XeKr B0
þ
; v max
ð
ÞþKr
1 S
À Á ! XeKr B0
þ
; v max À Dv
ð
Þ þ Kr
1 S
À Á
ð4Þ
! XeKr X0
þ
; A1
ð
ÞþKr
1 S
À Á
ð5Þ
! Xe
3 P 1
À Á þ 2Kr
1 S
À Á
ð6Þ
10. Calculate the steady-state concentration of the O(
3 P) and (O…O 2 )
# intermediate species if it is known that the processes
O 2 þ hv ! . . . ! 2O
3 P
À Á
ð1Þ
O
3 P
À Á þ O 2 $ O. . .O 2
ð
Þ
#
ð2Þ
O. . .O 2
ð
Þ
# !
M O 3 þ M
ð3Þ
occur in the system under study.
References
1. IUPAC Compendium of Chemical Terminology, 2nd ed. (the Gold book). Complied by A.D.
McNaught and A. Wilkinson, Blackwell Scientific Publications, Oxford (1997). https://doi.org/
10.1351/goldbook
2. Kondratiev, V.N., Nikitin, E.E.: Gas-phase Reactions: Kinetics and Mechanism.
Springer-Verlag, Berlin Heidelberg New York (1981). https://doi.org/10.1007/978-3-64267608-6
3. Glasstone, S.: Theoretical Chemistry, D. van Nostrand Comp., Inc. (1944)
4. Laidler, K.J.: Chemical Kinetics. McGaw Hill Book Co, New York-London (1965). https://doi.
org/10.1002/bbpc.19660700316
5. Blanksby, S.J., Ellison, G.B.: Bond dissociation energies of organic molecules. Acc. Chem.
Res. 36, 255–263 (2003). https://doi.org/10.1021/ar020230d
6. Liberman, M.A., Velikovich, A.L.: Physics of Shock Waves in Gases and Plasmas. Springer
(1986). https://doi.org/10.1017/S0022112094211059
7. Herzberg, G.: Molecular Spectra and Molecular Structure, vol. 1. Spectra of Diatomic
Molecules, Van Nostrand, New York (1950)
8. Calvert, J.G., Pitts, J.N., Jr.: Photochemistry. John Wiley & Sons; 1st edition (1966)
9. Porter, G.: Mechanism of third-order recombination reactions. Disc. Far. Soc. 33, 198–204
(1962)
36
2 General Kinetic Rules for Chemical Reactions, Collisional …
þ
; v max
ð
ÞþKr
1 S
À Á ! XeKr B0
þ
; v max À Dv
ð
Þ þ Kr
1 S
À Á
ð4Þ
! XeKr X0
þ
; A1
ð
ÞþKr
1 S
À Á
ð5Þ
! Xe
3 P 1
À Á þ 2Kr
1 S
À Á
ð6Þ
10. Calculate the steady-state concentration of the O(
3 P) and (O…O 2 )
# intermediate species if it is known that the processes
O 2 þ hv ! . . . ! 2O
3 P
À Á
ð1Þ
O
3 P
À Á þ O 2 $ O. . .O 2
ð
Þ
#
ð2Þ
O. . .O 2
ð
Þ
# !
M O 3 þ M
ð3Þ
occur in the system under study.
References
1. IUPAC Compendium of Chemical Terminology, 2nd ed. (the Gold book). Complied by A.D.
McNaught and A. Wilkinson, Blackwell Scientific Publications, Oxford (1997). https://doi.org/
10.1351/goldbook
2. Kondratiev, V.N., Nikitin, E.E.: Gas-phase Reactions: Kinetics and Mechanism.
Springer-Verlag, Berlin Heidelberg New York (1981). https://doi.org/10.1007/978-3-64267608-6
3. Glasstone, S.: Theoretical Chemistry, D. van Nostrand Comp., Inc. (1944)
4. Laidler, K.J.: Chemical Kinetics. McGaw Hill Book Co, New York-London (1965). https://doi.
org/10.1002/bbpc.19660700316
5. Blanksby, S.J., Ellison, G.B.: Bond dissociation energies of organic molecules. Acc. Chem.
Res. 36, 255–263 (2003). https://doi.org/10.1021/ar020230d
6. Liberman, M.A., Velikovich, A.L.: Physics of Shock Waves in Gases and Plasmas. Springer
(1986). https://doi.org/10.1017/S0022112094211059
7. Herzberg, G.: Molecular Spectra and Molecular Structure, vol. 1. Spectra of Diatomic
Molecules, Van Nostrand, New York (1950)
8. Calvert, J.G., Pitts, J.N., Jr.: Photochemistry. John Wiley & Sons; 1st edition (1966)
9. Porter, G.: Mechanism of third-order recombination reactions. Disc. Far. Soc. 33, 198–204
(1962)
36
2 General Kinetic Rules for Chemical Reactions, Collisional …