186
C.M.G. van den Berg
Acknowledgements
The speciation research of the author is financially supported by a grant from the NERC
("PRIME" GST/0211 058), and contracts with EU ("MERLIM" MAS3-CT95-0005, and
"MOLAR" ENV 4-CT95-0007).
References
Batley GE, Florence TM (1976) Determination of the chemical forms of dissolved cadmium, lead and
copper in seawater. Mar Chern 4:347-363
Berger P, Ewald M, Liu D, Weber JH (1984) Application of the fluorescence quenching titration method
to tile complexation of copper(II) in the Gironde estuary (France). Mar Chern 14:289-295
Buckley PJM, van den Berg CMG (1986) Copper complexation profiles in tile Atlantic Ocean. Mar Chern
19:281-296
Campbell PGC, Bisson M, Gagne R, Tessier A (1977) Critical evaluation of the copper (II) solubilization method for the determination of the complexation capacity of natural waters. Anal Chern
49:2358-2363
Campos MLAM, van den Berg CMG (1994) Determination of copper complexation in sea water bycatilodic
stripping voltammetry and ligand competition witil salicylaldoxime. Anal Chim Acta 284:481-496
Chau YK, Gachter R, Lum-Shue-Chan K (1974) Determination of the apparent complexing capacity
of lake waters. J Fish Res B Canada 31:1515-1519
Coale KH, Bruland KW (1988) Copper complexation in the Northeast Pacific. Limnol Oceanogr
33:lO84-1101
Coale KH, Bruland KW (1990) Spatial and temporal variability in copper complexation in the North
Pacific. Deep-Sea Res 47:317-336
Harwood-Sears V, Gordon AS (1990) Copper-induced production of copper-binding supernatant proteins by tile marine bacterium Vibrio alginolyticus. Appl Environ MicrobioI56:1327-1332
Kramer CJM (1986) Apparent copper complexation capacity and conditional stability constants in
North Atlantic waters. Mar Chern 18:335-349
Leal MFC, Vasconcelos MTSD, van den Berg CMG (1999) Copper induced release of complexing ligands
similar to thiols by Emiliania huxleyi in seawater cultures. Limnol Oceanogr, in proof
Mills GL, Quinn JG (1981) Isolation of dissolved organic matter and copper-organic complexes from
estuarine waters using reverse-phase liquid chromatography. Mar Chern lO:93-102
Moffett JW, lika RG (1987) Solvent extraction of copper acetylacetonate in studies of copper(II)
speciation in seawater. Mar Chern 21:301-313
Ostapczuk P, Valenta P, Niirnberg HW (1986) Square wave voltammetry - a rapid and reliable determination method of In, Cd, Pb, Cu, Ni and Co in biological and environmental samples. J
Electroanal Chern 214:51-64
Raspor B, Nurnberg HW, Valenta P, Branica M (1980) The chelation of lead by organic ligands in sea
water. In: Branica M, Konrad l (eds) Lead in the marine environment. Pergamon Press, Oxford,
pp 181-195
Rue EL, Bruland KW (1995) Complexation of iron(III) by natural organic ligands in the Central North
Pacific as determined by a new competitive ligand equilibration/adsorptive cathodic stripping
voltammetric method. Mar Chern 50:117-138
Ruzic I (1982) Theoretical aspects of the direct titration of natural waters and its information yield
for trace metal speciation. Anal Chim Acta 140:99-113
Shuman MS, Michael LC (1978) application of the rotating disk electrode to measurement of copper
complex dissociation rate constants in marine coastal samples. Env Sci Technol12:1069-1072
Sueur S, van den Berg CMG, Riley JP (1982) Measurement of the metal complexing ability of exudates
of marine macroalgae. Limnol Oceanogr 27:536-543
van den Berg CMG (1982) Determination of copper complexation with natural organic ligands in
seawater by equilibration with MnO,. I. Theory. Mar Chern 11:307-322
van den Berg CMG (1984a) Determination of the complexing capacity and conditional stability constants of complexes of copper(II) with natural organic ligands in seawater by cathodic stripping
voltammetry of copper-catechol complex ions. Mar Chern 15:1-18
van den Berg CMG (1984b) Direct determination of sub-nanomolar levels of zinc in seawater by cathodic stripping voltammetry. Talanta 31:lO69-1073
van den Berg CMG (1985) Determination of the zinc complexing capacity in seawater by cathodic stripping voltammetry of zinc-APDC complex ions. Mar Chern 16:121-130
C.M.G. van den Berg
Acknowledgements
The speciation research of the author is financially supported by a grant from the NERC
("PRIME" GST/0211 058), and contracts with EU ("MERLIM" MAS3-CT95-0005, and
"MOLAR" ENV 4-CT95-0007).
