E
E/f labeling, 108
Einstein absorption coefficient, 97
Einstein spontaneous emission coefficient, 12,
101, 102, 132, 272
Einstein stimulated emission coefficient, 98,
101
Elastic collision, 38, 60, 154
Electronic deactivation, 5, 81, 82, 189, 266,
271
Electronic Hamiltonian, 178, 179
Electronic interaction, 71, 127, 128
Electronic interaction matrix element, 127, 136
Electronic partition function, 19, 21, 22
Electronic Predissociation (EP), 136, 207, 213,
220, 221, 223, 228, 230, 231, 235, 237,
238, 245, 250, 251, 253
Electronic statistical weight, 20
Electron-rotational interaction, 72, 275
Electrostatic perturbations, 111
Electrostatic predissociation, 136
Emission, 1, 2, 79, 202, 266
Energy transfer mechanism, 30, 277
Equilibrium constant, 16, 19, 23, 24, 43, 276
Exchange chemiluminescence, 266
F
Fermi Golden Rule, 75
First-order PT, 50
Franck-Condon density, 97, 137
Franck-Condon principle, 79, 103
Frank-Condon Factor (FCF), 72, 97, 120, 122,
167, 170, 185, 186, 189, 194, 205, 210,
221, 227, 249
Frank-Condon principle, 103, 274
G
Gas kinetic constant, 26
Gas-kinetic cross-section, 62
Gas-kinetic diameter, 26, 58, 174
Gateway model, 169, 171, 173
Gyroscopic predissociation, 135–139
H
Halogen bond, 200, 257
Hamiltonian, 44, 65, 70, 111, 130, 137, 177
Heterogeneous perturbation, 114
HFI matrix element, 124
Homogeneous perturbation, 114, 115
Hydrogen bond, 200
Hyperfine Hamiltonian, 120
Hyperfine Interaction (HFI), 107, 118, 120,
122–125, 128, 156
Hyperfine Predissociation (HFP), 137, 138, 139
I
Image point, 43, 59, 62, 64–66, 70, 74, 76, 140,
141, 147, 158, 166, 168, 171, 192, 221,
237, 272, 275
Indirect heterogeneous perturbation, 117
Inelastic collision, 38, 42, 153
Integral absorption coefficient, 132
Integral chemiluminescence rate constant, 270
Integral intensity of chemiluminescence, 270
Intermolecular, 1–3, 37, 49, 50, 57, 58, 199,
202, 253
Intermolecular dissociation energy, 201
Intermolecular interaction, 159
Intermolecular PES, 244
Intermolecular potential energy, 50
Intermolecular vibrational levels, 212
Intramolecular, 1, 156
Intramolecular perturbations, 79, 174
Intramolecular Vibrational Redistribution
(IVR), 207, 208, 230, 231, 234, 252,
255
Inverse dissociation, 265, 267, 270, 273
Inverse electronic predissociation, 265, 268,
274
Inverse predissociation, 74, 267, 276
Irreducible representations, 47, 71, 86, 88
K
Kinetic order, 8, 9
L
Landau-Teller formula, 159, 164
Landau-Zener formula, 77, 136
Lennard–Jones potential, 58
Luminescence, 81, 84, 188, 238
M
Massey parameter, 48, 59, 60, 70, 73
MD interaction, 120, 125
Microscopic equilibrium constant, 43
Microscopic reaction rate constant, 39
MQ interaction, 120
Mulliken difference potential, 103, 104, 106
N
Nonadiabatic coupling, 73
Nonadiabatic interaction, 71, 73, 111
Nonadiabatic predissociation, 136
Nonadiabatic process, 59, 70, 147, 158, 231,
275
Nonadiabatic transition, 37, 70, 73–76, 81, 82,
140, 179, 268
Nuclear partition function, 19, 21, 23
Number of collisions, 8, 24–26, 156, 157
290
Index
E/f labeling, 108
Einstein absorption coefficient, 97
Einstein spontaneous emission coefficient, 12,
101, 102, 132, 272
Einstein stimulated emission coefficient, 98,
101
Elastic collision, 38, 60, 154
Electronic deactivation, 5, 81, 82, 189, 266,
271
Electronic Hamiltonian, 178, 179
Electronic interaction, 71, 127, 128
Electronic interaction matrix element, 127, 136
Electronic partition function, 19, 21, 22
Electronic Predissociation (EP), 136, 207, 213,
220, 221, 223, 228, 230, 231, 235, 237,
238, 245, 250, 251, 253
Electronic statistical weight, 20
Electron-rotational interaction, 72, 275
Electrostatic perturbations, 111
Electrostatic predissociation, 136
Emission, 1, 2, 79, 202, 266
Energy transfer mechanism, 30, 277
Equilibrium constant, 16, 19, 23, 24, 43, 276
Exchange chemiluminescence, 266
F
Fermi Golden Rule, 75
First-order PT, 50
Franck-Condon density, 97, 137
Franck-Condon principle, 79, 103
Frank-Condon Factor (FCF), 72, 97, 120, 122,
167, 170, 185, 186, 189, 194, 205, 210,
221, 227, 249
Frank-Condon principle, 103, 274
G
Gas kinetic constant, 26
Gas-kinetic cross-section, 62
Gas-kinetic diameter, 26, 58, 174
Gateway model, 169, 171, 173
Gyroscopic predissociation, 135–139
H
Halogen bond, 200, 257
Hamiltonian, 44, 65, 70, 111, 130, 137, 177
Heterogeneous perturbation, 114
HFI matrix element, 124
Homogeneous perturbation, 114, 115
Hydrogen bond, 200
Hyperfine Hamiltonian, 120
Hyperfine Interaction (HFI), 107, 118, 120,
122–125, 128, 156
Hyperfine Predissociation (HFP), 137, 138, 139
I
Image point, 43, 59, 62, 64–66, 70, 74, 76, 140,
141, 147, 158, 166, 168, 171, 192, 221,
237, 272, 275
Indirect heterogeneous perturbation, 117
Inelastic collision, 38, 42, 153
Integral absorption coefficient, 132
Integral chemiluminescence rate constant, 270
Integral intensity of chemiluminescence, 270
Intermolecular, 1–3, 37, 49, 50, 57, 58, 199,
202, 253
Intermolecular dissociation energy, 201
Intermolecular interaction, 159
Intermolecular PES, 244
Intermolecular potential energy, 50
Intermolecular vibrational levels, 212
Intramolecular, 1, 156
Intramolecular perturbations, 79, 174
Intramolecular Vibrational Redistribution
(IVR), 207, 208, 230, 231, 234, 252,
255
Inverse dissociation, 265, 267, 270, 273
Inverse electronic predissociation, 265, 268,
274
Inverse predissociation, 74, 267, 276
Irreducible representations, 47, 71, 86, 88
K
Kinetic order, 8, 9
L
Landau-Teller formula, 159, 164
Landau-Zener formula, 77, 136
Lennard–Jones potential, 58
Luminescence, 81, 84, 188, 238
M
Massey parameter, 48, 59, 60, 70, 73
MD interaction, 120, 125
Microscopic equilibrium constant, 43
Microscopic reaction rate constant, 39
MQ interaction, 120
Mulliken difference potential, 103, 104, 106
N
Nonadiabatic coupling, 73
Nonadiabatic interaction, 71, 73, 111
Nonadiabatic predissociation, 136
Nonadiabatic process, 59, 70, 147, 158, 231,
275
Nonadiabatic transition, 37, 70, 73–76, 81, 82,
140, 179, 268
Nuclear partition function, 19, 21, 23
Number of collisions, 8, 24–26, 156, 157
290
Index