Contents
IX
4 Metalorganic and Metalloidorganic Compounds
146
4.1
Element Hydride (Elementane) Names ..
146
4.2
Functionally Substituted Elementanes . . . . . . . . .. 149
4.3
Elementanes with Repeating Diads . . . . . . . . . . .. 149
4.4
Organic Derivatives of Alkali and Alkaline Earth Metals
and Comparable Compounds
. . . . . . .
150
4.5
"ate" Complexes. . . . . . . . . . . . . . . . . . . . . .. 153
5 Carbohydrates ..
155
5.1
Aldoses
155
5.2
Ketoses . . . . . . . . . . . . . . . .
158
5.3
Ketoaldoses (Aldoketoses, Aldosuloses) . . . . . . . .
160
5.4
Deoxy Sugars . . . . . . . . . . . . . . . . . . . . . . .
161
5.5
Amino Sugars and Analogously Substituted Derivatives 162
5.6
Transformations of the Carbonyl Functions
162
5.6.1
Oximes, Hydrazones, Osazones .
162
5.6.2
Acetals, Ketals . . . . . . . . . . . . . . . . .
163
5.7
Branched Sugars . . . . . . . . . . . . . . .
163
5.8
Sugar Alcohols (Alditols) . . . . . . . . . .
164
5.9
Acids Derived from Sugars . . . . . . . . . .
165
5.10
O-Substitution. . . . . . . . . . . . . . . . .
168
5.10.1
O-Substitution with Alkyl and Acyl Groups .
168
5.10.2
Cyclic Acetals and Ketals . . . . . . . . . .
168
5.11
Monosaccharides as Substituent Groups .
169
5.12
Glycosides and Glycosyl Compounds
170
5.12.1
Glycosides. . . . . . .
170
5.12.2
Glycosyl Compounds. . . . . . . . . .
172
5.13
Oligo saccharides . . . . . . . . . . . . . . . . . . .
173
5.13.1
Oligo saccharides with Free Hemiacetal Group ..
173
5.13.2
Oligosaccharides without Free Hemiacetal Group
174
5.13.3
Polysaccharides (Glycans) . . . . . . . . . . . .
175
5.14
Customary Trivial Names . . . . . . . . . . . . .
176
6 Construction of the Names of Complex Compounds . . . . .
178
6.1
6.2
6.3
6.4
6.5
Determination of the Highest Ranked Chain
(Main or Senior Chain) . . . . . . . . . . . . . . . .
Determination of the Most Senior Ring System ..
Treatment of the Most Senior Characteristic Group
in the Light of the Two Preceding Paragraphs ..
Numbering . . . . . . . . . . . . . . . . . . . . . .
Order of Prefixes . . . . . . . . . . . . . . . . . . .
178
179
180
181
182
IX
4 Metalorganic and Metalloidorganic Compounds
146
4.1
Element Hydride (Elementane) Names ..
146
4.2
Functionally Substituted Elementanes . . . . . . . . .. 149
4.3
Elementanes with Repeating Diads . . . . . . . . . . .. 149
4.4
Organic Derivatives of Alkali and Alkaline Earth Metals
and Comparable Compounds
. . . . . . .
150
4.5
"ate" Complexes. . . . . . . . . . . . . . . . . . . . . .. 153
5 Carbohydrates ..
155
5.1
Aldoses
155
5.2
Ketoses . . . . . . . . . . . . . . . .
158
5.3
Ketoaldoses (Aldoketoses, Aldosuloses) . . . . . . . .
160
5.4
Deoxy Sugars . . . . . . . . . . . . . . . . . . . . . . .
161
5.5
Amino Sugars and Analogously Substituted Derivatives 162
5.6
Transformations of the Carbonyl Functions
162
5.6.1
Oximes, Hydrazones, Osazones .
162
5.6.2
Acetals, Ketals . . . . . . . . . . . . . . . . .
163
5.7
Branched Sugars . . . . . . . . . . . . . . .
163
5.8
Sugar Alcohols (Alditols) . . . . . . . . . .
164
5.9
Acids Derived from Sugars . . . . . . . . . .
165
5.10
O-Substitution. . . . . . . . . . . . . . . . .
168
5.10.1
O-Substitution with Alkyl and Acyl Groups .
168
5.10.2
Cyclic Acetals and Ketals . . . . . . . . . .
168
5.11
Monosaccharides as Substituent Groups .
169
5.12
Glycosides and Glycosyl Compounds
170
5.12.1
Glycosides. . . . . . .
170
5.12.2
Glycosyl Compounds. . . . . . . . . .
172
5.13
Oligo saccharides . . . . . . . . . . . . . . . . . . .
173
5.13.1
Oligo saccharides with Free Hemiacetal Group ..
173
5.13.2
Oligosaccharides without Free Hemiacetal Group
174
5.13.3
Polysaccharides (Glycans) . . . . . . . . . . . .
175
5.14
Customary Trivial Names . . . . . . . . . . . . .
176
6 Construction of the Names of Complex Compounds . . . . .
178
6.1
6.2
6.3
6.4
6.5
Determination of the Highest Ranked Chain
(Main or Senior Chain) . . . . . . . . . . . . . . . .
Determination of the Most Senior Ring System ..
Treatment of the Most Senior Characteristic Group
in the Light of the Two Preceding Paragraphs ..
Numbering . . . . . . . . . . . . . . . . . . . . . .
Order of Prefixes . . . . . . . . . . . . . . . . . . .
178
179
180
181
182