References
Batley GE, Florence TM (1976) Determination of the chemical forms of dissolved cadmium, lead and
copper in seawater. Mar Chern 4:347-363
Berger P, Ewald M, Liu D, Weber JH (1984) Application of the fluorescence quenching titration method
to tile complexation of copper(II) in the Gironde estuary (France). Mar Chern 14:289-295
Buckley PJM, van den Berg CMG (1986) Copper complexation profiles in tile Atlantic Ocean. Mar Chern
19:281-296
Campbell PGC, Bisson M, Gagne R, Tessier A (1977) Critical evaluation of the copper (II) solubilization method for the determination of the complexation capacity of natural waters. Anal Chern
49:2358-2363
Campos MLAM, van den Berg CMG (1994) Determination of copper complexation in sea water bycatilodic
stripping voltammetry and ligand competition witil salicylaldoxime. Anal Chim Acta 284:481-496
Chau YK, Gachter R, Lum-Shue-Chan K (1974) Determination of the apparent complexing capacity
of lake waters. J Fish Res B Canada 31:1515-1519
Coale KH, Bruland KW (1988) Copper complexation in the Northeast Pacific. Limnol Oceanogr
33:lO84-1101
Coale KH, Bruland KW (1990) Spatial and temporal variability in copper complexation in the North
Pacific. Deep-Sea Res 47:317-336
Harwood-Sears V, Gordon AS (1990) Copper-induced production of copper-binding supernatant proteins by tile marine bacterium Vibrio alginolyticus. Appl Environ MicrobioI56:1327-1332
Kramer CJM (1986) Apparent copper complexation capacity and conditional stability constants in
North Atlantic waters. Mar Chern 18:335-349
Leal MFC, Vasconcelos MTSD, van den Berg CMG (1999) Copper induced release of complexing ligands
similar to thiols by Emiliania huxleyi in seawater cultures. Limnol Oceanogr, in proof
Mills GL, Quinn JG (1981) Isolation of dissolved organic matter and copper-organic complexes from
estuarine waters using reverse-phase liquid chromatography. Mar Chern lO:93-102
Moffett JW, lika RG (1987) Solvent extraction of copper acetylacetonate in studies of copper(II)
speciation in seawater. Mar Chern 21:301-313
Ostapczuk P, Valenta P, Niirnberg HW (1986) Square wave voltammetry - a rapid and reliable determination method of In, Cd, Pb, Cu, Ni and Co in biological and environmental samples. J
Electroanal Chern 214:51-64
Raspor B, Nurnberg HW, Valenta P, Branica M (1980) The chelation of lead by organic ligands in sea
water. In: Branica M, Konrad l (eds) Lead in the marine environment. Pergamon Press, Oxford,
pp 181-195
Rue EL, Bruland KW (1995) Complexation of iron(III) by natural organic ligands in the Central North
Pacific as determined by a new competitive ligand equilibration/adsorptive cathodic stripping
voltammetric method. Mar Chern 50:117-138
Ruzic I (1982) Theoretical aspects of the direct titration of natural waters and its information yield
for trace metal speciation. Anal Chim Acta 140:99-113
Shuman MS, Michael LC (1978) application of the rotating disk electrode to measurement of copper
complex dissociation rate constants in marine coastal samples. Env Sci Technol12:1069-1072
Sueur S, van den Berg CMG, Riley JP (1982) Measurement of the metal complexing ability of exudates
of marine macroalgae. Limnol Oceanogr 27:536-543
van den Berg CMG (1982) Determination of copper complexation with natural organic ligands in
seawater by equilibration with MnO,. I. Theory. Mar Chern 11:307-322
van den Berg CMG (1984a) Determination of the complexing capacity and conditional stability constants of complexes of copper(II) with natural organic ligands in seawater by cathodic stripping
voltammetry of copper-catechol complex ions. Mar Chern 15:1-18
van den Berg CMG (1984b) Direct determination of sub-nanomolar levels of zinc in seawater by cathodic stripping voltammetry. Talanta 31:lO69-1073
van den Berg CMG (1985) Determination of the zinc complexing capacity in seawater by cathodic stripping voltammetry of zinc-APDC complex ions. Mar Chern 16:121-130