nanohybrid surface, 390
nanoparticles, 388
photothermal therapy, 390
simultaneous imaging, 388
targeted therapy, 388
Thermal deactivation, 187
Thermal organic reactions, 324
Thermogravimetric analysis (TGA), 87, 94, 117
Thin MOF films
approach, 113
1,4-butanediol, 130, 132
chromophore, 140
conductance photoswitching, 142
conduction properties, 142
controlled thermal desorption, 132, 133
dipole moments, 130
E-AZB@HKUST-1, 127
electronic coupling, 142
fluorescence spectroscopic measurements,
139
hole injection, 142
homogenous morphology, 141
host-guest interactions, 140
hybrid, 127
in situ layer-by-layer growth, 127
IR spectroscopy, 128, 129, 134, 142
JUC-120, 138
light-induced conversion processes, 138
N 2 sorption isotherms, 131
photochromic dye, 138
photochromic properties, 127
photochromism, 139, 140
photorelaxation, 139
photostability, 130
photoswitching, 130
reversible gas permeation, 132, 133
spiropyrans, 141
SP-Nitro@UiO-67, 142
SP-to-MC conversion, 140
tF-AZB, 130
UV light irradiation, 139
UV/vis spectra, 127–129
XPS, 128, 129
XRPD measurements, 138, 141
Thiocarbonyl compounds, 336
Thioflavin (TF), 340, 347
benzothiazole dye, 349
excimer emission, 348
titration of solution, 348
Thioketone photochemistry, 336, 337
Time-of-flight secondary ion mass spectrometry
(ToF-SIMS), 128
Transition metal polyimines, 159–160
Transition probability, 186, 187
Transmission electron microscopy (TEM,
91–92
Triethoxysilylated coumarin dye (TSPCU), 20
1,3,5-Tris(4-carboxyphenyl)benzene (TCPB),
167
1,3,5-Tris[(N-pyridinium)aniline-4-yl]-benzene
(TPAB), 196, 197
Twisted-intramolecular charge transfer (TICT)
behavior, 339
biphenyl/bipyridinium, 343
chromophores, 340
complexation processes, 342
destabilization, 341
DMABN, 339
DNC, 340
emission, 339
geometry, 338
locally excited (LE) state, 339
stilbazole ST1, 341
U
Upconversion nanoparticles (UCNPs)
applications, 373
chromophores, 373, 378–379
luminescence, 373
PDT, 387–388
photoactive nanohybrids, 378–379
preparation methods, 373
properties (see NIR excitation)
sensing
biomolecules, 385–386
fluorescence sensors, 379
inner filter, 380
LRET, 380–381
microscale cellular level, 379
pH, 381–385
photoactive species, 379
photophysical properties, 379
ratiometric/time-resolved
measurements, 379
synthetic protocols, 373
tunable long-lifetime emission, 378
UV-Vis irradiation, 81
V
Van der Waals model, 24, 27, 46
W
Water-resistant dye-ZL composite, 11
Wettability, 289, 290
White-light-emitting diodes (WLEDs), 99
Index
405
nanoparticles, 388
photothermal therapy, 390
simultaneous imaging, 388
targeted therapy, 388
Thermal deactivation, 187
Thermal organic reactions, 324
Thermogravimetric analysis (TGA), 87, 94, 117
Thin MOF films
approach, 113
1,4-butanediol, 130, 132
chromophore, 140
conductance photoswitching, 142
conduction properties, 142
controlled thermal desorption, 132, 133
dipole moments, 130
E-AZB@HKUST-1, 127
electronic coupling, 142
fluorescence spectroscopic measurements,
139
hole injection, 142
homogenous morphology, 141
host-guest interactions, 140
hybrid, 127
in situ layer-by-layer growth, 127
IR spectroscopy, 128, 129, 134, 142
JUC-120, 138
light-induced conversion processes, 138
N 2 sorption isotherms, 131
photochromic dye, 138
photochromic properties, 127
photochromism, 139, 140
photorelaxation, 139
photostability, 130
photoswitching, 130
reversible gas permeation, 132, 133
spiropyrans, 141
SP-Nitro@UiO-67, 142
SP-to-MC conversion, 140
tF-AZB, 130
UV light irradiation, 139
UV/vis spectra, 127–129
XPS, 128, 129
XRPD measurements, 138, 141
Thiocarbonyl compounds, 336
Thioflavin (TF), 340, 347
benzothiazole dye, 349
excimer emission, 348
titration of solution, 348
Thioketone photochemistry, 336, 337
Time-of-flight secondary ion mass spectrometry
(ToF-SIMS), 128
Transition metal polyimines, 159–160
Transition probability, 186, 187
Transmission electron microscopy (TEM,
91–92
Triethoxysilylated coumarin dye (TSPCU), 20
1,3,5-Tris(4-carboxyphenyl)benzene (TCPB),
167
1,3,5-Tris[(N-pyridinium)aniline-4-yl]-benzene
(TPAB), 196, 197
Twisted-intramolecular charge transfer (TICT)
behavior, 339
biphenyl/bipyridinium, 343
chromophores, 340
complexation processes, 342
destabilization, 341
DMABN, 339
DNC, 340
emission, 339
geometry, 338
locally excited (LE) state, 339
stilbazole ST1, 341
U
Upconversion nanoparticles (UCNPs)
applications, 373
chromophores, 373, 378–379
luminescence, 373
PDT, 387–388
photoactive nanohybrids, 378–379
preparation methods, 373
properties (see NIR excitation)
sensing
biomolecules, 385–386
fluorescence sensors, 379
inner filter, 380
LRET, 380–381
microscale cellular level, 379
pH, 381–385
photoactive species, 379
photophysical properties, 379
ratiometric/time-resolved
measurements, 379
synthetic protocols, 373
tunable long-lifetime emission, 378
UV-Vis irradiation, 81
V
Van der Waals model, 24, 27, 46
W
Water-resistant dye-ZL composite, 11
Wettability, 289, 290
White-light-emitting diodes (WLEDs), 99
Index
405