4.1 Element Hydride (Elementane) Names
147
Table 14. Systematic names for parent hydrides (elementanes) of element groups 13-17
13
14b
IS b,c
16 b
17 b
BH3 Borane
CH4 Carbane
NH3 Azane
OHz Oxidane FH Fluorane
AIH3 Aluminane SiH4 Silane
PH3 Phosphane SHz Sulfane ClH Chlorane
GaH3 Gallane
GeH4 Germane AsH3 Arsane
SeHz Selane BrH Bromane
InH3 Indi(c)ane SnH4 Stannane SbH3 Stibane
TeH z Tellane IH Iodane
TIH3 Thallane
PbH4 Plumbane BiH3 Bismutane PoHz Polane AtH Astatane
a The possibilitiy to assign systematic names to all of these fundamental hydrides
should be no means prejudice the abolishment of the perennial trivial designations
methane, ammonia, water, and hydrogen halides.
b For hydrides with non-standard valencies of the core atom the following ruling holds:
EHn = ,\n-elementane.
C For the elements of group 15 Chern, Abstr. still uses the traditional designations
phosph-, ars-, stib-, bismuthine.
Ph-Pd-H
Ph
< ~T(OAch
Ph
(EtOhSiH
Dicyclohexylphosphane
Tri-t-butylborane
Hexakis-( 4-trifluormethylphenyl)-,,\6-tellane
Tetramethyl-,,\4-sulfane
Trineopentyl-,,\3-iodane
Tetraisopropyl-,,\4-ti tanane
Bis( trifluormethyl)mercurane
Hexamethyl-,,\6-wolframane (tungstane)
Phenyl-,,\2-palladane
Tetrakisacetyloxy-( 1,1' :3',1"terphenyl-2' -yl)-,P-iodane
Triethoxysilane
Butylindi(c)ane