
158–159
Photoactive moiety, 108
Photoactive molecules, 113
Photoactive nanohybrids, 378–379
Photochemical properties, 189–190
absorption spectra, 192, 193
cationic molecule, 194
clay nanosheet, 194
fluorescence quantum yield, 193
intramolecular motion, 193
layered silicates, 193
porphyrin molecule, 192, 193
radiative deactivation process, 193
saponite, 193, 194
Sb(V)porphyrin derivatives, 194, 195
Photochemical reactants, 158–159
Photochemistry, 324
alkene, 356
cavitands, 327
ground-state reactions, 324
in heterogeneous systems, 253
modes of interactions, 326
NpEs, 362, 363
physical and chemical processes, 324
state energy diagram of molecule, 186
thioketone, 336
Photochromic behavior, 134
Photochromic dyes, 147, 148
Photochromic moiety, 114
Photochromic molecules, 108
Photochromic properties, 108, 112
Photochromic unit, 114
Photochromism, 108–110
Photocycloadditions (PCA)
alkene photochemistry, 356
bimolecular, 355
non-identical alkenes, 360
palladium nanocage, 361
polyaromatic hydrocarbons, 359
supramolecular approach, 356
unimolecular, 355
Photocyclodimerization, 359
Photodynamic therapy (PDT), 387–388
Photo-Fries rearrangement reaction
carbon-heteroatom bond, 361
decarbonylated products, 362
naphthyl benzoates, 362
photochemistry, 363
radical mechanism, 361
Photoinduced phenomena
basal spacing, 287–289
magnetism, photoswitching, 291–292
photoinduced adsorption of phenol,
292–294
wettability, photoswitching, 289, 290
Photoluminescence
in copper clusters, 77–78
2-cyclohexene-1-one, photocycloaddition,
285
silver-exchanged zeolites, 83
UCNP emissions, 378
Photophysics
dye-clay hybrid systems (see Dye-clay
hybrid systems)
luminescent silver-zeolite composites,
83–85
RuBpy complex, 159, 180
stilbene fluorescence, 331
thioflavin (TF), 347
thione, 338
Photosensitizer (PS), 387
Photostationary state (PSS), 114, 118
Photoswitch, 114
pH sensing, 381–385
Physicochemical environment, 114
Pigments, 2, 3, 63, 207
Planar aromatic molecules, 199, 200
Polyelectrolytes, 228–229
Polyethylene glycol (PEG), 388
Polymer-encapsulated silver clusters, 81
Polymers
industrial, 228
luminescent, 229
nanocomposites, 228
polyelectrolytes, 228–229
type, 227
Poly(methyl methacrylic acid) (PMAA), 81
Polyoxoanions, 166
Polyoxometalates (POMs), 166
Poly(tetrafluoroethylene) (PTFE), 5, 10
Porous coordination polymer (PCP), 117
Porous interpenetrated zirconium-organic
frameworks (PIZOFs), 113
Porphyrin macrocycles, 158–159
Probability density functions (PDFs), 213
Pyridine-substituted spiropyran (Py-SP), 283,
288
Index
403
Jablonski diagram, 332
RTP efficiency, 334
Phosphors, 94–96, 99
Photoactive guests, 159–160, 325
Photoactive metal organic frameworks,
158–159
Photoactive moiety, 108
Photoactive molecules, 113
Photoactive nanohybrids, 378–379
Photochemical properties, 189–190
absorption spectra, 192, 193
cationic molecule, 194
clay nanosheet, 194
fluorescence quantum yield, 193
intramolecular motion, 193
layered silicates, 193
porphyrin molecule, 192, 193
radiative deactivation process, 193
saponite, 193, 194
Sb(V)porphyrin derivatives, 194, 195
Photochemical reactants, 158–159
Photochemistry, 324
alkene, 356
cavitands, 327
ground-state reactions, 324
in heterogeneous systems, 253
modes of interactions, 326
NpEs, 362, 363
physical and chemical processes, 324
state energy diagram of molecule, 186
thioketone, 336
Photochromic behavior, 134
Photochromic dyes, 147, 148
Photochromic moiety, 114
Photochromic molecules, 108
Photochromic properties, 108, 112
Photochromic unit, 114
Photochromism, 108–110
Photocycloadditions (PCA)
alkene photochemistry, 356
bimolecular, 355
non-identical alkenes, 360
palladium nanocage, 361
polyaromatic hydrocarbons, 359
supramolecular approach, 356
unimolecular, 355
Photocyclodimerization, 359
Photodynamic therapy (PDT), 387–388
Photo-Fries rearrangement reaction
carbon-heteroatom bond, 361
decarbonylated products, 362
naphthyl benzoates, 362
photochemistry, 363
radical mechanism, 361
Photoinduced phenomena
basal spacing, 287–289
magnetism, photoswitching, 291–292
photoinduced adsorption of phenol,
292–294
wettability, photoswitching, 289, 290
Photoluminescence
in copper clusters, 77–78
2-cyclohexene-1-one, photocycloaddition,
285
silver-exchanged zeolites, 83
UCNP emissions, 378
Photophysics
dye-clay hybrid systems (see Dye-clay
hybrid systems)
luminescent silver-zeolite composites,
83–85
RuBpy complex, 159, 180
stilbene fluorescence, 331
thioflavin (TF), 347
thione, 338
Photosensitizer (PS), 387
Photostationary state (PSS), 114, 118
Photoswitch, 114
pH sensing, 381–385
Physicochemical environment, 114
Pigments, 2, 3, 63, 207
Planar aromatic molecules, 199, 200
Polyelectrolytes, 228–229
Polyethylene glycol (PEG), 388
Polymer-encapsulated silver clusters, 81
Polymers
industrial, 228
luminescent, 229
nanocomposites, 228
polyelectrolytes, 228–229
type, 227
Poly(methyl methacrylic acid) (PMAA), 81
Polyoxoanions, 166
Polyoxometalates (POMs), 166
Poly(tetrafluoroethylene) (PTFE), 5, 10
Porous coordination polymer (PCP), 117
Porous interpenetrated zirconium-organic
frameworks (PIZOFs), 113
Porphyrin macrocycles, 158–159
Probability density functions (PDFs), 213
Pyridine-substituted spiropyran (Py-SP), 283,
288
Index
403